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The System Boron-Bromine

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B Boron Compounds

Part of the book series: Gmelin Handbook of Inorganic Chemistry ((955,volume B / 1-20 / 1-4 / 3 / 4))

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Abstract

BBr can be detected spectroscopically when BBr3 is passed through a radiofrequency discharge in order to prepare B2Br4 [2]. For the reaction BBr3+BBr→B2Br4, the value of the standard Gibbs potential ΔGf° of B2Br4 is unknown; however, the highly positive value of ΔGf° of BBr (+195.4 kJ/mol) in conjunction with ΔGf° for BBr3 (-232.5 kJ/mol) ensures that AGf° of this reaction will be highly negative for any reasonable value of ΔGf° (B2Br4) [1]. In the discharge, an intensive A→X band system of BBr is observed in which the longest wavelength band is the (3,5), corresponding to a vibrational excitation energy of 43.7 kJ/mol [1]. The standard enthalpy of formation has been calculated to be ΔGf°(gas) = +234.3 kJ/mol and the bond order-dependent enthalpy term of the B-Br bond is given with E(B-Br) = 437.6 kJ/mol [2]. Thermochemical data obtained by a combination of tungsten transport measurements and theoretical estimates for BBr3 (in the gaseous state) are ΔH298 = 228 kJ/mol, S298 = 225 kJ/mol, and Cp,298 = 33 J/mol·K [3]. The dissociation energy has been calculated on the basis of molecular constants (from literature data) to be D = 4.4eV [4].

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Meller, A. (1988). The System Boron-Bromine. In: Buschbeck, KC., Niedenzu, K. (eds) B Boron Compounds. Gmelin Handbook of Inorganic Chemistry, vol B / 1-20 / 1-4 / 3 / 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-06138-1_2

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