Skip to main content

Reactions with Boron

  • Chapter
W Tungsten

Part of the book series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th Edition ((1058,volume W / A-B / A / 5 / b))

  • 248 Accesses

Abstract

The phase diagram of the W-B system as proposed by [1] and redrawn by [2] is shown in Fig. 120. It is mainly based on the work of [3]. For earlier phase diagrams, see [4, 5, 69]. For the W-B system as a special case of the ternary systems W-B-M (M = Y, La, Ce, Pr, Gd, and Er), see [6]. A calculation of the W-B phase diagram was attempted [79], see also [80] for the thermochemical data.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Moffatt, W. G. (Handbook of Binary Phase Diagrams, Business Growth Services, Schenectady, New York, 1976).

    Google Scholar 

  2. Massalski, T. D. (Binary Alloy Phase Diagrams, Vol. 1–2, American Society for Metals, Metals Park, Ohio, 1986, pp. 395–397).

    Google Scholar 

  3. Rudy, E. (AFML-TR-65–2 Pt. V; AD-689843 [1969] 1–689, 214–5).

    Google Scholar 

  4. Kieffer, R.; Benesovsky, F. (Hartstoffe, Springer, Wien 1963, pp. 429–34).

    Google Scholar 

  5. Portnoi, K. I.; Romashov, V. M.; Levinskii, Yu V.; Romanovich, I. V. (Poroshk. Metall. [Kiev] 1967 No. 5, pp. 75–80; Sov. Powder Metall. Met. Ceram. [Engl. Transi.] 1967 398–402).

    Google Scholar 

  6. Kuz’ma, Yu. B.; Mikhalenko, S. I.; Chaban, N. F. (Issled. Primen. Splavov Tugoplavkikh Met. 1983 5–11; C.A. 100 [1984] No. 72496).

    Google Scholar 

  7. Chrétien, A.; Helgorsky, J. (C. R. Hebd. Seances Acad. Sci. 252 [1961] 742–4).

    Google Scholar 

  8. Helgorsky, J. (Ann. Chim. [Paris] 6 [1961] 1339–81).

    CAS  Google Scholar 

  9. Goldschmidt, H. J.; Catherall, E. A.; Ham, W. M.; Oliver, D. A. (ASD-TDR-62–25 Pt. II [AD-418033] [1963], pp. 1–36) from [10, 11].

    Google Scholar 

  10. Shunk, F. A. (Constitution of Binary Alloys, 2nd Suppl., McGraw-Hill, New York 1969, pp. 101–2).

    Google Scholar 

  11. Romans, P. A.; Krug, M. P. (Acta Crystallogr. 20 [1966] 313–6).

    Article  CAS  Google Scholar 

  12. Shtein, L M. (Legir. Obrab. Legk. Splavov 1981 117–9; C.A. 96 [1982] No. 56374).

    Google Scholar 

  13. Galasso, F.; Pinto, J. (Trans. Metall. Soc. AIME 242 [1968] 754–5).

    CAS  Google Scholar 

  14. Rudy, E.; Benesovsky, F.; Toth, L. (Z. Metallk. 54 [1963] 345–53).

    CAS  Google Scholar 

  15. DiCarlo, J. A. (NASA-TM-79077, E-9894 [1979] 1–23; C.A. 91 [1979] No. 161538).

    Google Scholar 

  16. Avlokhashvili, D. Zh.; Tavadze, G. F.; Gabuniya, D. L. (Metalloved. Korrz. Met. 5 [1977] 21–5; C.A. 88 [1978] No. 195847).

    Google Scholar 

  17. Kiessling, R. (Acta Chem. Scand. 1 [1947] 893–916).

    Article  CAS  Google Scholar 

  18. Brewer, L.; Sawyer, D. L.; Templeton, D. H.; Dauben, C. H. (J. Am. Ceram. Soc. 34 [1951] 173–9).

    Article  CAS  Google Scholar 

  19. Kornilov, I. L; Matveeva, N. M.; Pryakhina, L. L; Polyakova, R. S. (Metallokhimicheskie Svoistva Elementov Periodicheskoi Systemy [Metal-Chemical Properties of the Elements of the Periodical System], Moscow 1966, pp. 179–82; C.A. 68 [1968] No. 16365).

