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Nuclear Magnetic Resonance and Relaxation of Molecules Adsorbed on Solids

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NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte

Abstract

Nuclear magnetic resonance (NMR) signals can only be observed from a sample which contains nuclei with a nonvanishing magnetic moment (cf. Table 1.1, first column). The resonance frequency is proportional to the magnetic field H 0 applied to the sample and different for nuclei of different kind (cf. Table 1.1, second column). The intensity of the NMR signal for equal numbers of nuclei at constant field H 0 also depends on the kind of nucleus and is maximum for protons (cf. Table 1.1, third column).

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References

  • Abragam, A.: The principles of nuclear magnetism. Oxford: 1961.

    Google Scholar 

  • Andrew, E.R., Bersohn, R.: Nuclear magnetic resonance line shape for a triangular configuration of nuclei. J. Chem. Phys. 18, 159–161 (1950).

    Article  CAS  Google Scholar 

  • Andrew, E.R., Eades, R.G.: A nuclear magnetic resonance investigation of solid cyclohexane. Proc. Roy. Soc. London A 216, 398–412 (1953).

    Article  CAS  Google Scholar 

  • Andrew, E.R., Eades, R.G.: A nuclear magnetic resonance investigation of three solid benzenes. Proc. Roy. Soc. London A 218, 537–552 (1953).

    Article  CAS  Google Scholar 

  • Andrew, E.R., Brookeman,J.R.: NMR spectra of reorienting nuclear pairs in solids: Application to conformational changes. J. Magn. Res. 2, 259–266 (1970).

    CAS  Google Scholar 

  • Aston, J. G., Bernard, H.W.: The structure of the nuclear magnetic resonance lines for methane adsorbed on rutile. J. Am. Chem. Soc. 85, 1573–1575 (1963).

    Article  CAS  Google Scholar 

  • Ayant, Y., Ducros, P., Paré, X., Soutif, M.: Résonance des deutons de l’eau lourde adsorbée dans une zéolite. Compt. Rend. 252, 550–552 (1961). R: Concerning theory compare (Ayant 1962, 1963, 1964).

    CAS  Google Scholar 

  • Ayant, Y., Sur la largeur de la raie résonance magnétique nucléaire de l’eau zéolitique. Compt. Rend. 255, 3400–3402 (1962).

    CAS  Google Scholar 

  • Ayant, Y., Une théorie des largeurs de raie dans les transitions a deux quanta. J. Phys. 24, 225–232 (1963).

    Article  CAS  Google Scholar 

  • Ayant, Y., Beloritzy, E., Paré, X., Rosset, J.: Sur la largeur des raies de résonance magnétique nucléaire des protons de l’eau dans les zéolites. J. Phys. 25, 696–700 (1964).

    Article  CAS  Google Scholar 

  • Bakaev, V.A., Dubinin, M.M.: NMR signal of lithium in dehydrated synthetic zeolite. (in Russian). Izv. Akad. Nauk. Ser. Chini. H. 10, 1869 (1966).

    Google Scholar 

  • Barnaal, D.E., Lowe, I.J.: Experimental free-induction-decay shapes and theoretical second moments for hydrogen in hexagonal ice. J. Chem. Phys. 46, 4800–4809 (1967).

    Article  CAS  Google Scholar 

  • Barnes, G.T.: Phase transitions in water sorbed on silica gel. Z. Angew. Math. Phys. 13, 533–544 (1962).

    Article  CAS  Google Scholar 

  • Barnes, G.T.: Phase transitions in water sorbed on ice forming nuclei. Z. Angew. Math. Phys. 14, 510–518 (1963).

    Article  CAS  Google Scholar 

  • Beckert, D., Pfeifer, H.: Zur Theorie der kernmagnetischen Relaxation in Zweiphasensystemen. Ann. Phys. (Leipzig) 16, 262–268 (1965).

    CAS  Google Scholar 

  • Beckert, D., Pfeifer, H.: The measurement of the diffusion coefficient of methane adsorbed on silica gel by NMR. Phys. Letters 25 A, 502–503 (1967).

    Google Scholar 

  • Beckert, D., Pfeifer, H.: Theorie der intermolekularen kernmagnetischen Relaxation adsorbierter Moleküle. Ann. Phys. (Leipzig) 20, 220–229 (1967).

    CAS  Google Scholar 

  • Beckert, D., Pfeifer, H.: Theorie der intermolekularen kernmagnetischen Relaxation adsorbierter Moleküle. Ann. Phys. (Leipzig) 23, 98–103 (1969).

    CAS  Google Scholar 

  • Beckert, D., Pfeifer, H.: Protonenspinrelaxation von adsorbiertem Methan. I. Relaxationsanalyse. Z. Phys. Chem. (Leipzig) 246, 113–132 (1971).

    CAS  Google Scholar 

  • Beckert, D., Pfeifer, H.: Protonenspinrelaxation von adsorbiertem Methan. II. Isotopieeffekt. Z. Phys. Chemie (Leipzig) 246, 155–160 (1971).

    CAS  Google Scholar 

  • Belwe, R.: Diplomarbeit, Sektion Physik der Karl-Marx-Universität Leipzig (1968).

    Google Scholar 

  • Benoit, H., Conard, J., Gradsztajn, S.: Résonance magnétique nucléaire: Étude en haute résolution de liquides adsorbés sur des carbones a grande surface. Origine de la larger des raies. 15. Colloque Ampère, Grenoble (1968).

    Google Scholar 

  • Benson, G.C., Balk, P.: Estimation of the effect of surface on the dipolar broadening of magnetic resonance lines in crystals. Can. J. Phys. 39, 1071–1073 (1961).

    Article  CAS  Google Scholar 

  • Bermudez, V.M.: A proton nuclear magnetic resonance technique for determining the surface hydroxyl content of hydrated silica gel. J. Phys. Chem. 74, 4160–4161 (1970). R: The method depends on the questionable assumption that T2S (transverse relaxation time of the hydroxyl protons) is a constant for the adsorbents to be studied.

    Article  CAS  Google Scholar 

  • Berson, R.: Nuclear resonance spectrum of a system of four nuclei. Phys. Rev. 87, 226 (1952).

    Google Scholar 

  • Berson, R., Gutowsky, H.S.: Proton magnetic resonance in an ammonium chloride single crystal. J. Chem. Phys. 22, 651–658 (1954).

    Article  Google Scholar 

  • Bienkiewicz, K.J., Florkowski, Z., Hennel, J.W., Lalowicz, Z.: Die Untersuchungen des Kollagen-Wasser-Systems mit der NMR-Methode. Leder 21, 5–11 (1970).

    CAS  Google Scholar 

  • Bittner, H., Kerber, W.: Untersuchungen an zeolithischen Heptagermanaten mit Hilfe der Kernresonanzmethode. Monatsh. Chem. 100, 427–438 (1969).

    Article  CAS  Google Scholar 

  • Bittner, H., Hauser, E.: Kernresonanzuntersuchungen an zeolithischen Heptagermanaten, 2. Mitt. Monatsh. Chem. 101, 1471–1482 (1970).

    Article  CAS  Google Scholar 

  • Blicharski, J.S.: Spin rotational magnetic relaxation for nonlinear molecules. Acta Physica Polon. 24, 817–821 (1963).

    Google Scholar 

  • Blicharski, J.S.: Interference effect in nuclear magnetic relaxation. Phys. Letters 24A, 608–610 (1967).

    Google Scholar 

  • Blicharski, J.S.: Nuclear magnetic relaxation by spin-rotation interaction for nonlinear molecules. II. Physica 39, 161–164 (1968).

    Article  Google Scholar 

  • Blicharski, J.S., Schneider, H.: Kernmagnetische Relaxation von Mehrspinsystemen mit ungleichen Kernen (I). Ann. Phys. (Leipzig) 22, 306–318 (1969).

    Google Scholar 

  • Blicharski, J.S.: Interference effect in nuclear magnetic relaxation. II. Acta Physica Polon. 36, 211–218 (1969).

    CAS  Google Scholar 

  • Blicharski, J.S.: Interference effect in nuclear magnetic relaxation. III. Acta Physica Polon. A 38, 19–24 (1970).

    CAS  Google Scholar 

  • Blicharski, J.S.: Interference effect in nuclear magnetic relaxation for three-spin system. IV. Acta Physica Polon. A 38, 25–32 (1970).

    CAS  Google Scholar 

  • Blicharski, J.S., Nosel, W., Schneider, H.: Der Interferenzeffekt in der magnetischen Kernrelaxation für Vierspin-Systeme. V. Ann. Phys. (Leipzig) 27, 17–32 (1971).

    Article  CAS  Google Scholar 

  • Bloch, F.: Nuclear relaxation in gases by surface catalysis. Phys. Rev. 83, 1062–1063 (1951).

    Article  CAS  Google Scholar 

  • Boddenberg, B.: Diffusionskoeffizienten und kernmagnetische Relaxationszeiten adsorbierter Fremdmoleküle an Festkörperoberflächen. Dissertation, Hannover (1967).

    Google Scholar 

  • Boddenberg, B., Haul, R., Oppermann, G.: Spinecho-Messungen des Diffusionskoeffizienten von Benzol in Aerosil-Preßlingen. Naturwissenschaften 56, 635–636 (1969).

    Article  CAS  Google Scholar 

  • Bonera, G., Rigamonti,A.: Intra- und intermolecular contributions to the proton spin-lattice relaxation in liquids. J. Chem. Phys. 42, 171–174 (1965).

    Article  CAS  Google Scholar 

  • Borel, J.-P., Cornaz, P.: Observation de l’effet Overhauser dans un gaz en presence d’une substance paramagnétique solide. Compt. Rend. 247, 1988–1990 (1959).

    Google Scholar 

  • Borsutzkij, S.R., Tulbovič, D.I.: Proton magnetic resonance of benzene and cyclohexane adsorbed on silica gel. I. Temperature dependence of benzene and cyclohexane adsorbed on aerosil. (in Russian). Žurn. Fiz. Chim. 43, 1682–1685 (1969).

    Google Scholar 

  • Boss, B.D., Stejskal, E.O.: Anisotropic diffusion in hydrated vermiculite. J. Chem. Phys. 43, 1068–1069 (1965).

    Article  CAS  Google Scholar 

  • Boss, B.D., Stejskal, E.O.: Restricted, anisotropic diffusion and anisotropic nuclear spin relaxation of protons in hydrated vermiculite crystals. J. Colloid Interf. Sci. 26, 271–278 (1968).

    Article  CAS  Google Scholar 

  • Bradbury, J.H., Forbes, W.F., Leeder, J.D., West, G.W.: Proton magnetic resonance study of sorption of water and alcohols by wool. J. Polymer Sci. A, 2, 3191–3196 (1964).

    Google Scholar 

  • Brechunec, A.G., Mank, V.V., Ovčarenko, F.D., Sujunova, Z.E., Tarasevič, Ju.I., Šapinskaja, L.M., Šulepov, Ju.V.: The state of interlayer water and exchangeable lithium cations in vermiculite as investigated by the NMR method (in Russian). Dokl. Akad. Nauk SSSR 192, 586–589 (1970).

    Google Scholar 

  • Brechunec, A.G., Mank, V.V., Ovčarenko, F.D., Sujunova, Z.E., Tarasevič, Ju.I.: The state of interlayer water and exchangeable lithium cations in montmorillonite as investigated by the NMR method (in Russian). Teoriya i Eksp. Chim. 6, 523–529 (1970).

    Google Scholar 

  • Brechunec, A.G., Mank, V.V., Ovčarenko, F.D., Piontkovskaja, M.A., Denisenko,G.I.: An investigation of the state of water and of lithium exchange in LiNaA-zeolites by the NMR method (in Russian). Teoriya Eksp. Chim. 7, 125–129 (1971).

    Google Scholar 

  • Brey, W.S., Lawson, K.D.: Nuclear magnetic resonance studies of adsorption on thorium oxide. J. Phys. Chem. 68, 1474–1481 (1964).

    Article  CAS  Google Scholar 

  • Brey, W.S., Evans, T.E., Hitzrot, L.H.: Nuclear magnetic relaxation times of water sorbed by proteins. Lysozyme and serum albumin. J. Colloid Interf. Sci. 26, 306–316 (1968).

