Abstract
In the preceding chapter we saw how clusters are formed on surfaces starting from atom deposition. Nucleation and aggregation processes determine the surface morphology and these are governed by diffusion barriers on terraces, kinks and steps. Cluster formation in this context is strongly determined not by the minimisation of the total energy of the cluster alone but rather by the total energy and the energy barriers of the cluster-surface system. These two are fundamentally different. An example for strongly interacting surfaces is given below: the binding energy of a silver dimer Ag2 in the gas phase is 1.6 eV [1], which is a medium strength bond. If this dimer is formed on a Pt(111) surface, the energy corresponding to the bond reduces roughly by a factor of 10 [2]. The gas phase structure of Ag7 is a bipyramidal pentagon [3], while Ag7 on Pt(111) has been calculated to be a compact two-dimensional island [4].
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Harbich, W. (2000). Collision of Clusters with Surfaces: Deposition, Surface Modification and Scattering. In: Metal Clusters at Surfaces. Springer Series in Cluster Physics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-57169-5_4
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