    Google Scholar 

  20. Samsonov, G. V. (Izv. Sekt. Fiz.-Khim. Anal. Inst. Obshch. Neorg. Khim Akad. Nauk SSSR 27 [1956] 97–125; Ref. Zh. Khim. 1957 No. 11177).

    CAS  Google Scholar 

  21. Minkevich, A. N.; Rastorguev, L. N.; Andryushechkin, V. I. (Izv. Vyssh. Uchebn. Zaved. Chern. Metall. 1960 No. 7, pp. 171–9; C.A. 1961 11231).

    Google Scholar 

  22. Vetters, H. (Sitz. Arbeitskreises Rastermikrosk. Materialprüf. 10 1981 [1982] 215–28; C.A. 99 [1983] No. 57383).

    Google Scholar 

  23. Seybolt, A. U. (Trans. Am. Soc. Met. 52 [1960] 971–89).

    CAS  Google Scholar 

  24. Epik, A. P. (Poroshk. Metall. [Kiev] 3 No. 5 [1963] 21–7; Sov. Powder Metall. Met. Ceram. [Engl. Transi.] 1963 361–5).

    Google Scholar 

  25. Samsonov, G. V. (Dokl. Akad. Nauk SSSR 113 [1957] 1299–301;

    CAS  Google Scholar 

  26. Samsonov, G. V. Dokl. Chem. [Engl. Transi.] 113 [1957] 417–9).

    Google Scholar 

  27. Tucker, S. A.; Moody, H. R. (Proc. Chem. Soc. London 17 [1901] 129–30).

    Google Scholar 

  28. Wedekind, E. (Ber. Dtsch. Chem. Ges. 46 [1913] 1198–207, 1206).

    Article  CAS  Google Scholar 

  29. Halla, F.; Thury, W. (Z. Anorg. Allg. Chem. 249 [1942] 229–37).

    Article  CAS  Google Scholar 

  30. Post, B.; Glaser, F. W. (J. Chem. Phys. 20 [1952] 1050–1).

    Article  CAS  Google Scholar 

  31. Post, B.; Glaser, F. W.; Moskowitz, D. (Acta Metall. 2 [1954] 20–5).

    Article  CAS  Google Scholar 

  32. Glaser, F. W. (Trans. Am. Inst. Min. Metall. Pet. Eng. 194 [1952] 391–6).

    Google Scholar 

  33. Vetters, H.; Mayr, P. (Scanning Electron Microsc. 1983 No. 1, pp. 105–11 ; C. A. 99 [1983] No. 199128).

    Google Scholar 

  34. Vetters, H.; Mayr, P. (HTM Härterei-Tech. Mitt. 40 No. 5 [1985] 198–210).

    CAS  Google Scholar 

  35. Kieffer, R.; Benesovsky, F.; Honak, E. R. (Z. Anorg. Allg. Chem. 268 [1952] 191–200).

    Article  CAS  Google Scholar 

  36. Moers, K.; Agte, C. (Z. Anorg. Allg. Chem. 198 [1931] 233–75, 243–75).

    Article  Google Scholar 

  37. Hansen, M.; Anderko, K. (Constitution of Binary Alloys, McGraw-Hill, New York 1958, pp. 264–5).

    Google Scholar 

  38. Levinskii, Yu. V.; Salibekov, S. E.; Levinskaya, M. Kh. (Poroshk. Metall. [Kiev] 5 No. 12 [1965] 56–62; Sov. Powder Metall. Met. Ceram. [Engl. Transi.] 1965 1004–9).

    Google Scholar 

  39. Jiménez-Crespo, A.; Tergenius, L. E.; Lundström, T. (J. Less-Common Met. 77 [1981] 147–50).

    Article  Google Scholar 

  40. Itoh, H.; Matsudaira, T.; Naka, S.; et al. (J. Mater. Sci 22 [1987] 2811–5).

    Article  CAS  Google Scholar 

  41. Matsudaira, T.; Itoh, H.; Naka, S.; et al. (Yogyo Kyokaishi 95 No. 2 [1987] 248–52 from C.A. 106 [1987] No. 124531).

    Google Scholar 

  42. Matsudaira, T.; Itoh, H.; Naka, S.; et al. (Zairyo 36 [1987] 1167–71 from C.A. 108 [1988] No. 80553).

    CAS  Google Scholar 

  43. Minkevic, A. N. (Härterei-Tech. Mitt. 17 No. 3 [1962] 141–7).

    CAS  Google Scholar 

  44. Matsuda, F.; Nakata, K. (1st Int. Conf. Surf. Eng., Brighton, UK, 1985 [1986], Vol. 3, pp. 109–20 from C.A. 107 [1987] No. 138902).

