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Wolfram und Wasserstoff

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W Wolfram

Part of the book series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition ((1058,volume W / A-B / B / 1))

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Zusammenfassung

Die Reaktion von Wolfram mit Wasserstoff führt bei tiefen Temperaturen (< etwa 500 K) zur Bildung von Adsorptionsschichten, in denen der Wasserstoff atomar und molekular in verschiedenen Adsorptionszuständen gebunden vorliegt. Die Kinetik und Thermodynamik der Adsorptions- und Desorptionsprozesse, die auftretenden geordneten Strukturen der Adsorptionsschichten sowie deren Einfluß auf physikalische Eigenschaften wie Austrittsarbeit und elektronische Zustände werden in zahlreichen Arbeiten und unter Verwendung aller modernen Techniken an mono- und polykristallinen Proben beschrieben. Dabei bietet Wolfram wegen seiner außerordentlich geringen Löslichkeit für Wasserstoff und seiner experimentellen Vorteile eine ideale Modellsubstanz für die Untersuchung von Adsorptionsphänomenen an kubisch raumzentrierten Metallen.

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Jehn, H. (1978). Wolfram und Wasserstoff. In: Katscher, H., Berg, L., Hein, H. (eds) W Wolfram. Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, vol W / A-B / B / 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-12478-9_2

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