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Measurement of Spectrum with High-Quality Including Quantitative Analysis

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NMR Spectroscopy of Polymers

Part of the book series: Springer Laboratory ((SPLABORATORY))

Abstract

NMR is uniquely powerful in the determination of polymer microstructure, such as stereochemical configuration (tacticity), geometrical isomerism, regioirregularity, and monomer sequences in copolymers. Quantitative data concerning these structural characteristics of polymers can be obtained from relative intensities of the respective peaks for these structures, and are hardly collected by other analytical means. NMR measurements for the analyses of polymers should be performed with much higher accuracy and precision than those for low molecular weight compounds; in the latter only approximate intensity ratios, such as CH3:CH2=3:2, are required.’ Experimental conditions for quantitative polymer analysis have been discussed in reviews [1, 2] and those for general purposes in a book by Derome [3].

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Authors and Affiliations

  1. Graduate School of Engineering Science Department of Chemistry, Osaka University, Machikaneyama 1-3, 560-8531, Toyonaka Osaka, Japan

    Prof. Dr. Koichi Hatada & Prof. Dr. Tatsuki Kitayama

Authors
  1. Prof. Dr. Koichi Hatada
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  2. Prof. Dr. Tatsuki Kitayama
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© 2004 Springer-Verlag Berlin Heidelberg

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Hatada, K., Kitayama, T. (2004). Measurement of Spectrum with High-Quality Including Quantitative Analysis. In: NMR Spectroscopy of Polymers. Springer Laboratory. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-08982-8_2

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  • DOI: https://doi.org/10.1007/978-3-662-08982-8_2

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-07293-2

  • Online ISBN: 978-3-662-08982-8

  • eBook Packages: Springer Book Archive

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