    Article  CAS  Google Scholar 

  • Brown, R.J.S., Fatt, J.: Measurements of fractional wettability of oilfield rocks by the NMR method. Petroleum Transactions 207, 262–264 (1956).

    CAS  Google Scholar 

  • Brown, R.J.S.: Field dependence of proton relaxation in water near surfaces. Bull. Am. Phys. Soc. 3, Jan. 29, 23 (1958).

    Google Scholar 

  • Brown, R.J.S., Gutowsky, H.S., Shimomura, A.: Nuclear spin relaxation in liquid CHFCl2. J. Chem. Phys. 38, 76–86 (1963).

    Article  CAS  Google Scholar 

  • Buckingham, A.D., McLauchlan, K.A.: High resolution nuclear magnetic resonance in partially oriented molecules. In: Progress in nuclear magnetic resonance spectroscopy Vol. 2, p. 63–109. Oxford: Pergamon Press 1967.

    Google Scholar 

  • Burke, T.E., Chan, S.L.: Nuclear spin relaxation in the presence of internal rotation. J. Magnet. Res. 2, 120–140 (1970).

    CAS  Google Scholar 

  • Bylina, E.A., Beloraj, Ja.L.: Wettability and nuclear magnetic relaxation data of some disperse materials (in Russian). Žurn. Fiz. Chem. 42, 2138–2140 (1968).

    CAS  Google Scholar 

  • McCall, D.W., Hamming, R.W.: Acta Cryst. 12, 81 (1959).

    Article  CAS  Google Scholar 

  • Careri, G., Santini, M.: Nuclear magnetic properties of adsorbed He3. Phys. Letters 4, 61–62 (1963).

    Article  CAS  Google Scholar 

  • Careri, G.,Giura, M., Santini, M.: Further measurements on the nuclear magnetic properties of adsorbed He3. Phys. Letters 5, 102 (1963).

    Article  CAS  Google Scholar 

  • Careri, G., Santini, M., Signorelli, G.: Nuclear magnetic susceptibility of adsorbed 3He. In: Proc. 9th Internat. Conf. Low Temp. Physics p. 364–365. New York: Plenum Press 1965.

    Google Scholar 

  • Casabella, P.A.: Determination of nuclear quadrupole coupling constants from nuclear magnetic resonances in polycrystalline solids. J. Chem. Phys. 40, 149–152 (1964).

    Article  CAS  Google Scholar 

  • Charvolin, J., Rigny, P.: Mesure du temps de relaxation nucléaire transversal des deuterons de l’eau lourde sur une surface. Compt. Rend. 269 B, 224–227 (1969).

    Google Scholar 

  • Chelouche, M., Cohen-Addad, J.P., Ducros, P.: Relaxation des protons des molecules d’eau en présence d’ions paramagnétiques dans une zéolite synthétique. In: Proc. 13th Coll. Ampère, p. 411–413. Amsterdam: North Holland 1965.

    Google Scholar 

  • Chutsishvili, G. R.: Spin diffusion and nuclear magnetic relaxation in crystals containing magnetic centres (in Russian). Usp. Fiz. Nauk. 96, 441–466 (1968).

    Google Scholar 

  • Clifford, J., Sheard, B.: Nuclear magnetic resonance investigation of the state of water in human hair. Biopolymers 4, 1057–1065 (1966).

    Article  CAS  Google Scholar 

  • Clifford, J., Lecchini, S.M.A.: The state of liquid water near solid interfaces. In: S.C.J. Monograph 25 “Wetting”, p. 174–195 (1967).

    Google Scholar 

  • Clough, S., McDonald, I.R.: Nuclear magnetic resonance spin-spin relaxation. Proc. Phys. Soc. 86, 833–845 (1965).

    Article  CAS  Google Scholar 

  • Cobb, Th.B., Johnson, Ch.S.: Magnetic resonance line shapes in solids: The rotating three spin group. J. Chem. Phys. 52, 6224–6231 (1970).

    Article  CAS  Google Scholar 

  • Cohen-Addad, J.P., Chelouche, M.: Étude par le r.m.n., entre ‒30°C et +20°C du mouvement de rotation des molécules d’eau adsorbées par l’edingtonite naturelle. J. Physique (Paris) 27, 570–578 (1966).

    Article  CAS  Google Scholar 

  • Cohen-Addad, J.P., Farges, J.P.: Étude par la r.m.n., au-dessous de +20° C des mouvements des molécules d’eau adsorbées par les zéolites synthétiques 4A et 13X. J. Physique (Paris) 27, 739–747 (1966). R: The influence of paramagnetic impurities must be taken into account cf. (Resing 1969), (Deininger 1969, 1970). Contrary results concerning the coverage dependence and a difference between 4A and 5A/water were observed in later work (Pfeifer, 1967), (Deininger, 1969, 1970).

    Article  CAS  Google Scholar 

  • Conrad, M.J.: Étude par résonance magnétique nucléaire de gaz hydrogénés adsorbés sur un charbon. Compt. Rend. 259, 1107–1110 (1964). R: adsorbate = methane.

    Google Scholar 

  • Conard, J., Gradsztajn, S., Vivien, D.: High resolution NMR of adsorbed polar molecules like formic acid or methylalcohol. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p. 166–170 (1969).

    Google Scholar 

  • Conard, J.: Utilisation de la résonance magnétique nucléaire pour l’étude des surfaces solides. Bull. Soc. Chim. France 3290–3296 (1970).

    Google Scholar 

  • Conway, T. F., Smith, R. J.: Magnetic resonance determines moisture. Electronics, engineering edition — February 28, 51–53 (1958).

    Google Scholar 

  • Cornaz, P.: Relaxation nucléaire de l’hélium 3 gazeux a la surface du verre pyrex. Phys. Letters 7, 123–124 (1963).

    Article  CAS  Google Scholar 

  • Cornaz, P.: Relaxation magnétique nucléaire par contact avec des surfaces solides. Helv. Phys. Acta 38, 841–859 (1965). R: adsorbate = methane and 3He.

    CAS  Google Scholar 

  • Crosnier, Y., Gabillard, R., Citerne, J.: Étude de l’influence des dimensions des grains d’un milieu poreux sur la relaxation des spins nucléaires d’un liquide imprégnant ce milieu, en champ directeur faible. Compt. Rend. 269 B, 1285–1288 (1969).

    Google Scholar 

  • Crosnier, Y., Gabillard, R., Citerne, J.: Étude de l’influence de la température sur la relaxation des spins nucléaires d’un liquide contenu dans un milieu poreux, en champ directeur faible. Compt. Rend. 269 B, 1328–1331 (1969).

    Google Scholar 

  • Dehl, R.E.: Broadline NMR study of H2O and D2O in oriented rayon fibers. J. Chem. Phys. 48, 831–835 (1968).

    Article  CAS  Google Scholar 

  • Dehl, R.E., Hoeve, C.A.J.: Broad-line NMR study of H2O and D2O in collagen fibers. J. Chem. Phys. 50, 3245–3251 (1969).

    Article  CAS  Google Scholar 

  • Deininger, D., Pfeifer, H., Przyborowski, F., Schirmer, W., Stach, H.: NMR-studies of water protons in NaX-, NaA-, CaA-, and MgA-zeolites. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p. 171–183 (1969).

    Google Scholar 

  • Deininger, D.: Diplomarbeit, Sektion Physik der Karl-Marx-Universität (1969).

    Google Scholar 

  • Deininger, D., Pfeifer, H., Przyborowski, F., Schirmer, W., Stach, H.: Kernspinresonanzmessungen an Zeolithen. II. Untersuchung der magnetischen Protonenresonanz von Wasser, das an NaX-, NaA-, CaA- und MgA-Zeolithen adsorbiert ist. Z. Physik Chem. (Leipzig) 245, 68–80 (1970).

    CAS  Google Scholar 

  • Demco, D.: Nuclear magnetic resonance free induction decay in a system of several species. Phys. Letters 27 A, 702–703 (1968).

    Google Scholar 

  • Derouane, E.G., Karra, J.S., Fujita, Y.: Dynamic polarization of protons in charcoal and benzene adsorbed on charcoal. Bull. Soc. Chim. Belg. 76, 678–697 (1967).

    Article  CAS  Google Scholar 

  • Deininger, D.: Étude par r.m.n. de haute résolution de l’état adsorbé. I. Mise en evidence d’un systeme nucléaire triphase. Bull. Soc. Chim. Belg. 78, 89–99 (1969).

    Google Scholar 

  • Deininger, D.: Étude par r.m.n. de haute résolution de l’état adsorbé. II. Orientation moléculaire dans les micropores saturés. Bull. Soc. Chim. Belg. 78, 101–110 (1969).

    Google Scholar 

  • Deininger, D.: Étude par r.m.n. de haute résolution de l’état adsorbé. III. Mise en évidence de points de congélation et interprétation. Bull. Soc. Chim. Belg. 78, 111–120 (1969).

    Google Scholar 

  • Devereux, O.F.: Effect of crude oil on the nuclear magnetic relaxation of water protons in sandstone. Nature 215, 614–615 (1967).

    Article  CAS  Google Scholar 

  • Dmitrieva, L.V., Moskalev, V. V.: Calculation of the second moment of a nuclear magnetic resonance line in isotropic rotation of molecules (in Russian). Fiz. Twerd. Tela 5, 2230–2231 (1963).

    CAS  Google Scholar 

  • Doskočilová, D., Schneider, B.: Narrowing of proton NMR lines by magic angle rotation. Chem. Phys. Letters 6, 381–384 (1970).

    Article  Google Scholar 

  • Dowley, M.W.: Quadrupole broadening of NMR signal in 200 Å particles. Phys. Letters 24 A, 428–429 (1967).

    Google Scholar 

  • Drost-Hansen, W.: Structure of water near solid interfaces. Ind. Eng. Chem. 61, 10–47 (1969).

    Article  CAS  Google Scholar 

  • Dubin, A.S., Chan, S.J.: Nuclear-spin-internal-rotation coupling. J. Chem. Phys. 46, 4533–4535 (1967).

    Article  CAS  Google Scholar 

  • Ducros, P., Dupont, M.: Étude par résonance magnétique nucléaire des protons dans les argiles. Compt. Rend. 254, 1409–1410 (1962).

    Google Scholar 

  • Ducros, P., Dupont, M.: Étude par résonance magnétique nucléaire de l’eau des argiles. In: Proc. XI. Coll. Ampère, p. 654–657. Amsterdam: North Holland 1963.

    Google Scholar 

  • Dupont, M.: Étude de l’eau contenue dans les argiles par résonance magnétique nucléaire des protons. Thèse, Université de Grenoble (1965).

    Google Scholar 

  • Ebert, I., Seifert, G.: Kernresonanz im Festkörper, p. 191–200. Leipzig: 1966.

    Google Scholar 

  • Egorov, M.M., Kvlividze, W.I., Kiselev, V.F., Krassilnikov, K.G.: Die Natur der Oberfläche und die Adsorptionseigenschaften von Siliziumdioxid. Kolloid-Z. u. Z. Polymere 212, 126–138 (1966). R: Concerning the separation into Gaussian components compare Section 2.2.3.1.

    Article  CAS  Google Scholar 

  • Eigeles, M.A., Moiseev, B.M., Marčenko, V.B., Fedorov, L.I., Milovidova, H.D.: The state of water on the surface of minerals as studied by NMR (in Russian). Dokl. Akad. Nauk. SSSR 185, 1101–1103 (1969).

    CAS  Google Scholar 

  • Eremenko, A.M., Piontkovskaja, M.A., Matjaš, I.V., Mank, V.V., Starkov, M.G., Nejmark I.E.: Proton magnetic resonance of ammonia adsorbed on different cation exchanged zeolites of type A (in Russian). Žurn. Strukt. Chim. 7, 106–107 (1966).

    CAS  Google Scholar 

  • Ernst, R.R., Anderson, W. A.: Application of Fouriertransform spectroscopy to magnetic resonance. Rev. Sci. Instr. 37, 93–102 (1966).

    Article  CAS  Google Scholar 

  • Estrade, H.: Étude des surfaces de carbons par résonance magnétique. Relaxation magnétique et polarisation dynamique des noyaux de molécules adsorbées. Thèse, Université de Paris (1968).