    Google Scholar 

  45. Omae, N.; Nakamura, A.; Koike, S.; Umeno, M. (J. Vac. Sci. Technol. A 5 [1987] 1367–70).

    Article  CAS  Google Scholar 

  46. Shtein, L. M. (Legir. Obrab. Legk. Splavov 1981 117–9; C.A. 96 [1982] No. 56374).

    Google Scholar 

  47. Deiss, W. J.; Andrieux, J. L (Bull. Soc. Chim. Fr. 1959 178–82).

    Google Scholar 

  48. Champbell, I. E.; Powell, C. F.; Nowicki, D. H.; Gonser, B. W. (Trans. Electrochem. Soc. 96 [1949] 318–33, 331).

    Article  Google Scholar 

  49. Boman, M.; Carlsson, J. O. (Surf. Technol. 24 [1985] 173–90).

    Article  CAS  Google Scholar 

  50. Bonetti, R.; Comte, D.; Hintermann, H. E. (Proc. Conf. Chem. Vap. Deposition 5th Int. Conf., Slough, Engl., 1975, pp. 495–508; C.A. 84 [1976] No. 154195).

    Google Scholar 

  51. v. Naray-Szabo, S.; Tobias, C. W. (J. Am. Chem. Soc. 71 [1949] 1882–3).

    Article  Google Scholar 

  52. Beck, K.; Kopitzki, K.; Krauss, G.; Mertler, G. (Radiat. Eff. 77 [1983] 79–87).

    Article  CAS  Google Scholar 

  53. Andersen, J. U.; Laegsgaard, E.; Feldman, L. C. (Radiat. Eff. 12 [1972] 219–23).

    Article  CAS  Google Scholar 

  54. Skakun, N. A.; Matyash, P. P.; Dikii, N. P. (Ukr. Fiz. Zh. 19 [1974] 1610–3).

    CAS  Google Scholar 

  55. Samsonov, G. V.; Epik, A. P. (Fiz. Met. Metalloved. 14 [1962] 479–80;

    CAS  Google Scholar 

  56. Samsonov, G. V.; Epik, A. P. Phys. Met. Metallogr. [Engl. Transi.] 14 No. 3 [1962] 144–5).

    Google Scholar 

  57. Samsonov, G. V.; Latysheva, V. P. (Fiz. Met. Metalloved. 2 [1956] 309–19; C.A. 1957 6258).

    CAS  Google Scholar 

  58. Samsonov, G. V.; Latysheva, V. P. (Dokl. Akad. NaukSSSR 109 [1956] 582–5; C.A. 1957 9249).

    CAS  Google Scholar 

  59. Samsonov, G. V. (Bor Tr. Konf. Khim. Bora Ego Soedin., Moscow 1955 [1958], pp. 74–89; C.A. 1960 23564).

    Google Scholar 

  60. Samsonov, G. V. (Dokl. Akad. Nauk SSSR 93 [1953] 859–61).

    CAS  Google Scholar 

  61. Samsonov, G. V. (Izv. Sekt. Fiz.-Khim. Anal. Inst. Obshch. Neorg. Khim. Akad. Nauk SSSR 27 [1956] 97–125; Ref. Zh. Khim. 1957 No. 11177).

    Google Scholar 

  62. Klopp, W. D.; Barth, V. D. (DMIC-Memo-50 [1960] 1–10; C.A. 57 [1962] 6984).

    Google Scholar 

  63. Spivak, L.L. (Fiz. Met. Metalloved. 22 [1966] 859–64;

    CAS  Google Scholar 

  64. Spivak, L.L. Phys. Met. Matallogr. [Engl. Transi.] 22 No. 6 [1966] 52–7).

    Google Scholar 

  65. Panteleeva, G. V.; Kharimov, R. Kh. (Izv. Akad. Nauk SSSR Neorg. Mater. 11 [1975] 943–4;

    CAS  Google Scholar 

  66. Panteleeva, G. V.; Kharimov, R. Kh. Inorg. Mater. [Engl. Transi.] 11 [1975] 806–7).

    Google Scholar 

  67. Tolstobrov, Yu O.; Povarova, K. B. (Fiz. Khim. Obrab. Mater. 187 No. 5, pp. 121–4 from C.A. 108 [1988] No. 42281).

    Google Scholar 

  68. Khitrova, V. I.; Tikhonova, A. A.; Titov, V. V.; et al. (Izv. Akad. Nauk Kaz. SSR Ser. Fiz. Mat. 1981 No. 6, pp. 50–6; C.A. 96 [1982] No. 113729).

