Abstract
We have several times encountered ET phenomena caused by the action of electricity or light upon chemical species, and shall now treat these areas in more detail. As pointed out in Chapter I, electrochemistry is the science of ET, as has been recognized for a long time, whereas the all-pervasive nature of photochemical ET has been generally appreciated only during the last 10–15 years. Also, the ET character of the converse process, emission of light from thermal reactions or chemiluminescence, has only been recognized recently.
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References
For general treatises on electrochemistry, see: Bard, A. J., Faulkner, L.: Elec-trochemical Methods, New York, Wiley 1980; Bockris, J. O’M., Reddy, A. K. N.: Modern Electrochemistry, Vol. 1 and 2, New York, Plenum 1970.
Damaskin, B. B., Petrii, O. A., Batrakov, V. V.: Adsorption of Organic Compounds, New York, Plenum 1971; Gileadi, E. et al.: Electrosorption (ed.) Gileadi, E., New York, Plenum Press 1967.
Hale, J. M.: The Rates of Reactions Involving Only Electron Transfer at Metal Electrodes. In: Reactions of Molecles at Electrodes (ed.) Hush, N. S., London, Wiley 1971.
Soriaga, M. P., White, J. H., Song, D., Hubbard, A. T.: J. Phys. Chem. 88, 2284 (1984) and previous papers of this series.
Lipkowski, J., Buess-Herman, C., Lambert, J. P., Gierst, L.: J. Electroanal. Chem. 202, 169 (1986).
Streitwieser, A.: Molecular Orbital Theory for Organic Chemists, New York, Wiley 1961.
Klingler, R. J., Kochi, J. K.: J. Am. Chem. Soc. 104, 4186 (1982).
Marcus, R. A.: J. Chem. Phys. 43, 679 (1965).
Eberson, L., Nyberg, K.: Adv. Phys. Org. Chem. 12, 1 (1976).
Cannon, R. D.: Electron Transfer Reactions, London, Butterworths 1980.
Klingler, R. J., Kochi, J. K.: J. Phys. Chem. 85, 1731 (1981); reorganization energies of alkylmetals were obtained from Eberson, L.: Adv. Phys. Org. Chem. 18, 79 (1982).
Klingler, R. J., Kochi, J. K.: J. Am. Chem. Soc. 102, 4790 (1980).
Osa, T., Yildiz, A., Kuwana, T.: J. Am. Chem. Soc.: J. Am. Chem. Soc. 91, 3994 (1969).
Fremery, M., Höver, H., Schwarzlose, G.: Chemie-Ing.-Techn. 46, 635 (1974); Clarke, J. S., Ehigamusoe, R. E., Kuhn, A. T.: J. Electroanal. Chem. 70, 333 (1976).
Jönsson, L.: Acta. Chem. Scand. B34, 697 (1980).
van Gent, J., Wismeijer, A. A., Peters Rit, A. W. P. G., van Bekkum, H.: Tetrahedron Lett. 27, 1059 (1986).
For a comprehensive treatise of this topic, see: Baizer, M. M. : Organic Electrochemistry (ed.) Baizer, M. M., Lund, H., New York, Dekker 19832.
Wendt, H.: Electrochim. Acta 29, 1513 (1984); Köster, K., Riemenschneider, P., Wendt, H.: Israel J. Chem. 18, 141 (1979).
Simonet, J., Le Guillanton, G.: Bull. Soc. Chim. Fr. 1985, 180.
Meyer, T. J.: J. Electrochem. Soc. 131, 221C (1984).
Murray, R. W.: Acc. Chem. Res. 13, 135 (1980).
Baizer, M. M.: J. Electrochem. Soc. Ill, 215 (1964); Current Contents 26, 16, March 24 (1986).
Tallec, A.: Bull. Soc. Chim. Fr. 1985, 743.
Scheffold, R., Dike, M., Dike S., Herold, T., Walder, L.: J. Am. Chem. Soc. 102, 3642 (1980).
Margel, S., Anson, F. C.: J. Electrochem. Soc. 125, 1232 (1978).
Gosden, C., Pletcher, D.: J. Organometal. Chem. 186, 401 (1980).
Hawecker, J., Lehn, J.-M., Ziessel, R.: J. Chem. Soc. Chem. Comm. 1984, 328.