    Google Scholar 

  • Evans, W.A., Powles, J.G.: The line shape problem in nuclear magnetic resonance. Phys. Letters 24 A, 218–219 (1967).

    Article  CAS  Google Scholar 

  • Favro, I.D.: Theory of the rotational Brownian motion of a free rigid body. Phys. Rev. 119, 53–62 (1960).

    Article  Google Scholar 

  • Fenzke, D.: Kernmagnetische Relaxation von Mehr-Spin-Molekülen. Ann. Phys. (Leipzig) 16, 281–288 (1965).

    CAS  Google Scholar 

  • Fenzke, D.: Kernmagnetische Relaxation von Mehr-Spin-Molekülen R: Erratum Ann. Phys. (Leipzig) 19, 321–322 (1967).

    Article  CAS  Google Scholar 

  • Fenzke, D.: Über das Signal-Rausch-Verhältnis bei der Untersuchung magnetischer Kernresonanzen mit der Spin-Echo-Methode. Dissertation, Karl-Marx-Universität Leipzig (1966).

    Google Scholar 

  • Fenzke, D., Schneider, H.: Bemerkungen zu der Arbeit “A note on the spin-lattice relaxation of nuclei in liquids” von J. G. Powles and R. Figgins. Ann. Phys. (Leipzig) 19, 321–322 (1967).

    CAS  Google Scholar 

  • Fiat, D., Reuben, J., Folman, M.: NMR relaxation mechanisms at solid-gas interfaces. CH3OH, CD3OH, and CH3OD adsorbed on porous glass. J. Chem. Phys. 46, 4453–4456 (1967).

    Article  CAS  Google Scholar 

  • Fitzsimmons, W.A., Walters, G.K.: Very long nuclear spin relaxation times in gaseous 3He by suppression of 3He-surface interactions. Phys. Rev. Letters 19, 943–946 (1967).

    Article  CAS  Google Scholar 

  • Fraissard, J., Solomon, I., Caillat, R., Elston, J., Imelik, B.: Application de la resonance magnétique nucléaire a l’étude de l’eau de constitution des gels de silice. J. Chini. Phys. 60, 670–683 (1963).

    Google Scholar 

  • Fraissard, J., Caillat, R., Elston, J., Imelik, B.: Étude de l’acide formique adsorbé sur les gels de silice par la résonance magnétique nucléaire (r.m.n.). J. Chim. Phys. 60, 1017–1018 (1963).

    CAS  Google Scholar 

  • Fraissard, J., Bielikoff, S., Imelik, B.: Isomérisation du 1-butène sur un catalyseur silice-alumine: étude par résonance magnétique nucléaire du complexe chimisorbé. Compt. Rend. 271 C, 897–900 (1970).

    CAS  Google Scholar 

  • Fratiello, A., Douglass, E.C.: Nuclear magnetic resonance study of solid perfluorocyclohexane. J. Chem. Phys. 41, 974–978 (1964).

    Article  CAS  Google Scholar 

  • Freude, D., Pfeifer, H., Winkler, H.: Die Temperaturabhängigkeit der Protonenrelaxationszeiten des Systems Benzol-Silikagel. Z. Phys. Chem. (Leipzig) 232, 276–280 (1966).

    CAS  Google Scholar 

  • Freude, D.: Untersuchung der Selbstdiffusionskoeffizienten und der kernmagnetischen Relaxationszeiten von am Silikagel adsorbierten Diäthyläther, Benzol und n-Hexan. Z. Phys. Chem. (Leipzig) 242, 57–66 (1969).

    CAS  Google Scholar 

  • Freude, D.: Magnetische Protonenresonanzuntersuchungen von Silikagel und daran adsorbiertem Diäthyläther, n-Hexan und Benzol. Dissertation, Karl-Marx-Universität Leipzig (1970).

    Google Scholar 

  • Freude, D., Müller, D., Schmiedel, H.: On the line shape problem of proton resonance spectra of hydroxil groups on solid surfaces. Surface Sci. 25, 289–297 (1971).

    Article  CAS  Google Scholar 

  • Freude, D., Müller, D., Schmiedel, H.: Concerning the experimental results on hydroxil groups in decationated zeolites compare (Freude 1971b).

    Google Scholar 

  • Freude, D., Müller, D., Schmiedel, H.: NMR-studies of hydroxyl groups in decationated zeolites Y. J. Colloid Interf. Sci. 36, 320–324 (1971).

    Article  CAS  Google Scholar 

  • Freude, D.: Untersuchung der kernmagnetischen Relaxationszeiten und der Selbstdiffusionskoeffizienten von am Silikagel adsorbierten Diäthyläther und n-Hexan. Z. Phys. Chem. (Leipzig) 247, 209–218 (1971).

    CAS  Google Scholar 

  • Freude, D., Müller, D., Schmiedel, H.: Magnetische Protonenresonanzuntersuchungen an dekationisierten Zeolithen. Z. Physik Chem. (Leipzig) (in the press).

    Google Scholar 

  • Fripiat, J.J., Touillaux, R.: Proton mobility in solids. Part 3. — Proton magnetic relaxation in Boehmite. Trans. Faraday Soc. 557, 65, 1236–1247 (1969).

    Article  Google Scholar 

  • Fripiat, J.J., Meersche, C. van der, Touillaux, R., Jelli, A.: Study of protonic transfers in the ammonia-silica gel system by infrared and pulsed proton magnetic resonance spectroscopy and by conductivity measurements. J. Phys. Chem. 74, 382–393 (1970). R: The assumption that the translational motion rules T -11 while T -12 is contributed by both the rotational and translational motions can not be checked. It seems possible to assume also two regions of different adsorption energy. Instead of Eqs. (9) and (10) the results of Beckert (Beckert 1971 a and 1971 b) should be used.

    Article  CAS  Google Scholar 

  • Fuschillo, N., Aston, J. G.: Nuclear magnetic resonance as a method for detecting relaxation phenomena of molecules adsorbed on surfaces. J. Chem. Phys. 24, 1277–1278 (1956). R: adsorbent TiO2.

    Article  CAS  Google Scholar 

  • Fuschillo, N., Renton, C.A.: Nuclear magnetic resonance of methane adsorbed on titanium dioxide. Nature 180, 1063–1064 (1957).

    Article  CAS  Google Scholar 

  • Gabuda, S.P.: Diffusion of water molecules in natrolite (in Russian). Dokl. Akad. Nauk. SSSR 146, 840–843 (1963).

    Google Scholar 

  • Gabuda, S.P., Michailov, G.M.: Proton magnetic resonance of water in zeolites at low temperatures (in Russian). Žurn. Strukt. Chim. 4, 446–447 (1963).

    CAS  Google Scholar 

  • Gabuda, S.P., Michailov, G.M., Aleksandrov, K.S.: The behaviour of zeolitic water and the symmetry of harmotom (in Russian). Dokl. Akad. Nauk SSSR 153, 1360–1362 (1963).

    CAS  Google Scholar 

  • Gabuda, S.P., Lundin, A.G.: Diffusion of water molecules in hydrates and NMR spectra (in Russian). Zum. Eks. i Teor. Fiz. 55, 1066–1076 (1968).

    CAS  Google Scholar 

  • Gabuda, S.P., Ivleva, L.V., Lundin, A.G.: Proton magnetic resonance in heulandite (in Russian). Žurn. Strukt. Chim. 11, 646–649 (1970).

    CAS  Google Scholar 

  • Galkjn, A.A., Matjaš, I.V.: NMR study of adsorbed gases (in Russian). Žurn. Eks. i Teor. Fiz. 38, 1332–1334 (1960). R: no discussion of the experimental results.

    Google Scholar 

  • Galkjn, A.A., Matjaš, I.V.: Study of nuclear magnetic relaxation of adsorbed gases by the spin echo method (in Ukrain). Ukrain. Fis. Žurn. 7, 54–66 (1962). R: adsorbate: H2; pressure 0.1–1 at ~ 70K; adsorbate: 3He; surface density 1013–1014 cm-2.

    Google Scholar 

  • Geschke, D., Pfeifer, H.: Eine Methode zur Bestimmung der Orientierung adsorbierter Moleküle an Festkörperoberflächen. Z. Phys. Chemie (Leipzig) 232, 127–133 (1966).

    CAS  Google Scholar 

  • Geschke, D., Pfeifer, H.: An NMR method for determining the orientation of molecules adsorbed on surfaces of solids. In: “Proc. 14th Coll. Ampère”, p. 430–431. Amsterdam: North Holland (1967).

    Google Scholar 

  • Geschke, D.: Verschiebungen der magnetischen Kernresonanzsignale adsorbierter Moleküle. Z. Naturforsch. 23a, 689–694 (1968).

    CAS  Google Scholar 

  • Geschke, D., Pfeifer, H., Winkler, H.: Proton relaxation in liquids sorbed on alumina. J. Colloid Interf. Sci. 26, 287–290 (1968). R: The alumina has been impregnated with different amounts of Fe2O3.

    Article  CAS  Google Scholar 

  • Geschke, D.: NMR-Linienverschiebungen am System Wasser-Saccharosekohle. Z. Phys. Chem. (Leipzig) 239, 138–141 (1968).

    CAS  Google Scholar 

  • Geschke, D., Pfeifer, H., Reinert, D.: Die Untersuchung der Adsorption von Cyclohexan an Aluminiumoxyd mit Hilfe der kernmagnetischen Resonanz. Z. phys. Chem. (Leipzig) 237, 167–176 (1968).

    CAS  Google Scholar 

  • Geschke, D.: Die Untersuchung adsorbierter Moleküle mit Hilfe der hochauflösenden magnetischen Kernresonanz. Z. phys. Chem. (Leipzig) 242, 74–80 (1969).

    CAS  Google Scholar 

  • Geschke, D., Michel, D., Pfeifer, H., Winkler, H.: NMR investigations of adsorbed molecules. In: „Tagung Hochfrequenzspektroskopie Leipzig 1969“, p. 45–71 (1969).

    Google Scholar 

  • Geschke, D., Michel, D., Pfeifer, H.: Temperature dependence of the nuclear magnetic relaxation times of benzene and cyclohexane adsorbed on γ-Al2O3. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p. 199–206 (1969).

    Google Scholar 

  • Geschke, D.: 13C-Kernspinresonanz adsorbierter Moleküle. Z. Phys. Chem. (Leipzig) (in the press).

    Google Scholar 

  • Giulotto, L.: Temps de relaxation en résonance magnétique nucléaire en relation avec les phénomènes d’adsorption, d’association moléculaire et de polymerisation. J. Chim. Phys. 61, 177–181 (1964).

    CAS  Google Scholar 

  • Glasel, J.A.: NMR relaxation in heterogeneous systems. Nature 227, 704–705 (1970).

    Article  CAS  Google Scholar 

  • Gradsztajn, S., Conard, J.: Étude par résonance magnétique nucléaire à haute resolution du gaz inclus dans une série d’anthracites naturels. Compt. Rend. 262 C, 1213–1216 (1966).

    Google Scholar 

  • Gradsztajn, S.: Étude en haute résolution des liquides adsorbés sur des carbones à grande surface. Origine du déplacement des raies. Compt. Rend. 266 B, 817–819 (1968).

    Google Scholar 

  • Gradsztajn, S.: Étude de la surface de solides par r.m.n. de liquides adsorbé. — I. Origine du déplacement et de la largeur des raies dans le cas des carbones. J. Phys. Chem. Solids 31, 1121–1135 (1970).

    Article  CAS  Google Scholar 

  • Gradsztajn, S.: Résonance magnétique nucléaire des molécules adsorbées. Contribution à l’étude de certains solides microporeux. R: adsorbents charcoal and ZrO2. Thèse, Université de Paris (1970).

    Google Scholar 

  • Graham, D., Phillips, W.D.: Shifts in the proton magnetic resonance frequencies of organic compounds adsorbed on carbon. In: Solid-Gas Interface, p. 22–26. London: Butterworth 1957.

    Google Scholar 

  • Graham, J., Walker, G.F., West, G.W.: Nuclear magnetic resonance study of interlayer water in hydrated layer silicates. J. Chem. Phys. 40, 540–550 (1964).

