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Selective Adsorbents for Improved Removal of Malodorous Compounds

  • Conference paper
Role of Interfaces in Environmental Protection

Part of the book series: NATO Science Series ((NAIV,volume 24))

Abstract

This work presents different methods of adsorbents characterisation. Their use towards improved removal of malodorous compounds is considered. These methods are applied to different modified silica gels. At first, the synthesis conditions were optimised using aminopropylsilanes. Afterwards the stability of the samples against ethanol and water was examined. The modified silica gels are suggested to be selective adsorbents in the field of odour control.

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References

  1. VDI-Guideline, VDI 3477 (2002) Biological waste gas purification — Biofilters.

    Google Scholar 

  2. VDI-Guideline, VDI 3477 (1996) Biological waste gas purification — Bioscruppers and trickle bed reactors.

    Google Scholar 

  3. VDI-Guideline, VDI 2442 (1987) Waste gas cleaning by thermal combustion.

    Google Scholar 

  4. VDI-Guideline, VDI 3476 (1990) Catalytic; exhaust gas purification.

    Google Scholar 

  5. VDI-Guideline, VDI 3674 (1998) Waste gas cleaning by adsorption — Process and waste gas cleaning.

    Google Scholar 

  6. Leffingwell, J.C. (2001) Olfaction, Leffingwell Reports 1, 1–24

    Google Scholar 

  7. Pauling, L. (1946) Molecular architecture and Biological Reactions, Chem. Eng. News 24, 1375–1377

    Article  CAS  Google Scholar 

  8. Amoore, J.E. (1970) Molecular Basis of Odor, C.C. Thomas, Pub., Springfield

    Google Scholar 

  9. Dyson, G.M. (1938) The Scientific Basis of Odor, Chem. Ind. 57, 647–651

    Article  Google Scholar 

  10. Wright RH (1982) The Sense of Smell, CRC Press, Boca Raton, USA

    Google Scholar 

  11. Turin, L. (1996) A spectroscopic mechanism for primary olfactory reception, Chem. Senses 21,773–791

    Article  CAS  Google Scholar 

  12. Jones, K. (1987) Optimisation Procedure for the Silanisation of Silicas for Reversed-Phase High-Performance Liquid Chromatography-I. Elimination of Non-Significant Variables, J. Chrom. 392, 1–10.

    Article  CAS  Google Scholar 

  13. Jones, K. (1987) Optimization procedure for the silanistion of silicas for reversed-phase high-performance liquid chromatography — II. detailed examination of significant, J. Chromatogr. 392, 11–16

    Article  CAS  Google Scholar 

  14. Scholten, A.B., de Haan, J.W., Ciaessens, H.A., van de Ven, L.J.M., Cramers C.A. (1996) Fundamental Study of Residual Silanol Populations on Alkylsilane-Derivatized Silica Surfaces, Langmuir 12, 4741–4747

    Article  CAS  Google Scholar 

  15. Czajkowska, T., Tittelbach, Y., Bereznitski, Y., Jaroniec, M. (1998) Adsorption, thermogravimetric, and Chromatographic studies of bare silicas and silica-based octyl bonded phases, J. Liq. Chrom. & Rel. Technol. 21, 1957–1977

    Article  CAS  Google Scholar 

  16. Kinkel, J.N., Unger, K.K. (1984) Role of Solvent and Base in the Silanization Reaction of Silicas for Reversed-Phase High-Performance Liquid Chromatography, J. Chrom. 316, 193–200

    Article  CAS  Google Scholar 

  17. Berendsen, G. E., Pikaart, K. A., de Galan, L. (1980) Preparation of various bonded phases for HPLC using monochlorosilanes, J. Liq. Chromatogr. 3, 1437–1464

    Article  CAS  Google Scholar 

  18. Cheng, W., McCown, M. (1985) Effect of Alkyl chain length on surface silanization of silica, J. Chrom., 318, 173–185.

    Article  CAS  Google Scholar 

  19. Waddell, T. G., Leyden, D. E., DeBello, M. T. (1981) The Nature of Organosilane to Silica-Surface Bonding, J. Am. Chem. Soc. 103, 5303–5307

    Article  CAS  Google Scholar 

  20. P. Van Der Voort, E. F. Vansant (1996) Silylation of the Silicia Surface — A Review, Journal of Liquid Cromatography and Related Technology, 19, 2723–2752

    Article  Google Scholar 

  21. Burns, G.Th., Deng, Q., Hahn, J.R., Reggio, G.L., Su, K. (2000): Method for removing metal contaminants from solution using mercapto-functional silica xerogels. US-Patent 6013187

    Google Scholar 

  22. Blitz, J. P., Shreedhara Murthy, R. S., Leyden, D. E. (1988) The role of amine structure on catalytic activity for silylation reactions with Cab-O-Sil, J. Colloid Interface Sci. 126, 387–392

