Abstract
High resolution NMR spectra of liquids are usually described in terms of a hamiltonian which consists of two terms, i.e. the Zeeman energy term and a term containing two types of molecular constants. These are the shielding constants σ i of the nuclei and the indirect spin-spin couplings Jij between pairs of nuclei i and j. These constants are in fact averaged tensors, the averaging mechanism being the Brownian motion.
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Hilbers, C.W., MacLean, C. (1972). NMR of Molecules Oriented in Electric Fields. In: Diehl, P., Fluck, E., Kosfeld, R. (eds) NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte. NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte, vol 7. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-65312-4_1
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