    Article  CAS  Google Scholar 

  • Grinčenko, I.V., Gabuda, S.P.: Molecular motion of benzene adsorbed on zeolite NaX and CaX (in Russian). Žurn. Strukt. Chim. 10, 739–740 (1969).

    Google Scholar 

  • Grinčenko, I.V., Gabuda, S.P.: Proton magnetic resonance of n-paraffines adsorbed on zeolite CaA (in Russian). Žum. Strukt. Chim. 11, 443–453 (1970).

    Google Scholar 

  • Grinčenko, I.V., Gabuda, S.P.: NMR spectra and molecular motion of water in some porous crystals (in Russian). Žurn. Strukt. Chim. 12, 34–39 (1971).

    Google Scholar 

  • Gross, B., Kosfeld, R.: Anwendung der Spin-Echo-Methode bei der Messung der Selbstdiffusion. Messtechnik 77, 171–177 (1969).

    Google Scholar 

  • Gutowsky, H.S., Pake, G.E.: Structural investigations by means of nuclear magnetism. II. hindered rotation in solids. J. Chem. Phys. 18, 162–170 (1950).

    Article  CAS  Google Scholar 

  • Gutsze, A.: Nuclear magnetic resonance relaxations times of water adsorbed on sugar carbon. Acta Physica Polon. 34, 239–245 (1968).

    CAS  Google Scholar 

  • Gutsze, A., Deininger, D., Pfeifer, H., Finger, G., Schirmer, W., Stach, H.: Kernspinresonanzmessungen an Zeolithen. III. Untersuchung der kernmagnetischen Relaxation von Wasserprotonen in NaX-Zeolithen hoher Reinheit. Z. Phys. Chem. (Leipzig) (in the press). R: Reprints in English available.

    Google Scholar 

  • Gvacharija, V.G., Kvlividze, V.I., Kubasov, A.A., Romanovskij, B.V., Topčieva, K.V., Cicišvilli, G.V.: Proton resonance spectra in decationated zeolite Y (in Russian). Kinetika i Kataliz 10, 1392–1394 (1969). R: cf. Section 2.2.3.1, (Freude 1971a), and (Freude 1971b).

    Google Scholar 

  • Gvacharija, V.G., Kvlividze, V.I., Kiselev, V.F., Pylova, M.B., Cicišvili, G.V.: The nature of proton centres in catalytically active zeolites (in Russian). Dokl. Akad. Nauk SSSR 188, 379–382 (1969). R: cf. Section 2.2.3.1, (Freude 1971 a), and (Freude 1971 b).

    Google Scholar 

  • Haeberlen, U., Hausser, R., Noack, F.: Kernmagnetische Messungen an einem linearen Polyäthylen. I. Spin-Gitter-Relaxationszeit T 1 und Linienform. Z. Naturforsch. 18a, 689–700 (1963).

    Google Scholar 

  • Haeberlen, U.: Nuclear dipolar relaxation in pure solids. Z. Naturforsch. 25a, 1459–1466 (1970).

    CAS  Google Scholar 

  • Hall, W.K., Leftin, H.P., Cheselske, F.J., O’Reilly, D.E.: Studies of the hydrogen held by solids. IV. Deuterium exchange and NMR investigations of silica, alumina, and silica-alumina. J. Catalysis 2, 506–517 (1963).

    Article  CAS  Google Scholar 

  • Hall, G.E., Lawrence, J.G., Simpson, R.J.: Nuclear magnetic resonance as a method for continously monitoring rehydration. Nature 216, 474–475 (1967).

    Article  CAS  Google Scholar 

  • Haul, R.: Oberflächendiffusion und Relaxationszeiten adsorbierter Moleküle. Angew. Chem. 79, 908 (1967).

    Article  Google Scholar 

  • Haupt, J., Müller-Warmuth, W.: Kernrelaxation und Spindiffusion in organischen Festkörpern mit paramagnetischen Radikalzentren. Z. Naturforsch. 22a, 643–650 (1967).

    CAS  Google Scholar 

  • Hecht, A.M., Dupont, M., Ducros, P.: Étude des phénomènes de transport de l’eau adsorbée dans certains minéraux argileux par la résonance magnétique nucléaire. Bull. Soc. France Minéral. Crist. 89, 6–13 (1966).

    CAS  Google Scholar 

  • Hecht, A.M., Geissler, E.: Nuclear magnetic resonance and relaxation of adsorbed water in synthetic fluor montmorillonite. J. Colloid Interf. Sci. 34, 32–35 (1970).

    Article  CAS  Google Scholar 

  • Heinze, H.E., Pfeifer, H.: Die Frequenzabhängigkeit des rotatorischen und translatorischen Anteils der kernmagnetischen Relaxation in Flüssigkeiten. Z. Physik 192, 329–339 (1966).

    Article  CAS  Google Scholar 

  • Hertz, H.G.: Rotational and translational diffusion and dipolar spin relaxation in diamagnetic electrolyte solutions. Ber. Bunsenges. 71, 979–999 (1967).

    CAS  Google Scholar 

  • Hickmott, T.W., Selwood, P.W.: Proton relaxation on catalytic solids. J. Phys. Chem. 60, 452–457 (1956). R: The results depend strongly on the unknown amount of paramagnetic impurities.

    Article  CAS  Google Scholar 

  • Hilt, R.L., Hubbard, P.S.: Nuclear magnetic relaxation of three spin systems undergoing hindered rotations. Phys. Rev. 134, A 392–A 398 (1964).

    Article  Google Scholar 

  • Hirota, K., Fueki, K., Sakai, T.: Spectroscopic studies of methylamine adsorption on gamma-alumina. Bull Chem. Soc. Japan 35, 1545–1548 (1962).

    Article  CAS  Google Scholar 

  • Hirota, K., Kondo, T., Ogawa, T.: NMR and infra-red study of the adsorbed state of acetic acid on silica. J. Chem. Soc. Japan 88, 137–139 (1967).

    CAS  Google Scholar 

  • Hougardy, J., Serratosa, J. M., Stone, W., Olphen, H. van: Interlayer water in vermiculite: Thermodynamic properties, packing density, nuclear pulse resonance, and infra-red adsorption. Faraday Discussion Cambridge, September 1970, 7 pages, preprint (1970).

    Google Scholar 

  • Hubbard, P.S.: Quantum mechanical and semiclassical forms of the density operator theory of relaxation. Rev. Mod. Phys. 33, 249–264 (1961).

    Article  CAS  Google Scholar 

  • Hubbard, P.S.: Nuclear magnetic resonance and relaxation of four spin molecules in a liquid. Phys. Rev. 128, 650–658 (1962).

    Article  CAS  Google Scholar 

  • Hubbard, P.S.: Nuclear magnetic relaxation by intermolecular dipole-dipole interactions. Phys. Rev. 131, 275–282 (1963).

    Article  CAS  Google Scholar 

  • Hubbard, P.S.: Theory of nuclear magnetic relaxation by spin-rotational interactions in liquids. Phys. Rev. 131, 1155–1165 (1963).

    Article  CAS  Google Scholar 

  • Hubbard, P.S.: Nonexponential relaxation of three-spin systems in nonspherical molecules. J. Chem. Phys. 51, 1647–1651 (1969). R: cf. (Schneider 1964b).

    Article  CAS  Google Scholar 

  • Hubbard, P.S.: Nonexponential relaxation of rotating three-spin systems in molecules of a liquid. J. Chem. Phys. 52, 563–568 (1970).

    Article  CAS  Google Scholar 

  • Hummel, R.: Zur magnetischen Protonenrelaxation von Wasser, das an Kohlen adsorbiert ist. Dissertation, Karl-Marx-Universität Leipzig (1967).

    Google Scholar 

  • Hummel, R.: Zur magnetischen Protonenrelaxation von Wasser, das an Saccharosekohlen adsorbiert ist. I. Die Struktur der verwendeten Kohleadsorbentien. Z. Phys. Chem. (Leipzig) 242, 119–137 (1969).

    CAS  Google Scholar 

  • Itoh, J., Kusaka, R., Yamagata, Y., Kiriyama, R., Ibamoto, H.: Nuclear magnetic resonance experiment on a four-proton system in a single crystal of K2HgCl4 · H2O. J. Chem. Phys. 20, 1503–1504 (1952).

    Article  CAS  Google Scholar 

  • Itoh, J., Kusaka, R., Yamagata, Y., Kiriyama, R., Ibamoto, H.:Nuclear magnetic resonance experiment on a four-proton system in a single crystal of K2HgCl4 · H2O Erratum J. Chem. Phys. 21, 190 (1953).

    Article  CAS  Google Scholar 

  • Itoh, J., Kusaka, R., Yamagata, Y., Kiriyama, R., Ibamoto, H.: The resonance absorption due to four proton system and the revised determination of their crystal structures. J. phys. Soc. Japan 8, 293–301 (1953).

    Article  CAS  Google Scholar 

  • Ivanov, E.N.: Theory of rotational Brownian movement (in Russian). Žurn. Eks. Teor. Fiz. 45, 1509–1517 (1963).

    CAS  Google Scholar 

  • Ivanov, E.N.: Theory of rotational Brownian movement (in Russian) JETP 18, 1041 (1964).

    Google Scholar 

  • Ivleva, L.V., Gabuda, S.P., Lundin, A.G.: The state of water molecules and their mobility in stilbite (in Russian). Žurn. Strukt. Chim. 10, 797–803 (1969).

    CAS  Google Scholar 

  • Jeener, J., Broekhaert, P.: Nuclear magnetic resonance in solids: Thermodynamic effects of a pair of rf pulses. Phys. Rev. 157, 232–240 (1967).

    Article  CAS  Google Scholar 

  • Jeener, J.: Thermodynamics of spin systems in solids. In: Advances in magnetic resonance, ed. J. Waugh, Vol. 3, p. 206–310. New York: 1968.

    Google Scholar 

  • Kärger, J., Pfeifer, H.: Zur Theorie der Protonenrelaxation infolge Wechselwirkung mit paramagnetischen Zentren. Ann. Phys. (Leipzig) 22, 51–60 (1968).

    Google Scholar 

  • Kärger, J.: On the measurement of diffusion coefficients by means of nuclear magnetic resonance in the presence of statistically distributed gradients. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p. 213–215 (1969).

    Google Scholar 

  • Kärger, J.: Zur Bestimmung der Diffusion in einem Zweibereichsystem mit Hilfe von gepulsten Feldgradienten. Ann. Phys. (Leipzig) 24, 1–4 (1969).

    Google Scholar 

  • Kärger, J.: Seyd, W., Pfeifer, H., Geschke, D.: An investigation of diffusion processes in 13 X-zeolites using NMR pulsed field gradient techniques. In: Proc. 16. Colloque Ampère Bucharest 1970. 635–636 (1971).

    Google Scholar 

  • Kärger, J.: Diffusionsmessungen in freien und adsorbierten Flüssigkeiten. In: Herbstschule Hochfrequenzspektroskopie Binz 1971. 229–260 (1971).

    Google Scholar 

  • Kärger, J.: Heink, W.: Zur Meßbarkeit von Diffusionskoeffizienten mit Hilfe der Methode der gepulsten Feldgradienten. Exp. Techn. Phys. 19, 453–465 (1971).

    Google Scholar 

  • Kärger, J.: Der Einfluß der Zweibereichdiffusion auf die Spinechodämpfung unter Berücksichtigung der Relaxation bei Messungen mit der Methode der gepulsten Feldgradienten. Ann. Phys. (Leipzig) 27, 107–109 (1971).

    Google Scholar 

  • Kärger, J.: Diffusionsuntersuchung von Wasser an 13 X- sowie 4A- und 5 A-Zeolithen mit Hilfe der Methode des gepulsten Feldgradienten. Z. Phys. Chem. (Leipzig) 248, 27–41 (1971).

    Google Scholar 

  • Kanichi Kamiyoshi, M.: Étude par résonance magnétique nucléaire de l’eau fixée sur un gel de süice. J. Phys. Radium 20, 60 (1959).

    Article  Google Scholar 

  • Karagounis, G.: Nuclear magnetic resonance of adsorbed molecules. Nature 201, 604–605 (1964). R: Concerning the dependence of line width on coverage cf. (Pickett 1970 a).

    Article  CAS  Google Scholar 

  • Karagounis, G., Stassinopoulos, C.I.: Über die NMR-Spektren adsorbierter Moleküle. III. Mitteilung. Z. Phys. Chem. (N.F.) 71, 39–50 (1970).

    Article  CAS  Google Scholar 

  • Koji Kawasaki, Yoshiyasu Sekita: Sorption and diffusion of water vapor by nylon 6. J. Polymer: Sci. A 2, 2437–2443 (1964).

    Google Scholar 

  • Kermarec, J., Fraissard, J., Imelik, B.: Application de la résonance magnétique nucléaire a l’étude de l’eau de constitution des solides divisés. I. — Théorie des mesures. II. — Silice — alumine. J. Chim. Phys. 64, 911–915 (1967);

    CAS  Google Scholar 

  • Kermarec, J., Fraissard, J., Imelik, B.: Application de la résonance magnétique nucléaire a l’étude de l’eau de constitution des solides divisés. I. — Théorie des mesures. II. — Silice — alumine. J. Chim. Phys. 65, 920–925 (1968).

    CAS  Google Scholar 

  • Kibbe, A.H., Araujo, O.E.: Nuclear magnetic resonance and rheological studies on the thixotropic properties of montmorillonite — water systems. J. Pharm. Sci. 58, 714–718 (1969).

    Article  CAS  Google Scholar 

  • Kimmel, H.: Änderung der kernmagnetischen Wechselwirkungen in Flüssigkeiten durch Einfluß von Festkörper-Oberflächen. Z. Naturforsch. 16a, 1058–1062 (1961).

    CAS  Google Scholar 

  • Knappwost, A., Gunsser, W., Lechert, H.: Untersuchungen der 23Na- und der Protonenresonanz im System Zeolith-Wasser. Z. Naturforsch. 21a, 1200–1201 (1966).

    Google Scholar 

  • Knappwost, A., Lechert, H., Gunsser, W.: Das Temperaturverhalten der magnetischen Protonen- und Kationenresonanzen an den Natrium-, Lithium- und Cäsiumformen des synthetischen Zeoliths Linde 13X. Z. Phys. Chem. (N.F.) 58, 278–289 (1968). R: The interpretation on p. 286/287 was revised in (Lechert 1970).

    Article  CAS  Google Scholar 

  • Kroon, D.J.: Line shape of proton magnetic resonance in paramagnetic solids. Philips Res. Repts. 15, 501–583 (1960).

    CAS  Google Scholar 

  • Kumar, J., Fatt, I., Saraf, D.N.: Nuclear magnetic relaxation time of water in a porous medium with heterogeneous surface wettability. J. Appl. Phys. 40, 4165–4171 (1969). R: A linear relationship between the relaxation time and the fractional wettability of the sample could be observed.

    Article  CAS  Google Scholar 

  • Kvlividze, V.I., Jevskaja, N.M., Egorova, T.S., Kiselev, V.F., Sokolov, N.D.: Investigation of water adsorption on the surface of silica gel by the NMR method (in Russian). Kin. I Katal. 3, 91–98 (1962).

    CAS  Google Scholar 

  • Kvlividze, V.I.: Krasilnikov, K.G.: An investigation of the state of water adsorbed on CaO/SiO2 using the method of nuclear magnetic resonance (in Russian). Dokl. Akad. Nauk SSSR 145, 1305–1307 (1962).

    CAS  Google Scholar 

  • Kvlividze, V.I.: Nuclear magnetic resonance of water protons adsorbed on silica at 93° K (in Russian). Dokl. Akad. Nauk SSSR 157, 158–161 (1964). R: NMR theory of line shapes is not able to prove the procedure of line shape analysis, which was applied to the OH group signal in this work (cf. Section 2.2.3.1).

    CAS  Google Scholar 

  • Kvlividze, V.I., Kiselev, V.F., Serpinskij, V.V.: Investigation of the NMR signal of water protons in zeolites at low temperatures (in Russian). Dokl. Akad. Nauk SSSR 165, 1111–1114 (1965).

    CAS  Google Scholar 

  • Kvlividze, V.I., Zarifjanc, Ju.A., Kiselev, V.F.: Investigation of the surface of fresh cleaved graphite (in Russian). Žurn. Fiz. Chim. 39, 461–462 (1965). R: The NMR signal of polyethylene was observed for different contents of graphite.

    CAS  Google Scholar 

  • Kvlividze, V.I., Kiselev,V.F.: Investigation of phase transition of adsorbed water using the method of nuclear magnetic resonance (in Russian). Žurn. Strukt. Chim. 8, 221–226 (1967).

    CAS  Google Scholar 

  • Kvlividze, V.I., Brants, R.A., Kiselev, V.F., Bliznakov, G.M.: On the state of ammonia in the adsorbed phase. J. Catalysis 13, 255–260 (1969).

    Article  CAS  Google Scholar 

  • Kvlividze, V.I., Kiselev, V. F., Ušakova, L.A.: On the existence of quasi-liquid films on the surface of ice (in Russian). Dokl. Akad. Nauk SSSR 191, 1088–1090 (1970).

    CAS  Google Scholar 

  • Ladner, W.R., Wheatley, R.: Moisture in coal by NMR: effect of mineral matter and size. J. Inter. Fuel 39, 280–284 (1966).

    CAS  Google Scholar 

  • Laidler, K.J.: Chemical Kinetics. London: 1965. R: In applying the ideas discussed in “the theory of absolute reaction rates” of this book, the factor 1/2 in Eq. (2.74) can be easily verified.

    Google Scholar 

  • Lechert, H., Gunsser, W., Knappwost, A.: Kemmagnetische Resonanzuntersuchungen an den Natrium-, Lithium- und Cäsiumformen synthetischer Zeolithe vom Faujasittyp. Ber. Bunsenges. Physik. Chem. 72, 84–93 (1968).

    Article  CAS  Google Scholar 

  • Lechert, H., Gunsser, W., Knappwost, A.: Untersuchung der chemischen Verschiebung der 133Cs-Resonanz in synthetischen Zeolithen vom Faujasittyp. Z. Naturforsch. 23a, 1343–1346 (1968).

    Google Scholar 

  • Lechert, H., Knappwost, A., Rálek, M.: Das Temperaturverhalten der magnetischen Protonen-und 19F-Resonanzen an einigen im synthetischen Zeolithen Linde 13 X adsorbierten ringförmigen organischen Substanzen. Z. Naturforsch. 24a, 1759–1764 (1969).

    Google Scholar 

  • Lechert, H., Gunsser, W.: Über das Temperaturverhalten der 7Li-, 23Na- und der 133Cs-Resonanz an den Lithium-, Natrium- und Cäsiumformen des synthetischen Zeoliths Linde 13 X im H2O- und D2O-gesättigten Zustand. Surface Sci. 20, 44–54 (1970).

    Article  CAS  Google Scholar 

  • Leduc, M., Brossel, J.: Étude comparée de la relaxation sur des parois de silice de noyaux de 109Cd et de 111Cd, orientés par pompage optique. Compt. Rend. 266B, 287–290 (1968). R: Reduction of T 2 in the case of 109Cd due to quadrupole interaction at the walls.

    CAS  Google Scholar 

  • Lindner, U.: Protonenrelaxation in paramagnetischen Lösungen unter Berücksichtigung der Nullfeldaufspaltung. Ann. Phys. (Leipzig) 16, 319–335 (1965).

    Google Scholar 

  • Lipatov, Ju.S., Fabuljak, F.G.: Investigation of molecular motion in surface layers of polymethyl-methacrylate and polystyrene by pulsed NMR measurements (in Russian). Visokomolekuljarnije Sojedinenija 10 A, 1605–1612 (1968).

    CAS  Google Scholar 

  • Look, D.C., Lowe, I.J.: Nuclear dipole-dipole relaxation along the static and rotating magnetic fields: application to gypsum. J. Chem. Phys. 44, 2995–3000 (1966).

    Article  CAS  Google Scholar 

  • Look, D.C., Lowe, I.J.: Effect of hindered molecular rotation between unequal potential wells upon NMR spin-lattice relaxation times and second moments. J. Chem. Phys. 44, 3437–3441 (1966).

    Article  CAS  Google Scholar 

  • Lowe, I. J., Norberg, R.E.: Free-induction decays in solids. Phys. Rev. 107, 46–61 (1957).

    Article  CAS  Google Scholar 

  • Lynch, L. J., Marsden, K. H.: A study of the wool-water system by means of pulsed nuclear-magnetic-resonance techniques. J. Textile Inst. Transactions 57, T1–T7 (1966).

    Article  CAS  Google Scholar 

  • Lynch, L. J., Marsden, K. H., George, E.P.: I. A systematic method of analyzing NMR relaxation-time data for continuous distribution of nuclear correlation times. J. Chem. Phys. 51, 5673–5680 (1969).

    Article  CAS  Google Scholar 

  • Lynch, L. J., Marsden, K. H.: NMR of adsorbed systems II. A NMR study of keratin hydration. J. Chem. Phys. 51, 5681–5691 (1969).

    Article  CAS  Google Scholar 

  • Lynch, L. J., Haly, A.R.: A NMR study of the anisotropy of water absorbed by keratin. Kolloid Zeitschr. und Zeitschr. Polymere 239, 581–586 (1970).

    CAS  Google Scholar 

  • Mackey, J. H.: A proton magnetic resonance study of molecules sorbed in synthetic zeolites called molecular sieves. Diss. Abstr. 23, 3147–3148 (1963).

    Google Scholar 

  • Mank, V.V., Matjaš, J.V., Poljakov, V.E., Tarasevič, Ju.I., Ščerbak, Ja. Ja: Investigation of the state of water in montmorillonite by the NMR method (in Russian). Žurn. Fiz. Chim. 43, 1663–1667 (1969).

    CAS  Google Scholar 

  • Mank, V.V., Matjaš, J.V., Piontkovskaja, M.A., Nejmark, I.E., Tjutjunnik, R.S.: NMR spectra of water adsorbed on different ionexchanged zeolites of type A and X (in Russian). Žurn. Strukt. Chim. 11, 12–17 (1970).

    CAS  Google Scholar 

  • Matjaš, I.V, Piontkovskaja, M.A., Tarasenko, L.M., Tjutjunnik, R.S.: Magnetic resonance of water protons in zeolites (in Russian). Žurn. Strukt. Chim. 2, 214–215 (1962).

    Google Scholar 

  • Matjaš, I.V., Piontkovskaja, M.A., Tarasenko, L.M., Tjutjunnik, R.S.: Proton relaxation of zeolitic water (in Russian). Žurn. Strukt. Chim. 4, 106–107 (1963).

    Google Scholar 

  • Matjaš, I.V., Mank, V.V., Ščerbak, Ja. Ja., Piontkovskaja, M.A., Tjutjunnik, R.S.: NMR of the protons of water adsorbed on different ion-exchanged zeolites of type X and A (in Russian). Žurn. Neorg. Chim. 14, 508–510 (1969).

    Google Scholar 

  • Matjaš, I.V., Piontkovskaja, M.A., Denisenko, G.I., Kaliničenko, A.M.: NMR spectra of pyridine adsorbed on different cation-exchanged forms of faujasite (in Russian). Žurn. Strukt. Chim. 12, 13–18 (1971).

    Google Scholar 

  • Maya, I. M., Brady, G.W.: Nuclear magnetic resonance absorption by H2O on TiO2. J. Chem. Phys. 25, 583 (1956).

    Google Scholar 

  • Michel, D., Pfeifer, H.: Wandeffekte bei der kernmagnetischen Relaxation in Flüssigkeiten. Z. Naturforsch. 20a, 220–226 (1965). R: In some formulae of appendix I the indices W and F must be exchanged.

    Google Scholar 

  • Michel, D.: Einfluß von paramagnetischen Verunreinigungen auf die kernmagnetischen Relaxationszeiten von adsorbiertem Wasser. Z. Naturforsch. 21a, 366–368 (1966).

    Google Scholar 

  • Michel, D.: Zur Theorie der kernmagnetischen Relaxation eines Zweispinmoleküls mit verschiedenen Spins, zwischen denen eine skalare Kopplung besteht. Wiss. Z. Karl-Marx-Univ. 16, 635–638 (1967).

    Google Scholar 

  • Michel, D.: Zur Protonenrelaxation von Wasser an Silikagelen. Z. Naturforsch. 22a, 1751–1760 (1967).

    Google Scholar 

  • Michel, D.: Protonenspinrelaxation von Benzol an Silikageloberflächen. Z. Naturforsch. 23a, 339–347 (1968).

    Google Scholar 

  • Michel, D., Pfeifer, H., Todt, B: Die Frequenzabhängigkeit der longitudinalen Protonenrelaxationszeit von Benzol an Natriumchlorid. Z. Naturforsch. 23a, 823–826 (1968).

    Google Scholar 

  • Michel, D.: Zur Relaxation eines Kernspinpaares bei behinderter Bewegung. Ann. Phys. (Leipzig) (in the press).

    Google Scholar 

  • Michel, D., Thöring, J.: Kernspinrelaxation zum Studium des Adsorptionsverhaltens von Cyclohexan an NaX-Zeolithen. Z. Phys. Chem. (Leipzig) (in the press).

    Google Scholar 

  • Miller, G.R., Gutowsky, H.S.: NMR study of the alkali hexafluorophosphates dynamic structure. J. Chem. Phys. 39, 1983–1994 (1963).

    Article  CAS  Google Scholar 

  • Müller, D.: Dissertation, Karl-Marx-Universität Leipzig (in prep).

    Google Scholar 

  • Muha, G.M., Yates, D.J.C.: Nuclear magnetic resonance study of ethylene adsorbed on a zeolite. Chemical-shift measurements. J. Chem. Phys. 49, 5073–5083 (1968).

    Article  CAS  Google Scholar 

  • Muller, B.H.: Comment on the articles: Nuclear magnetic relaxation by intermolecular dipole-dipole interactions, and Nuclear spin relaxation in liquid and solid methane: isotope effects. Can. J. Phys. 44, 2511–2513 (1966).

    Article  CAS  Google Scholar 

  • Nagel, M., Michel, D., Geschke, D: Proton relaxation of benzene, cyclohexene, and cyclohexane in NaY-zeolite. J. Coll. Interf. Sci. 36, 254–257 (1971).

    Article  CAS  Google Scholar 

  • Noack, F., Preissing, G.: Magnetische Relaxation in Glycerin. Z. Naturforsch. 24a, 143–153 (1969).

    Google Scholar 

  • Noack, F., Joos, D.: Protonenrelaxation in adsorbiertem Wasser. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p. 217–221 (1969).

    Google Scholar 

  • Nowick, A.S., Berry, B.S.: Lognormal distribution function for describing anelastic and other relaxation processes. I. Theory and numerical computations. II. Data analysis and applications. IBM J. Res. Development 5, 297–311, 311–320 (1961).

    Article  Google Scholar 

  • Odajima, A., Sohma, J., Watanabe, S.: Nuclear magnetic resonance of water sorbed on fibrous materials. J. Chem. Phys. 31, 276–277 (1959).

    Article  CAS  Google Scholar 

  • Odajima, A.: Nuclear magnetic resonance of water sorbed on fibrous materials. J. Phys. Soc. Japan 14, 308–312 (1959).

    Article  CAS  Google Scholar 

  • Ogiwara, Y., Kubota, H., Hayashi, S., Mitomo, N.: Temperature dependency of bound water of cellulose studied by a high-resolution NMR spectrometer. J. Appl. Polymer. Sci. 14, 303–309 (1970).

    Article  CAS  Google Scholar 

  • Oppenheim, I., Bloom, M.: Nuclear spin relaxation in gases and liquids. I. Correlation functions. Can. J. Phys. 39, 845–869 (1961).

    Article  Google Scholar 

  • Ovčarenko, F.D., Mank, V.V., Matjas, J.V., Tarasevič, Ju.J., Ščerbak, Ja.Ja., Poljakov, V.E.: NMR of the protons of water adsorbed on vermiculite. Dokl. Akad. Nauk SSSR 177, 1131–1133 (1967).

    Google Scholar 

  • Packer, K.J.: Nuclear spin relaxation studies of molecules adsorbed on surfaces. In: Progress in NMR spectroscopy, ed. J. W. Emsley, J. Feeney, L. H. Sutcliffe, Vol. 3, p. 87–128. Oxford: 1967.

    Google Scholar 

  • Pake, G.E.: Nuclear resonance absorption in hydrated crystals: Fine structure of the proton line. J. Chem. Phys. 16, 327–336 (1948).

    Article  CAS  Google Scholar 

  • Paré, X.: Nouvelles expériences de résonance magnétique nucléaire dans les zéolithes. In: Proc. of the 11 th Colloque Ampère, Eindhoven 1962, p. 658–662. Amsterdam: 1963. R: Adsorbents: Edingtonite and stilbite.

    Google Scholar 

  • Paré, X., Ducros, P.: Étude par résonance magnétique nucléaire de l’eau dans le bérge. Bull. Soc. Franc. Minéral. Crist. 87, 429–433 (1964).

    Google Scholar 

  • Paré, X.: Étude par résonance magnétique nucléaire de l’eau adsorbée dans des monocristaux d’alumino-silicates naturels. Thèse, Grenoble (1965). R: Chabasite, edingtonite, stilbite, beryl.

    Google Scholar 

  • Parravano, C., Baldeschwieler, J.D., Boudart, M.: Diffusion of water in zeolites. Science 155, 1535–1536 (1967). R: In these experiments the diffusion between zeolite grains has not been taken into account, cf. (Kärger 1971).

    Article  CAS  Google Scholar 

  • Pasemann, L., Schneider, H.: Calculation of spectral density for translational nuclear spin diffusion. J. Magn. Res. (in the press).

    Google Scholar 

  • Pfeifer, H.: Der Translationsanteil der Protonenrelaxation in wäßrigen Lösungen paramagnetischer Ionen. Ann. Phys. (Leipzig) 8, 1–8 (1961).

    Google Scholar 

  • Pfeifer, H., Michel, D.: The effect of the surface on nuclear magnetic relaxation in liquids. In: Proc. of the 13th Coll. Ampère, Leuven 1964, p. 414–416. Amsterdam: 1965. R: cf. (Michel 1965).

    Google Scholar 

  • Pfeifer, H., Sames, D., Sprinz, H.: Proton magnetic relaxation in dilute solutions of paramagnetic ions. Molec. Phys. 11, 591–596 (1966). R: N P = number of protons per cm3, N I = number of paramagnetic ions per cm3.

    Article  CAS  Google Scholar 

  • Pfeifer, H., Winkler, H., Freude, D.: Temperature dependence of proton relaxation in benzene sorbed on silica gel. In: Bull. 14th Coll. Ampère, Ljubljana 1966, p. 1145–1146. Amsterdam: 1967. R: cf. (Freude 1966).

    Google Scholar 

  • Pfeifer, H., Przyborowski, F., Schirmer, W, Stach, H.: Kernspinresonanzmessungen an Zeolithen. Z. Phys. Chem. (Leipzig) 236, 345–361 (1967). R: Some of the results must be modified due to dominant proton-electron interaction, cf. (Deininger 1969, 1970).

    CAS  Google Scholar 

  • Pfeifer, H.: Nuclear magnetic resonance and relaxation study of adsorbed molecules. Second Intern. Symp. on Magn. Res., Săo Paulo (1968).

    Google Scholar 

  • Pfeifer, H., In: Paramagnetic Resonance 1944–1969. (Jubelee Conference on Paramagnetic Resonance, Kazan 1969) 255–261, Mosow 1971 (in Russian).

    Google Scholar 

  • Pfeifer, H., Staudte, B.: Der Einfluß von adsorbiertem Benzol auf die kernmagnetische Resonanz von Oberflächenhydroxylgruppen. Z. Naturforsch. 23a, 775 (1968).

    Google Scholar 

  • Pfeifer, H., Staudte, B.: The influence of adsorbed molecules on nuclear magnetic resonance of surface OH groups. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p. 222–226 (1969).

    Google Scholar 

  • Pickett, J. H., Rogers, L.B.: High resolution proton magnetic resonance of liquids adsorbed on a pyrogenic silica. Analyt. Chem. 39, 1872–1874 (1967). R: revised discussion cf. (Pickett 1970a).

    Article  CAS  Google Scholar 

  • Pickett, J. H., Rogers, L.B.: Effects of adsorbent properties on nuclear magnetic resonance line widths of adsorbates. Separation Sci. 5, 11–22 (1970). R: Systematic study of a series of silicas of different porosity.

    Article  CAS  Google Scholar 

  • Pickett, J. H., Lochmuller, C.H., Rogers, L.B.: Nuclear magnetic resonance measurements of line width, chemical shift, and intensity for molecules adsorbed on silica. Separation Sci. 5, 23–50 (1970).

    Article  CAS  Google Scholar 

  • Poole, C.P., MacIver, D.S.: Nuclear magnetic resonance of chromia-alumina catalysts. In: Adv. Catalysis 17, p. 279–289. New York: 1967.

    Google Scholar 

  • Powles, J.G., Figgins, R.: A note on the spin-lattice relaxation of nuclei in liquids. Ann. Phys. (Leipzig) 19, 84–87 (1967). R: cf. (Fenzke, 1967).

    CAS  Google Scholar 

  • Przyborowski, F., Pfeifer, H., Reessing, F.: NMR-studies of water protons in manganese exchanged 13X-zeolites. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p.227–231 (1969). R: NMR was used to localize Mn2+ in zeolites.

    Google Scholar 

  • Putzer, D.: Impulsspektrometrische Untersuchung der Protonenspinresonanz des zeolithisch gebundenen Wassers an Gismondin. Dissertation, Frankfurt/Main (1969).

    Google Scholar 

  • Rakos, M.: The nuclear magnetic resonance of water sorbed on sodium polymetacrylate. Czech. J. Phys. B 16, 864–866 (1966). R: Eq. (3) should be revised due to Zimmerman’s theory (Zimmerman, 1957).

    Article  Google Scholar 

  • Reinhardt, H.: Selbsttätige Spektralauswertung der Breitlinien-Protonenresonanz-Kurven bei der Feuchtemessung von Braunkohle. Exp. Techn. Phys. 17, 517–526 (1969).

    CAS  Google Scholar 

  • O’Reilly, D.E., Leftin, H.P., Hall, W.K.: Nuclear magnetic resonance of proton dilute silica gel and silica-aluminas. J. Chem. Phys. 29, 970–971 (1958).

    Article  Google Scholar 

  • O’Reilly, D.E.: Magnetic resonance techniques in catalytic research. Advan. Catalysis 12, 31–116 (1960).

    Article  Google Scholar 

  • O’Reilly, D.E., Poole, C.P.: Nuclear magnetic resonance of alumina containing transition metals. J. Chem. Phys. 67, 1762–1771 (1963). R 1: Distribution of chromia on the surface and adsorption of water. R 2: Eqs. (20), (21) must be substituted by the exact formulae of Beckert (Beckert, 1967, 1969).

    Article  Google Scholar 

  • O’Reilly, D.E., Peterson, E.M., Tung Tsang: Nuclear magnetic resonance and nonexponential spin-lattice relaxation in ferroelectric ammonium fluoroberyllate. Phys. Rev. 160, 333–342 (1967).

    Article  Google Scholar 

  • O’Reilly, D.E., Self-diffusion coefficients and rotational correlation times in polar liquids. J. Chem. Phys. 49, 5416–5420 (1968).

    Article  Google Scholar 

  • Resing, H. A., Thompson, J.K., Krebs, J.J: Nuclear magnetic resonance relaxation times of water adsorbed on charcoal. J. Phys. Chem. 68, 1621–1627 (1964).

    Article  CAS  Google Scholar 

  • Resing, H.A.: Apparent phase-transition effect in the NMR spin-spin relaxation time caused by a distribution of correlation times. J. Chem. Phys. 43, 669–678 (1965). R: cf. also (Resing, 1966).

    Article  CAS  Google Scholar 

  • Resing, H.A.: Thompson, J. K., Krebs, J.J.: Nuclear magnetic resonance relaxation in adsorbed benzene and water: Apparant phase transition effects. In: Molec. Relax. Processes, p. 145–150. London-New York: 1966.