    Article  CAS  Google Scholar 

  23. Chiang, C.H., Ishida, H., Koenig, J.L. (1980) The Structure of gamma-Aminopropyltriethoxysilane on Glass Surfaces, J. Coll. Interf. Sci. 74, 396–404

    Article  CAS  Google Scholar 

  24. Chiang, C.H., Liu, N., Koenig, J.L. (1982) Magic-Angle Cross-Polarization Carbon 13 NMR Study of Aminosilane Coupling Agents on Silica Surfaces. J. Coll. Interf. Sci. 86, 26–33

    Article  CAS  Google Scholar 

  25. Goodwin, J. W., Harbron, R. S., Reynolds, P. A. (1990) Functionalization of collodial silica and silica surfaces via silylation reactions, Colloid Polym. Sci. 268, 766–777

    Article  CAS  Google Scholar 

  26. Kallury, K. M. R., Cheung, M., Ghaemmaghami, V., Krull, U. J., Thompson, M. (1992) Silanization of oxidized silicon and aluminium surfaces with functionalized silanes with characterization by wettability, ellipsometry, XPS and quartz crystal microbalance studies, Colloids Surfaces 63, 1–9

    Article  CAS  Google Scholar 

  27. Iannicelli, J. (1991) Polymer reinforcement with amino and mercaptosilane grafted kaolin, Minerals & Metallurgical Processing 8, 135–138

    CAS  Google Scholar 

  28. Thiesen, P., Beneke, K., Lagaly G., Silylation of a crystalline silicic acid: an MAS-NMR and porosity study. J. Mater. Chem., accepted for publication

    Google Scholar 

  29. Foschiera, J.L., Pizzolato, T.M., Benvenutti, E.V. (2001): FTIR Thermal Analysis on Organofunctionalized Silica Gel. J. Braz. Chem. Soc., 12, 159–164

    Article  CAS  Google Scholar 

  30. Washburn, E.W. (1920) The Dynamics of Capillary Flow, Physical Review, 17 273–283

    Article  Google Scholar 

  31. Lucas, R. (1918) Ueber das Zeitgesetz des kapillaren Aufstiegs von Flüssigkeiten, Kolloid Zeitschrift, 23, 15–22.

    Article  CAS  Google Scholar 

  32. Thiesen, P.H., Mahlke, LT., Niemeyer, B. (2002) Characterization of adsorbents for odour reduction, Progr. Colloid Polym. Sci. 121, 23–27

    Article  CAS  Google Scholar 

  33. Dickinson, T.A., White, J., Kauer, J.S., Walt, D.R. (1998) Current trends in “artifical-nose” technology, TIBTECH, 16, 250–257

    Article  CAS  Google Scholar 

  34. Peri, J. B., Hensley, Jr. A. L. (1968) The Surface Structure of Silicia Gel, J. Phys. Chem. 72, 2926–2933.

    Article  CAS  Google Scholar 

  35. Sindorf, D.W., Maciel, G.E. (1982) Cross-Polarization/Magic-Angle-Spinning Silicon-29 Nuclear Magnetic Resonance Study of Silica Gel Using Trimethylsilane Bonding as a Probe of the Surface Geometry and Reactivity, J. Phys. Chem. 86, 5208–5219

    Article  CAS  Google Scholar 

  36. Jansen, J. (1999) Funktionalisierung bioaktiver Träger. Diploma Thesis, Univ. der Bundeswehr Hamburg, Hamburg

    Google Scholar 

  37. Braaß, O. (2002) Selektive Abtrennung von Alkoholdehydrogenase aus Bäckerhefe durch Anwendung hoher Drücke, PhD-Thesis, Univ. der Bundeswehr Hamburg, Hamburg

    Google Scholar 

  38. Braaß O, Niemeyer B, Thiesen P. (2000) Vergleich des Adsorptionsverhaltens von geruchsaktiven Substanzen an funktionalisierten Kieselgelen und Aktivkohle. CIT, 72: 1103

    Google Scholar 

  39. Braaß O, Thiesen P.H. Niemeyer B, (2002) Adsorptionskinetik von geruchsaktiven Substanzen an funktionalisierten Silicagelen und Aktivkohle, CIT, 78, in Press

    Google Scholar 

  40. Volz K.O. (2002) Kontaktwinkelmessungen an Kieselgelen und modifizierten Derivaten, Diploma Thesis, Univ. der Bundeswehr Hamburg, Hamburg

    Google Scholar 

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Thiesen, P.H., Jansen, J., Volz, K.O., Mahlke, I.T., Niemeyer, B. (2003). Selective Adsorbents for Improved Removal of Malodorous Compounds. In: Barany, S. (eds) Role of Interfaces in Environmental Protection. NATO Science Series, vol 24. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0183-0_19

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  • DOI: https://doi.org/10.1007/978-94-010-0183-0_19

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1479-6

  • Online ISBN: 978-94-010-0183-0

  • eBook Packages: Springer Book Archive

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