Abstract
In concentrates of natural and drinking waters of Dnieper river basin in Kiev region with enrichment factor of 1,80-105–3,47.105 PCB (PCB524, PCB664, PCB1015, PCB1185, PCB1055, PCB1536, PCB1386, PCB1807, PCB2008) have been identified and their isomeric-specific composition (tetrachloro-— heptachloroisomers) has been determined at MDL for total concentration of PCB at level as low as 0,19–0,38 ng/L and 0,19–0,36 ng/L calculated by the mean value in groups of pentachloro—and hexachloroisomers respectively.
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References
Pilipenko, A.T., Milyukin, M.V., Tulyupa, F.M. (1991) Concentration, identification and determination of microimpurities of organic compounds in waters by Chromatographic and mass-spectrometric methods, Soviet Journal of Water Chemistry and Technology (Khimiya i Tekhnologiya Vody) 13, no. 9, 53–101.
Milyukin, M.V., Pilipenko, A.T. (1993) Isolation and concentration of microimpurities of semivolatile and nonvolatile organic compounds of natural and drinking waters from neutral and acidic media by the method of solid-phase extraction, Journal of Water Chemistry and Technology (Khimiya i Tekhnologiya Vody) 15, no. 6, 7–10.
Milyukin, M.V. (1996) Solid-phase extraction of trace amounts of semivolatile and nonvolatile organic compounds of natural and drinking water from neutral and acid medium, Journal of Water Chemistry and Technology (Khimiya i Tekhnologiya Vody) 18, no. 12, 16–21.
Milyukin, M.V. (2000) Solid-phase extraction of microtraces of semivolatile and nonvolatile organic compounds from surface waters, Hydrobiological Journal (Gidrobiologitsheskii jurnal) 36, no 1, 102–112 (in Russian).
Milyukin, M.V., Pilipenko, A.T. (1993) Identification of microimpurities of semivolatile organic compounds of neutral and acidic character in natural and drinking waters by chromato-mass-spectrometry method, Journal of Water Chemistry and Technology (Khimiya i Tekhnologiya Vody) 15, no.6, 11–21.
Milyukin, M.V. (1994) Identification of microimpurities of aromatic semivolatile compounds of neutral and acidic character in natural and drinking waters by chromato-mass-spectrometry method (GC/MS), Journal of Water Chemistry and Technology (Khimiya i Tekhnologiya Vody) 16, no. 7, 34–40.
Milyukin, M.V. (1996) Identification of trace amounts of semivolatile organic compounds of neutral and acidic character in natural and drinking water concentrates after solid-phase extraction by GC/MS, Journal of Water Chemistry and Technology (Khimiya i Tekhnologiya Vody) 18, no. 11, 19–30.
Milyukin, M.V. (2000) Identification of microtraces of semivolatile organic compounds of neutral and acidic nature in concentrates of surface waters of Zaporozhie and Kakhovka reservoirs by GC/MS, Hydrobiological Journal (Gidrobiologitsheskii jurnal) 36, no. 4, 66–83 (in Russian).
Milyukin, M.V. (1996) Determination of chloroorganic pesticides and polychlorinated biphenyls in the natural and drinking waters of Dnieper river basin by GC/ECD and GC/MS, in Proceedings and Abstacts of the International Ecological Congress, Voronezh (Russia), 22-28 Sept., pp. 19–21.
Goncharuk, V.V., Milyukin, M.V. (1999) Evaluation of contamination level of Dnieper river by organic and inorganic toxicants, in Ph. Baveye, J.-C. Block, V.V. Goncharuck (eds.), Bioavailability of Organic Xenobiotics in the Environment (Practical Consequences for the Environment), Kluwer Academic Publishers, Dordrecht, pp. 35–56.
Milyukin, M.V. (1998) Monitoring of organochlorine pesticides and polychorinated biphenyls in natural and drinking waters of the Dnieper river basin by GC/ECD and GC/MS: methodology of solid-phase extraction, identification and determination, in Proceedings of USAID-USEPA-UNDP Ukraine Pest and Pesticide Management Project (PPMP) “Modern scientific approaches to registration of pesticides: ecotoxicology ”, Kyiv (Ukraine), 7-10 April, pp. 66–69.
Milyukin, M.V. (1999) Analytical problems of isolation, concentration, identification and determination of microtraces of semivolatile organic compounds in waters by GC/MS, in Proceedings of Analytical Russia-Germany-Ukraine Symposium (ARGUS-99), Odessa (Ukraine), 29 August — 2 September, pp. 70–71.
Milyukin, M.V. (2000) Determination of organochlorine pesticides and polychlorinated biphenyls in water objects by GC/MS in Abstracts book of M.P. Komar memoral Conference on Analytical Chemistry (KUAC 2000), Kharkiv (Ukraine), 15-19 May, p. 271.
Milyukin, M.V. (2000) Monitoring of organochlorine pesticides and polychorinated biphenyls in natural and drinking waters and sediments of the Dnieper river basin by GC/MS in Abstracts book of N.S. Poluektov and N.F. Zacharia memoral Conference “Modern methods of analysis for control quality of technical production products, ecology and toxicology”, Odessa (Ukraine), 28-31 August, pp. 57–58.
Milyukin, M.V. (1998) Analytical problems of isolation, concentration, identification and determination of microtraces of organic compounds in waters by ChromatographiC and mass-spectrometric methods, Journal of Water Chemistry and Technology (Khimiya i Tekhnologiya Vody) 20, no. 1, pp. 46–52.
Milyukin, M.V. (1997) Solid-phase extraction and identification of nonionic surfactants of the class of oxyethylated phenols and alkylphenols in mine waters by GC/MS, Journal of Water Chemistry and Technology (Khimiya i Tekhnologiya Vody) 19, no. 12, pp. 6–20.
Vaisberger, A., Proskauer, E., Riddick, D., Tups, E. (1958) Organic Solvents [Russian translation], Inostr. Lit, Moscow.
Klisenko, M. A. (ed.) (1983) Methods of determination of pesticides microtraces in food products, feeds and environment [Reference edition], Kolos, Moscow.
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Milyukin, M.V. (2003). Determination of Isomeric-Specific Composition of Polychlorinated Biphenyls in Natural and Drinking Waters of Dnieper River Basin in Kiev Region Using Gas Chromatography and Mass-Spectrometry. In: Barany, S. (eds) Role of Interfaces in Environmental Protection. NATO Science Series, vol 24. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0183-0_6
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DOI: https://doi.org/10.1007/978-94-010-0183-0_6
Publisher Name: Springer, Dordrecht
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