    Google Scholar 

  • Resing, H.A., Thompson, J. K.: NMR relaxation in adsorbed molecules. V. SF6 on faujasite: Dipolar coupling of fluorine nuclei to ferric-ion impurities. J. Chem. Phys. 46, 2876–2880 (1967).

    Article  CAS  Google Scholar 

  • Resing, H.A.: Nuclear magnetic resonance relaxation of molecules adsorbed on surfaces. Advan. Mol. Relaxation Processes 1, 109–154 (1967/68).

    Article  Google Scholar 

  • Resing, H.A.: Thompson, J.K.: NMR relaxation of water protons in zeolites; effect of paramagnetic impurities. In: Proc. of the 15 th Coll. Ampère, Grenoble 1968, p. 237–241. Amsterdam: 1969.

    Google Scholar 

  • Reuben, J., Fiat, D., Folman, M.: NMR relaxation times of adsorbed ammonia. J. Chem. Phys. 45, 311–320 (1966). R: The interpretation should be checked by measuring the temperature dependence of T 1 and T 2.

    Article  CAS  Google Scholar 

  • Richter, B.: Diplomarbeit, Sektion Physik der Karl-Marx-Universität Leipzig (1970).

    Google Scholar 

  • Riou, A., Gradsztajn, S., Conard, J., Donnet, J.-B., Couderc, P., Papirer, E.: Application de la résonance magnétique nucléaire à l’étude de la texture poreuse des charbons. Compt. Rend. 268 C, 297–299 (1969). R: Influence of activation and of oxidation of the charcoal.

    CAS  Google Scholar 

  • Rouquerol, J.: Étude de l’eau de constitution de plusieurs oxydes à grande surface spécifique (glucine, alumine, silice-alumine). Thèse, Paris (1964).

    Google Scholar 

  • Runnels, L.K.: Nuclear spin-lattice relaxation in three-spin molecules. Phys. Rev. 134, A 28–A 36 (1964).

    Article  Google Scholar 

  • Saito, T., Kotera, Y.: Some observations on the calcination process of precipitated magnesium hydroxide. Bull. Chem. Soc. Japan 36, 474–475 (1963).

    Article  CAS  Google Scholar 

  • Sames, D.: Thermische Relaxation in Flüssigkeiten. Ann. Phys. (Leipzig) 15, 363–382 (1965).

    CAS  Google Scholar 

  • Sames, D., Michel, D.: Protonenrelaxation in Mn2+ -Lösungen, Einfluß der Hyperfeinkopplung. I. Theorie. Ann. Phys. (Leipzig) 18, 353–378 (1966).

    CAS  Google Scholar 

  • Sanada, Y., Honda, H, Nishioka, A.: Temperature dependence of nuclear magnetic resonance absorption in coal. J. Appl. Polymer. Sci. 6, 94–97 (1962).

    Article  CAS  Google Scholar 

  • Saraf, D.N., Fatt, I.: Effect of electrolytes on moisture determination by nuclear magnetic resonance. Nature 214, 1219–1220 (1967). R: This effect should be negligible if a pulse apparatus (with low Q circuit) is used.

    Article  CAS  Google Scholar 

  • Saraf, D.N., Kumar, J., Fatt, I.: Determination of wettability of porous materials by the nuclear magnetic resonance technique. Indian J. Technology 8, 125–130 (1970).

    CAS  Google Scholar 

  • Sasaki, M., Kawai, T., Hirai, A., Hashi, T., Odajima, A.: A study of sorbed water on cellulose by pulsed NMR technique. J. Phys. Soc. Japan 15, 1652–1657 (1960).

    Article  CAS  Google Scholar 

  • Saunders, P.C., Hightower, J.W.: Catalytic sites for deuterium exchange with benzene over alumina. J. Phys. Chem. 74, 4323–4329 (1970).

    Article  Google Scholar 

  • Sčerbakov, V.N., Gabuda, S.P., Seryšev, S.A.: Influence of diffusion of water molecules in porous crystals on NMR line width of 7Li, 23Na, and 27A1 (in Russian). Fiz. Twerd. Tela 12, 3061–3063 (1970). R: The quantitative results concerning water diffusion, which were derived indirectly, are in contrast to direct measurements: (Kärger, 1971 d).

    Google Scholar 

  • Schmiedel, H.: The line shape problem in nuclear magnetic resonance. Phys. Letters 29 A, 682–683 (1969).

    Article  CAS  Google Scholar 

  • Schmiedel, H., Schneider, H.: Problems in NMR-line shape calculating for solids. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p. 140–148 (1969).

    Google Scholar 

  • Schmiedel, H.: Theorie der Linienform der kernmagnetischen Resonanz im Festkörper. Dissertation, Karl-Marx-Universität Leipzig (1969).

    Google Scholar 

  • Schmiedel, H., Freude, D., Gründer, W.: Measurements of correlation times by means of the temperature dependence of coherent pulse averaging effects in NMR. Phys. Letters A 34, 162–163 (1971).

    Article  CAS  Google Scholar 

  • Schneider, H.: Kernmagnetische Relaxation von Drei-Spin-Molekülen im flüssigen oder adsorbierten Zustand. I. Ann. Phys. (Leipzig) 13, 313–324 (1964).

    Article  Google Scholar 

  • Schneider, H.: Kernmagnetische Relaxation von Dreispinmolekülen im flüssigen oder adsorbierten Zustand bei anisotroper Bewegung. Z. Naturforsch. 19a, 510–512 (1964).

    CAS  Google Scholar 

  • Schneider, H.: Kernmagnetische Relaxation von Drei-Spin-Molekülen im flüssigen oder adsorbierten Zustand. II. Ann. Phys. (Leipzig) 16, 135–146 (1965).

    CAS  Google Scholar 

  • Schneider, H., Blicharski, J.S.: Kernmagnetische Relaxation von Mehrspinmolekülen mit ungleichen Kernen (II). Ann. Phys. (Leipzig) 23, 139–143 (1969).

    CAS  Google Scholar 

  • Selwood, P.W., Schroyer, F.K.: Proton relaxation and catalyst accessibility. Disc. Faraday. Soc. 8, 337–344 (1950). R: ferric oxide, chromic oxide, and cupric oxide supported on alumina.

    Article  Google Scholar 

  • Seyd, W.: Untersuchungen zur translatorischen Bewegung von Propan an 13X-Zeolith mit Hilfe der magnetischen Kernresonanz. Dissertation, Karl-Marx-Universität Leipzig (1969).

    Google Scholar 

  • Sharma, H.D., Subramanian, N.: Determination of water in ion-exchange resins: anion exchange resins. Analyt. Chem. 42, 1287–1290 (1970).

    Article  CAS  Google Scholar 

  • Shaw, T. M., Elsken, R.H.: Nuclear magnetic resonance absorption in hygroscopic materials. J. Chem. Phys. 18, 1113–1114(1950).

    Article  CAS  Google Scholar 

  • Shaw, T. M., Elsken, R. H.: Investigation of proton magnetic resonance line width of sorbed water. J. Am. Chem. Soc. 21, 565–566 (1953).

    CAS  Google Scholar 

  • Shaw, T. M., Elsken, R.H.: Techniques for nuclear magnetic resonance measurements on granular hygroscopic materials. J. Appl. Phys. 26, 313–317 (1955).

    Article  CAS  Google Scholar 

  • Shdanov, S.P., Kärger, J., Pfeifer, H., Schirmer,W.: Investigation of diffusion processes in 13 X zeolites using NMR pulsed gradient techniques (in Russian). Žurn. Fiz. Chim. (in the press).

    Google Scholar 

  • Sheldrick, G.M.: The second moment of the broad-line NMR absorption of a proton bounded to a quadrupolar nucleus. Molec. Phys. 13, 399–400 (1967).

    Article  CAS  Google Scholar 

  • Shimizu, H: Effect of molecular shape on nuclear magnetic relaxation. J. Chem. Phys. 37, 765–778 (1962).

    Article  CAS  Google Scholar 

  • Siegle, G.: Kernmagnetische Resonanzsignale in Festkörpern mit zwei verschiedenen Spinsorten. Z. Naturforsch. 23a, 556–562 (1968). R: cf. p. 560.

    Google Scholar 

  • Slichter, C.P.: Principles of magnetic resonance with examples from solid state physics, Chapter 6. New York: 1963.

    Google Scholar 

  • Snyder, L.R., Ward, J.W.: The surface structure of porous silicas. J. Phys. Chem. 70, 3941–3952 (1966).

    Article  CAS  Google Scholar 

  • Spooner, R.B., Selwood, P.W.: Nuclear induction and the structure of catalytically active solids. J. Am. Chem. Soc. 71, 2184–2187 (1949). R: Iron and neodymiumoxides supported on γ-alumina, and manganese dioxide supported on titanium dioxide.

    Article  CAS  Google Scholar 

  • Sprinz, H.: Protonenrelaxation in Mn2+-Lösungen, Einfluß der Hyperfeinkopplung. II. Experimente. Ann. Phys. (Leipzig) 20, 168–186 (1967).

    CAS  Google Scholar 

  • Staudte, B.: Dissertation, Karl-Marx-Universität Leipzig (in prep.).

    Google Scholar 

  • Steenwinkel, R. van: The spin lattice relaxation of the nuclear dipolar energy in some organic crystals with slow molecular motions. Z. Naturforsch. 24a, 1526–1531 (1969).

    Google Scholar 

  • Stejskal, E.O., Tanner, J.E.: Spin diffusion measurements: Spin echoes in the presence of a time-dependent field gradient. J. Chem. Phys. 42, 288–292 (1965).

    Article  CAS  Google Scholar 

  • Sternlicht, H.: Nuclear relaxation induced by paramagnetic ions having anisotropic g-factors. J. Chem. Phys. 42, 2250–2251 (1965).

    Article  CAS  Google Scholar 

  • Šulgin, E.I., Abramova, E.A.: Mobility of water adsorbed on different cellulose acetates (in Russian). Žurn. Prikl. Chim. 42, 476–478 (1969). R: Different ratios of acetate and cellulose (0–2.3).

    Google Scholar 

  • Šušić, M.V., Vučelić, D.R., Paušar, S.V., Karaulić, D.B., Milaković-Vučelić, V.: Nuclear magnetic resonance method for the determination of specific surface area. Study of the state of adsorbed polar vapors on zeolite linde 5 A. Chem. 73, 1975–1984 (1969). R: The concentration dependence of line width (∝ T ‒1 2) depends on temperature (cf. (Gutsze, 1971)) and therefore the results derived here simplify the problem, which is much more complicated.

    Google Scholar 

  • Šušić, M.V., Vučelić, D.R., Karaulić, D.B., Pausar, S.V.: Investigation of propylene sorption on zeolites 4 A, 5 A and 13X by the NMR method. Surface Sci. 18, 204–212 (1969). R: It seems necessary to study the temperature dependence and the influence of paramagnetic impurities.

    Article  Google Scholar 

  • Swift, T.J., Connicr,R.E.: NMR-relaxation mechanisms of 17O in aqueous solutions of paramagnetic cations and the lifetime of water molecules in the first coordination sphere. J. Chem. Phys. 37, 307–320 (1962)

    Article  CAS  Google Scholar 

  • Swift, T.J., Connicr,R.E.: NMR-relaxation mechanisms of 17O in aqueous solutions of paramagnetic cations and the lifetime of water molecules in the first coordination sphere. R: Erratum J. Chem. Phys. 41, 2553–2554 (1964).

    CAS  Google Scholar 

  • Swift, T.J., Weinberger, G.P.: Proton magnetic resonance determination of the primary number of nickel (II) in aqueous solution. J. Am. Chem. Soc. 90:8, 2023–2026 (1968).

    Article  CAS  Google Scholar 

  • Tanner, J.E.: Pulsed field gradients for NMR spin-echo diffusion measurements. Rev. Sci. Instrum. 36, 1086–1087 (1965).

    Article  CAS  Google Scholar 

  • Tanner, J.E., Stejsral, E.O.: Restricted self-diffusion of protons in colloidal systems by the pulsed-gradient, spin-echo method. J. Chem. Phys. 49, 1768–1777 (1968).