    Google Scholar 

  69. Bodrova, L. G.; Koval’chenko, M. S.; Serebryakova, T. I. (Poroshk. Metall. [Kiev] 1974 No. 1, pp. 1–4; Sov. Powder Metall. Met. Ceram. [Engl. Transi.] 13 [1974] 1–3).

    Google Scholar 

  70. Samsonov, G. V.; Epik, A. P. (Coatings of High-Temperature Materials, Pt. 1, Plenum, New York 1966, pp. 7–111, 25–9).

    Google Scholar 

  71. Galasso, F.; Paton, A. (Trans. Metall. Soc. AIME 236 [1966] 1751–2).

    CAS  Google Scholar 

  72. Gebhardt, M. (in: Bardsley, W.; Hurle, D. T. J.; Mullin, J. B.; Hartman, P.; Crystal Growth: An Introduction, North-Holland, Amsterdam 1973, pp. 105–42, 127).

    Google Scholar 

  73. Lundström, T. (Arkiv Kemi 30 [1968] 115–27, 118–20).

    Google Scholar 

  74. Boller, H.; Rieger, W.; Nowotny, H. (Monatsh. Chem. 95 [1964] 1497–501).

    Article  CAS  Google Scholar 

  75. Kuz’ma, Yu. B.; Serebryakova, T. I.; Plakhina, A. M. (Zh. Neorg. Khim 12 [1967] 559–60;

    Google Scholar 

  76. Kuz’ma, Yu. B.; Serebryakova, T. I.; Plakhina, A. M. Russ. Inorg. Chem. [Engl. Transi.] 12 [1967] 288–9).

    Google Scholar 

  77. Peshev, P.; Bliznakov, G.; Leyarovska, L. (J. Less-Common Met. 13 [1967] 241–7).

    Article  CAS  Google Scholar 

  78. Woods, H. P.; Wawner, F. E. Jr.; Fox, B. G. (Science 151 [1966] 75).

    Article  CAS  Google Scholar 

  79. Moissan, H. (C. R. Hebd. Seances Acad. Sci. 123 [1896] 13–6).

    Google Scholar 

  80. Minkevich, A. N. (Metalloved. Term. Obrab. Met. 1961 No. 8, pp. 9–15; Met. Sci. Heat Treat. Met. [Engl. Transi.] 1961 No. 8, pp. 347–51).

    Google Scholar 

  81. Nowotny, H.; Haschke, H.; Benesovsky, F. (Monatsh. Chem. 98 [1967] 547–54).

    Article  CAS  Google Scholar 

  82. Kiessling, R. (Acta Chem. Scand. 4 [1950] 209–27).

    Article  CAS  Google Scholar 

  83. Seith, W. (Diffusion in Metallen, Springer, Berlin 1955, p. 66).

    Book  Google Scholar 

  84. Kaufman, L.; Uhrenius, B.; Birnie, D.; Taylor, K. (CALPHAD: Comput. Coupling Phase Diagrams Thermochem. 8 [1984] 25–66 from [80]).

    Article  CAS  Google Scholar 

  85. Rogl, P.; Schuster, J. C. (Phase Diagrams of Ternary Boron Nitride and Silicon Nitride Systems, ASM International, Materials Park, Ohio, 1992, pp. 117–20).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Jörn von Jouanne Elisabeth Koch Ernst Koch

Rights and permissions

Reprints and permissions

Copyright information

© 1993 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Jehn, H., Gmünd, S., Bär, G., Best, E., Koch, E. (1993). Reactions with Boron. In: von Jouanne, J., Koch, E., Koch, E. (eds) W Tungsten. Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th Edition, vol W / A-B / A / 5 / b. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-08684-1_7

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-08684-1_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-08686-5

  • Online ISBN: 978-3-662-08684-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics