Abstract
Neither the cyclic nor the acyclic isomers of N5H have been observed experimentally; only organic derivatives of cyclopentazadiene, c-N5H, are known, but their thermal stability is low. The acyclic isomers of N5H are supposed to consist of a double-bonded N2 unit with a hydrogen and an N3 substituent. Each of the (Z) and (E) isomers forms an s-cis or s-trans conformer depending on the spatial arrangement of the approximately linear N3 unit with respect to the N-N double bond. An ab initio SCF MO calculation at the STO-3G level showed that cyclopentazadiene is the most stable isomer of N5H, followed by the (E) s-trans isomer of acyclic N5H and the (Z) s-trans, the (E) s-cis, and the (Z) s-cis isomers. The decomposition to HN3 and N2 is exothermal for all isomers of N5H. A mutual conversion between the (Z) and (E) isomers is predicted not to occur [1].
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Haubold, R., Heinrich-Sterzel, C., Merlet, P., Ohms-Bredeman, U., Strametz, C., Wietelmann, A. (1993). Penta- and Polynitrogen Compounds. In: Koschel, D., Merlet, P., Wietelmann, A., Merlet, P. (eds) N Nitrogen. Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th Edition, vol N / 0-b / b / 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06336-1_4
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