Moyer, B. A., Thompson, M. S., Meyer, T. J.: J. Am. Chem. Soc. 102, 2310 (1980).
Ali, S. Z., Trojanek, A., Kalvoda, R.: J. Electroanal. Chem. 52, 85 (1974).
Wendt, H., Schneider, H.: J. Appl. Electrochem. 16, 134 (1986).
Grosse Brinkhaus, K.-H., Steckhan, E.: Tetrahedron 42, 553 (1986).
Beck, F., Schulz, H.: Electrochim. Acta 29, 1569 (1984).
Collman, J. P.: Marrocco, M., Denisevich, P., Koval, C., Anson, F. C.: J. Elec- troanal. Chem. 101, 111 (1979).
Jägfeldt, H., Kuwana, T., Johansson, G.: J. Am. Chem. Soc. 105, 1805 (1983).
Gorton, L., Torstensson, A., Jägfeldt, H., Johansson, G.: J. Electroanal. Chem. 161, 103 (1984).
Van De Mark, M. R., Miller, L. L.: J. Am. Chem. Soc. 100, 3223 (1978).
Turro, N. J., Grätzel, M., Braun, A. M.: Angew. Chem. 19, 675 (1980).
Chibisov, A. K.: Russ. Chem. Rev. 50, 1169 (1981).
Beecroft, R. A., Davidson, R. S., Goodwin, D., Pratt, J. E.: Pure Appl. Chem. 54, 1605 (1982).
Juillard, M., Chanon, M.: Chem. Rev. 83, 425 (1983).
Energy Sources through Photochemistry and Catalysis (ed.) Grätzel, M., New York, Academic Press 1983.
Mariano, P. S., Stavinoha, J. L.: Synthetic Aspects of Photochemical Electron Transfer. In: Synthetic Organic Photochemistry (ed.) Horspool, W. M., New York, Plenum Press 1984.
Tolbert, L. M.: The Photochemistry of Organic Anions. In: Organic Photochemistry, Vol. 6 (ed.) Padwa, A., New York, Dekker 1983.
Mattes, S. L., Farid, S.: Photochemical Electron-Transfer Reactions of Olefins and Related Compounds. In: Organic Photochemistry, Vol. 6 (ed.) Padwa, A., New York, Dekker 1983.
Fox, M. A.: Adv. Photochem. 13, 238 (1986).
Kavarnos, G. J., Turro, N. J.: Chem. Rev. 86, 401 (1986).
Juillard, M., Chanon, M.: Chem. Britain 1982, 558.
Rehm, D., Weiler, A.: Ber. Bunsenges. Phys. Chem. 73, 834 (1969); Israel J. Chem. 8, 259 (1970).
Eberson, L.: Adv. Phys. Org. Chem. 18, 79 (1982).
Ballardini, R., Varani, G., Indelli, M. T., Scandola, F., Balzani, V.: J. Am. Chem. Soc. 100, 7219 (1978).
Eriksen, J., Lund, H., Nyvad, A. I.: Acta Chem. Scand. B37, 459 (1983); Erik- sen, J., Jörgensen, K. A., Linderberg, J., Lund, H.: J. Am. Chem. Soc. 106, 5083 (1984).
Ambroz, H. B., Butter, K. R., Kemp, T. J.: Faraday Discuss. Chem. Soc. 78, 107 (1984).
Fukuzumi, S., Wong, C. L., Kochi, J. K.: J. Am. Chem. Soc. 102, 2141 (1980).
Gordon, G., Taube, H.: J. Inorg. Nucl. Chem. 160, 272 (1961).
Fukuzumi, S., Kuroda, S., Tanaka, T.: J. Chem. Soc. Perkin Trans. 2 1986, 25.
Treinin, A., Hayon, E.: J. Am. Chem. Soc. 98, 3884 (1976).
Watkins, A. R.: J. Phys. Chem. 77, 1207 (1973); 78, 1885, 2555 (1974).
Martins, L. J. A., Kemp, T. J.: J. Chem. Soc. Faraday Trans. 1 80, 2509 (1984); Abdullah, K. A., Kemp, T. J.: J. Photochem. 28, 61 (1985); J. Chem. Soc. Perkin Trans. 2 1985, 1279.
Cornelisse, J., Havinga, E.: Chem. Rev. 75, 353 (1975).
Gassmann, P. G., Olson, K. D., Walter, L., Yamaguchi, R.: J. Am. Chem. Soc. 103, mil (i98i).
Beugelmans, R., LeGoff, M. T., Pusset, J., Roussi, G.: Tetrahedron Lett. 1976, 2305; Beugelmans, R.: Ginsburg, H., Lecas, A., LeGoff, M. T., Roussi, G.: Tetrahedron Lett. 1978, 3271; Mizuno, K., Pac, C., Sakurai, H.: J. Chem. Soc. Chem. Comm. 1975, 553.
Nilsson, S.: Acta Chem. Scand. 27, 329 (1973).
Cristol, S. J., Bindel, T. H.: Photosolvolyses and Attendant Photoreactions Involving Carbocations. In: Organic Photochemistry, Vol. 6 (ed.) Padwa, A., New York, Dekker 1983.
Cristol, S. J., Seapy, D. G., Aeling, E. O.: J. Am. Chem. Soc. 105, 7337 (1983); Cristol, S. J., Bindel, T. H., Hoffmann, D., Aeling, E. O.: J. Org. Chem. 49, 2368 (1984); Cristol, S. J., Aeling, E. O.: J. Org. Chem. 50, 2698 (1985).
Simon, J. D., Peters, K. S.: Acc. Chem. Res. 17, 277 (1984).
Hilinski, E. F., Masnovi, J. M., Kochi, J. K., Rentzepis, P. M.: J. Am. Chem. Soc. 106, 8071 (1984).
Masnovi, J. M., Kochi, J. K.: J. Org. Chem. 50, 5245 (1985).
Masnovi, J. M., Kochi, J. K., Hilinski, E. F., Rentzepis, P. M.: J. Am. Chem. Soc. 108, 1126 (1986).
Masnovi, J. M., Kochi, J. K.: J. Am. Chem. Soc. 107, 7880 (1985).
Fox, M. A.: Acc. Chem. Res. 16, 314 (1983).
Schuster, G. B., Schmidt, S. P.: Adv. Phys. Org. Chem. 18, 187 (1982).
Faulkner, L. R.: Int. Rev. Sci.: Phys. Chem. Ser. 2 9, 213 (1976).
Porter, J. E., Schuster, G. B.: J. Org. Chem. 50, 4068 (1985).
Becker, W. G., Seung, H. S., Bard, A. J.: J. Electroanal. Chem. 167, 127 (1984).
Prägst, F., Kaltofen, B.: Electrochim. Acta 27, 1181 (1982).
Eberson, L., Barry, J. E., Finkelstein, M., Moore, W. M., Ross, S. D.: Acta Chem. Scand. B39, 249 (1985).
Mussell, R. D., Nocera, D. G.: Polyhedron 5, 47 (1986).
Wendt, H.: J. Mol. Catal. 38, 89 (1986).
Steckhan, E.: Angew. Chem. 98, 681 (1986).
Mattes, S. L., Farid, S.: J. Am. Chem. Soc. 108, 7356 (1986).
Lewis, F. D., Petisce, J. R.: Tetrahedron 42, 6207 (1986); Lewis, F. D.: Acc. Chem. Res. 19, 401 (1986).
Cristol, S. J., Dickenson, W. A.: J. Org. Chem. 51, 3625 (1986).
Morrison, H., Muthurama, K., Pandey, G., Severance, D., Bigot, B.: J. Org. Chem. 51, 3358 (1986).
Cristol, S. J., Aeling, E. O., Heng, R.: J. Am. Chem. Soc. 109, 830 (1987).
Sankararaman, S., Kochi, J. K.: Reel. Trav. Chim. Pays-Bas 105, 278 (1986).
Masnovi, J. M., Kochi, J. K.: Reel. Trav. Chim. Pays-Bas 105, 286 (1986).
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Eberson, L. (1987). Electricity and Light Promoted ET. In: Electron Transfer Reactions in Organic Chemistry. Reactivity and Structure Concepts in Organic Chemistry, vol 25. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72544-9_9
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DOI: https://doi.org/10.1007/978-3-642-72544-9_9
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