Skip to main content

Polymers Formed from Self-Assembled Structures

  • Chapter
Soft Matter Physics
  • 775 Accesses

Abstract

Surfactant molecules are amphiphilic and associate together in aqueous solution to form various structures: micelles, microemulsions, vesicles, lyotropic liquid crystalline phases. In each case, their alkyl chains group together and their polar heads form a layer which separates them from the water. The laws governing this self-assembly involve subtle combinations of the two principles, order and mobility. Some fascinating illustrations are provided by the cell membrane in biological systems. In this case, order and mobility are related to the structure of functional units made up of lipids and proteins [6.10]. Such examples could only encourage chemists to carry out novel syntheses which would produce molecules capable of self-assembly.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

Bibliography

General articles

  1. Bader, H., Dorn, K., Hupfer, B., Ringsdorf, H. (1985) Advances in Polymer Science Vol. 64, Gordon, M. (Ed.). Springer, Berlin Heidelberg, 1–62

    Google Scholar 

  2. Barrall, E.M., Johnson, J.F. (1979) J. Macromol. Sci., Rev. Macromol. Chem. C 17 (1), 137

    Article  Google Scholar 

  3. Becher, P. (1984) Surfactants in Solution Vol. 3, Mittal, K.L., Lindman, B. (Eds.). Plenum, New York, 1925–1946

    Google Scholar 

  4. Candau, F., Ottewill, R.H. (eds.) (1990) An Introduction to Polymer Colloids, NATO ASI Series C 303. Kluwer, Dordrecht

    Google Scholar 

  5. Candau, F. (1992) Polymerisation in Organised Media, Paleos, C.M. (Ed.). Gordon and Breach, Philadelphia, 215–282

    Google Scholar 

  6. Fendler, J.H. (1984) Surfactants in Solution Vol. 3, Mittal, K.L., Lindman, B. (Eds.), Plenum, New York;

    Google Scholar 

  7. Fendler, J.H., Tundo, P. (1984) Accounts of Chem. Res. 17, 3

    Article  CAS  Google Scholar 

  8. Fendler, J.H. (1984) Science 223, 888

    Article  CAS  Google Scholar 

  9. Odian, G. (Ed.) (1991) Principles of Polymerisation, 3rd edn. Wiley, New York

    Google Scholar 

  10. Paleos, C.M. (1992) Polymerisation in Organised Media, Paleos, C.M. (Ed.), Gordon and Breach, Philadelphia, 183–214

    Google Scholar 

  11. Ringsdorf, H., Schlarb, B., Venzmer, J. (1988) Angew. Chemie 27, 1. Int. Ed. Eng., 113–158

    Google Scholar 

More specialised articles

  1. Anderson, D.M., Ström, P. (1989) Polymer Association Structures: Microemulsions and Liquid Crystals, El Nokaly, M. (Ed.). ACS Symp. Series 384, Washington DC, 204–224

    Google Scholar 

  2. Anderson, D.M., Ström, P. (1991) Physica A 151, 176

    Google Scholar 

  3. Beerbower, A., Hill, M.W. (1971) McCutcheon’s Detergent and Emulsifier Annual. Allured Ridgewood, New Jersey, 223–235

    Google Scholar 

  4. Bug, A.L.R., Safran, S.A., Grest, G.S., Webman, I. (1985) Phys. Rev. Lett. 55, 1896

    Article  CAS  Google Scholar 

  5. Candau, F. (1987) J. Chem. Phys. 84, 1095

    CAS  Google Scholar 

  6. Carver, M.T., Hirsch, E., Wittmann, J.C., Fitch, R.M., Candau, F. (1989) J. Phys. Chem. 93, 4867

    Article  CAS  Google Scholar 

  7. Cochin, D. (1991) PhD Thesis, Université Louis Pasteur, Paris;

    Google Scholar 

  8. Cochin, D., Zana, R., Candau, F. (1993) Polym. Int. 30, 491

    Article  CAS  Google Scholar 

  9. Daubresse, C. (1993) PhD Thesis, Université de Liège, Belgium (and articles to be published )

    Google Scholar 

  10. Herz, J., Reiss-Husson, F., Rempp, P., Luzzati, V. (1964) J. Polym. Sci. Part C 4, 1275

    Google Scholar 

  11. Holtzscherer, C., Candau, F., Ottewill, R. (1990) Prog. Colloid Polym. Sci. 80, 86

    Google Scholar 

  12. Laversanne, R. (1992) Macromolecules 25, 489

    Article  CAS  Google Scholar 

  13. Ruckenstein, E., Chi, J.C. (1975) J. Chem. Soc. Faraday Trans. II 71, 1690

    Article  CAS  Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1999 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Candau, F. (1999). Polymers Formed from Self-Assembled Structures. In: Daoud, M., Williams, C.E. (eds) Soft Matter Physics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03845-1_6

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-03845-1_6

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-03847-5

  • Online ISBN: 978-3-662-03845-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics