Abstract
In the preceding chapters we have dealt with single quantum transitions in the sense that a single “quantum of energy” hω jk is necessary and sufficient to create a transition (superposition of states) between the two eigenstates E j and E k of the systems Hamiltonian. In NMR we usually employ large magnetic fields B 0 which ensures that the magnetic quantum number m is a good quantum number. Magnetic dipole transitions Δm = l occur under the action of a radio-frequency field B 1. In NMR therefore an rc-quantum transition usually involves Δm = n.
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Mehring, M. (1983). Multiple-Quantum NMR Spectroscopy. In: Principles of High Resolution NMR in Solids. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-68756-3_6
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