    Article  CAS  Google Scholar 

  • Tarasevič, Ju. I., Ovčarenko, F.D., Matjaš, I.V., Manr, V.V., Torjanir, A.I.: Nuclear magnetic resonance of water protons adsorbed on montmorillonite (in Russian). Dokl. Akad. Nauk SSSR 156, 926–928 (1964).

    Google Scholar 

  • Thompson, J.K., Krebs, J.J., Resing, H.A.: NMR relaxation times of benzene adsorbed on charcoal: Molecular rotation and diffusion. J. Chem. Phys. 43, 3853–3865 (1965). R: cf. (Thompson, 1967).

    Article  CAS  Google Scholar 

  • Thompson, J.K., Resing, H.A.: Surface heterogeneity of a charcoal: Comparison of results of NMR and adsorption methods. J. Chem. Phys. 47, 3685–3686 (1967).

    Article  CAS  Google Scholar 

  • Thompson, J.K., Resing, H.A.: A study of surface diffusion by NMR: Sulfur hexafluoride adsorbed on synthetic faujasite. J. Colloid Interf. Sci. 26, 279–286 (1968).

    Article  CAS  Google Scholar 

  • Timsit, R.S., Daniels, J.M., May, A.D.: Nuclear relaxation of 3He gas on various solid surfaces. Canad. J. Phys. 49, 560–575 (1971).

    Article  CAS  Google Scholar 

  • Timur, A., Fatt, I.: Fluid flow in porous media studied by a nuclear magnetic resonance technique. Science 146, 1162–1163 (1964).

    Article  CAS  Google Scholar 

  • Timur, A.: Fluid displacement phenomena in porous media observed by a wide-line nuclear magnetic resonance method. Nature 209, 493–494 (1966).

    Article  CAS  Google Scholar 

  • Toledo, R., Steinberg, M.P., Nelson, A.I.: Determination of bound water by nuclear magnetic resonance. J. Food Sci. 33, 315–317 (1968).

    Article  CAS  Google Scholar 

  • Tomita, K.: Progr. Theor. Phys. 8, 138 (1952).

    Article  Google Scholar 

  • Tomita, K.: States of solid methane as inferred from nuclear magnetic resonance. Phys. Rev. 89, 429–438 (1953).

    Article  CAS  Google Scholar 

  • Tomita, K.: A general theory of magnetic resonance saturation. Progr. Theor. Phys. 19, 541–579 (1958).

    Article  Google Scholar 

  • Torrey, H.C.: Nuclear spin relaxation by translational diffusion. Phys. Rev. 92, 962–969 (1953).

    Article  CAS  Google Scholar 

  • Touillaux, R., Salvador, P., Vandermeersche, C., Fripiat, J.J.: Study of water layers adsorbed on Na- and Ca-montmorillonite by the pulsed nuclear magnetic resonance technique. Israel J. Chem. 6, 337–348 (1968)

    CAS  Google Scholar 

  • Touillaux, R., Salvador, P., Vandermeersche, C., Fripiat, J.J.: R: Eqs. (5) must be substituted by the exact formulae of Beckert (Beckert, 1967, 1969).

    Google Scholar 

  • Tovbina, Z.M., Kuc, V.S., Strelko, V.V.: Proton relaxation time of water adsorbed on silica gels of different pore structure (in Russian). Žurn. Teor. Eks. Chini. 5, 848–850 (1969). R: The formula used is not appropriate to the problem.

    CAS  Google Scholar 

  • Tulbovič, B.I., Slisarenko, F.A., Kljaev, V.I., Sorokin, S.I.: Proton magnetic resonance of water and n-alkanes adsorbed on silica gels of different pore structure (in Russian). Izv. Vys. Yceb. Zaved. SSSR Chim. i. Chimic. Tech. 5, 735–737 (1966). R: Dependence of T 1 and T 2 on the pore radius.

    Google Scholar 

  • Uebersfeld, J., Jacubowicz, M.: Double magnetic resonance of fluids adsorbed on coals. In: Proc. of the 4th Conf. on Carbon, Buffalo, p. 267–270 (1960).

    Google Scholar 

  • Uebersfeld, J., Legrand, A.P., Estrade-Szwarckopf, H.: Carbons surfaces study by dynamic polarization and nuclear relaxation. Colloqu. Am. Chem. Soc. Miami, April 1967.

    Google Scholar 

  • Umarchobžaev, R.M., Jevskaja, N.M., Matveec, L.V., Gromov, V.A.: Investigation of the chemical shift of water adsorbed on silica gel. (in Russian). Žurn. Fiz. Chim. 42, 2141–2142 (1968).

    Google Scholar 

  • Uytterhoeven, J.B., Schoonheydt, R., Fripiat, J.J.: London: Chemical Society 1966. International Symposium on Reaction Mechanisms of Inorganic solids, Abstract 5–2.

    Google Scholar 

  • Valijev, K.A., Zaripov, M.M.: Effect of the shape of molecules on the magnetic relaxation rate in liquids I (in Russian). Žurn. Eks. Teor. Fiz. 42, 503–510 (1962).

    Google Scholar 

  • Valijev, K.A., Timerov, R.Ch., Julmetjev, R.M.: Effect of shape of molecule on the rate of magnetic relaxation in liquids II (in Russian). Žurn. Eks. Teor. Fiz. 44, 522–529 (1963).

    Google Scholar 

  • VanVleck, J.H.: Dipolar broadening of magnetic resonance lines in crystals. Phys. Rev. 74, 1168–1183(1948).

    Article  Google Scholar 

  • Versmold, H.: Time correlation functions for internal and anisotropic rotational motion of molecules. Z. Naturforsch. 25a, 367–372 (1970).

    Google Scholar 

  • Volarovič, M.P., Ščukin, A.I.: The application of NMR to determine moisture of disperse systems and the nature of bound water (in Russian). Koll. Žurn. 26, 386–390 (1964).

    Google Scholar 

  • Watanabe, K., Sasaki, T.: Nuclear magnetic resonance study on the water in set cement. Kolloid-Z. 172, 185–186 (1960).

    Article  Google Scholar 

  • Waugh, J.S., Huber, L.M., Haeberlen, U.: Approach to high-resolution NMR in solids. Phys. Rev. Letters 20, 180–182 (1968).

    Article  CAS  Google Scholar 

  • Webster, R.K., Jones, T.L., Anderson, P.J.: Proton magnetic resonance studies of adsorbed water on magnesium oxide. Proc. Brit. Ceramic Soc. 5, 153–165 (1965).

    CAS  Google Scholar 

  • Weinstock, H., Long, C.E.: Search for a magnetically ordered state of adsorbed 3He. In: Proc. 9th Int. Conf. Low Temp. Phys. 1964, p. 366–367 (1965).

    Google Scholar 

  • Winkler, H.: Messungen kernparamagnetischer Relaxationszeiten von durch Aluminiumoxyd sorbiertem Wasser. Koiloid-Z. 161, 127–129 (1958).

    Article  CAS  Google Scholar 

  • Winkler, H.: NMR of water sorbed on A12O3. Arch. Sci. 12, fasc. Spéc. 161–163 (1959).

    CAS  Google Scholar 

  • Winkler, H.: Über die kernparamagnetischen Relaxationszeiten von Wasser, das durch Aluminiumoxyd sorbiert ist. Z. Naturforsch. 16a, 780–790 (1961).

    CAS  Google Scholar 

  • Winkler, H.: Untersuchung von Adsorptionserscheinungen mit Kerninduktionsmethoden. In: Bull. 10. Colloque Ampère, Leipzig 1961, p. 219–243 (1961).

    Google Scholar 

  • Winkler, H.: Anwendung von magnetischen Kernresonanz- und dielektrischen Methoden auf die Untersuchung von Festkörperoberflächen und daran adsorbierten Molekülen. Wiss. Z. Karl-Marx-Univ. 14, 913–924 (1965).

    CAS  Google Scholar 

  • Winkler, H.: Kernmagnetische Resonanz und Relaxation von Festkörperoberflächen und daran adsorbierten Molekülen. Habilitationsschrift (Anhang), Karl-Marx-Universität Leipzig (1966).

    Google Scholar 

  • Winkler, H., Nagel, M., Michel, D., Pfeifer, H.: Proton relaxation analysis with benzene adsorbed on silicagel. In: Tagung Hochfrequenzspektroskopie Leipzig 1969, p. 234–248 (1969).

    Google Scholar 

  • Winkler, H., Pfeifer, H.: NMR investigations of the interaction between surface OH groups of silicagel and benzene molecules adsorbed thereon. In: Proc. of the XV th Coll. Ampère, Grenoble 1968, p. 235–236 (1969).

    Google Scholar 

  • Winkler, H., Nagel, M., Michel, D., Pfeifer, H.: Protonenrelaxationsanalyse am System Benzol-Silikagel. Z. Phys. Chem. (Leipzig) 248, 17–26 (1971).

    CAS  Google Scholar 

  • Woessner, D.E.: Spin relaxation processes in a two-proton system undergoing anisotropic reorientation. J. Chem. Phys. 36, 1–4 (1962).

    Article  CAS  Google Scholar 

  • Woessner, D.E.: Nuclear spin relaxation in ellipsoids undergoing rotational Brownian motion. J. Chem. Phys. 37, 647–654 (1962).

    Article  CAS  Google Scholar 

  • Woessner, D.E., Zimmerman, J.R.: Nuclear transfer and anisotropic motional spin phenomena: Relaxation time temperature dependence studies of water adsorbed on silica gel. IV. J. Phys. Chem. 67, 1590–1600 (1963).

    Article  CAS  Google Scholar 

  • Woessner, D.E.: Temperature dependences of nuclear-transfer and spin-relaxation phenomena of water adsorbed on silica gel. J. Chem. Phys. 39, 2783–2787 (1963).

    Article  Google Scholar 

  • Woessner, D.E.: Nuclear-spin relaxation phenomena of adsorbed molecules. Temperature-dependence studies of benzene adsorbed on silica gel. J. Phys. Chem. 70, 1217–1230 (1966).

    Article  CAS  Google Scholar 

  • Woessner, D.E., Snowden, B.S.: NMR doublet splitting in aqueous montmorillonite gels. J. Chem. Phys. 50, 1516–1523 (1969).

    Article  CAS  Google Scholar 

  • Woessner, D.E., Snowden, B.S.: A study of the orientation of adsorbed water molecules on montmorillonite clays by pulsed NMR. J. Colloid Interf. Sci. 30, 54–68 (1969).

    Article  CAS  Google Scholar 

  • Woessner, D.E., Snowden, B.S., Meyer, G.H.: A tetrahedral model for pulsed nuclear magnetic resonance transverse relaxation: application to the clay-water system. J. Colloid Interf. Sci. 34, 43–52 (1970).

    Article  CAS  Google Scholar 

  • Wu, T.H.: A nuclear magnetic resonance study of water in clay. J. Geophys. Res. 69, 1083–1091 (1964).

    Article  CAS  Google Scholar 

  • Zeidler, M.D.: Umorientierungszeiten, Sprungzeiten und Quadrupolkopplungskonstanten in einigen organischen Flüssigkeiten aus kernmagnetischen Relaxationszeitmessungen. Ber. Bunsenges. Phys. Chem. 69, 659–669 (1965).

    CAS  Google Scholar 

  • Zimmerman, J.R., Holmes, B.G., Lasater, J.A.: A study of adsorbed water on silica gel by nuclear resonance techniques. J. Phys. Chem. 60, 1157–1161 (1956).

    Article  CAS  Google Scholar 

  • Zimmerman, J.R., Brittin, W.E.: Nuclear magnetic resonance studies in multiple phase systems: Lifetime of a water molecule in an adsorbing phase on silica gel. J. Phys. Chem. 61, 1328–1333 (1957).

    Article  CAS  Google Scholar 

  • Zimmerman, J.R., Lasater, J.A.: Nuclear magnetic resonance relaxation studies of adsorbed water on silica gel. III. J. Phys. Chem. 62, 1157–1163 (1958).

    Article  CAS  Google Scholar 

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Pfeifer, H. (1972). Nuclear Magnetic Resonance and Relaxation of Molecules Adsorbed on Solids. In: Diehl, P., Fluck, E., Kosfeld, R. (eds) NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte. NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte, vol 7. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-65312-4_2

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