Abstract
Surfactant molecules are amphiphilic and associate together in aqueous solution to form various structures: micelles, microemulsions, vesicles, lyotropic liquid crystalline phases. In each case, their alkyl chains group together and their polar heads form a layer which separates them from the water. The laws governing this self-assembly involve subtle combinations of the two principles, order and mobility. Some fascinating illustrations are provided by the cell membrane in biological systems. In this case, order and mobility are related to the structure of functional units made up of lipids and proteins [6.10]. Such examples could only encourage chemists to carry out novel syntheses which would produce molecules capable of self-assembly.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
Bibliography
General articles
Bader, H., Dorn, K., Hupfer, B., Ringsdorf, H. (1985) Advances in Polymer Science Vol. 64, Gordon, M. (Ed.). Springer, Berlin Heidelberg, 1–62
Barrall, E.M., Johnson, J.F. (1979) J. Macromol. Sci., Rev. Macromol. Chem. C 17 (1), 137
Becher, P. (1984) Surfactants in Solution Vol. 3, Mittal, K.L., Lindman, B. (Eds.). Plenum, New York, 1925–1946
Candau, F., Ottewill, R.H. (eds.) (1990) An Introduction to Polymer Colloids, NATO ASI Series C 303. Kluwer, Dordrecht
Candau, F. (1992) Polymerisation in Organised Media, Paleos, C.M. (Ed.). Gordon and Breach, Philadelphia, 215–282
Fendler, J.H. (1984) Surfactants in Solution Vol. 3, Mittal, K.L., Lindman, B. (Eds.), Plenum, New York;
Fendler, J.H., Tundo, P. (1984) Accounts of Chem. Res. 17, 3
Fendler, J.H. (1984) Science 223, 888
Odian, G. (Ed.) (1991) Principles of Polymerisation, 3rd edn. Wiley, New York
Paleos, C.M. (1992) Polymerisation in Organised Media, Paleos, C.M. (Ed.), Gordon and Breach, Philadelphia, 183–214
Ringsdorf, H., Schlarb, B., Venzmer, J. (1988) Angew. Chemie 27, 1. Int. Ed. Eng., 113–158
More specialised articles
Anderson, D.M., Ström, P. (1989) Polymer Association Structures: Microemulsions and Liquid Crystals, El Nokaly, M. (Ed.). ACS Symp. Series 384, Washington DC, 204–224
Anderson, D.M., Ström, P. (1991) Physica A 151, 176
Beerbower, A., Hill, M.W. (1971) McCutcheon’s Detergent and Emulsifier Annual. Allured Ridgewood, New Jersey, 223–235
Bug, A.L.R., Safran, S.A., Grest, G.S., Webman, I. (1985) Phys. Rev. Lett. 55, 1896
Candau, F. (1987) J. Chem. Phys. 84, 1095
Carver, M.T., Hirsch, E., Wittmann, J.C., Fitch, R.M., Candau, F. (1989) J. Phys. Chem. 93, 4867
Cochin, D. (1991) PhD Thesis, Université Louis Pasteur, Paris;
Cochin, D., Zana, R., Candau, F. (1993) Polym. Int. 30, 491
Daubresse, C. (1993) PhD Thesis, Université de Liège, Belgium (and articles to be published )
Herz, J., Reiss-Husson, F., Rempp, P., Luzzati, V. (1964) J. Polym. Sci. Part C 4, 1275
Holtzscherer, C., Candau, F., Ottewill, R. (1990) Prog. Colloid Polym. Sci. 80, 86
Laversanne, R. (1992) Macromolecules 25, 489
Ruckenstein, E., Chi, J.C. (1975) J. Chem. Soc. Faraday Trans. II 71, 1690
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Candau, F. (1999). Polymers Formed from Self-Assembled Structures. In: Daoud, M., Williams, C.E. (eds) Soft Matter Physics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-03845-1_6
Download citation
DOI: https://doi.org/10.1007/978-3-662-03845-1_6
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-03847-5
Online ISBN: 978-3-662-03845-1
eBook Packages: Springer Book Archive