Abstract
In an atom, ionization can be caused not only by electron impact, but also by energetic photons. In the photoionization process, the incident photon is absorbed and a single electron is ejected. It is a one-step process, A + hv → A + + e-. It plays an important role in the absorption of X-rays in matter. During the last 20 years, X-ray photoelectron spectroscopy (XPS) has become a powerful tool to probe the interactions within atoms, molecules and solids, starting with the work of Siegbahn et al. [4.1].
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Agarwal, B.K. (1991). Secondary Spectra and Satellites. In: X-Ray Spectroscopy. Springer Series in Optical Sciences, vol 15. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-38668-1_4
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