Abstract
Dissolution of soluble substrates such as gypsum presents a major hazard to dams in many parts of the world. This research simulates hypothesised conditions beneath the Mosul Dam, northwest Iraq, where collapse of a karstic system associated with continuous fresh water supply from its reservoir is a recognised problem. Gypsum rocks from northern Iraq and similar rocks from Bantycock gypsum mine, UK, were analysed for short-term mechanical response following immersion (5–50 weeks) and long-term loading during immersion (maximum 50 weeks). New experimental devices were developed from a conventional oedometer. Cylinder samples provided a proxy for massive gypsum strata. Samples were permanently submerged at atmospheric water pressure, with groundwater recharge, flow and dissolution simulated by regular changes of water. Stress on each sample was progressively increased to a maximum of 2,688 kPa. Small increases in strain were recorded by the end of each test but no failures occurred within 60 days. However, notable failure due to atmospheric water pressure and axial stress occurred over long time periods. Visible physical changes included a decrease in sample mass and volume. Similar change was recorded in ultrasonic velocities. These indicate that gypsum collapse risk beneath dams requires prolonged exposure to dissolution. The modified device performed well and was robust, and demonstrates that such a modification can provide a simple low cost system for conducting laboratory creep tests on weak rocks.
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1 Introduction
Gypsum rock underly more than 20 % of the earth surface (Johnson 2005) with seven million km2 underlain by highly soluble gypsum (CaSO4.2H2O) bearing rocks in a large number of countries (Cooper 2006). Its solubility in pure water is 2.531 g/l at 20 °C, around 140 times lower than halite and 4 times larger than CaCO3 (Johnson 2006).
Gypsum rock is common in Iraq, mainly in the Mid-Miocene Fatha (Lower Fars) Formation (Jassim and Goff 2006) and is associated with significant geotechnical problems. This is particularly the case in sites with high hydraulic gradients such as near dams (Salih 2013) e.g. the Mosul Dam, which is underlain by thick gypsum beds which are severely affected by dissolution and karstification, including general subsidence and sinkholes.
While cavity formation due to dissolution is known, mechanical change leading to creep and brittle failure has received little attention. This is significant as the formation of cavities will transfer load to surrounding, potentially weakened gypsum.
Gypsum resistance to compression is not high. Its average uniaxial compressive strength (UCS) is around 13.73 MPa, but it demonstrates considerable variability between 9.41 to 15.99 MPa (Kenneth 2005). While, others found their UCS is medium/moderately strength, varied from 24.1 to 40.8 and 18 to 36 MPa generally (Bell 1981; Karacan and Yilmaz 1997).
Clearly, exposure to water is a key control on gypsum dissolution (Jassim and Goff 2006). The chemical composition of this water is important and cause significant variability in rates. As a result, to control this, distilled water has commonly been used in experimental studies on dissolution. The degree of saturation also affects gypsum strength as measured in mechanical tests (Ali 1979; Elizzi 1976; Ergun and Yilmaz 2000; Gao et al. 2011; Sconnenfeld 1984), as may the soaking period (Gao et al. 2011; Sconnenfeld 1984).
2 Materials and Methods
The collection of gypsum in Iraq was limited by security concerns, though some samples could be collected from Bazyan, North of Iraq. Similar gypsum occurs in the highest strata of the Triassic Norian Mercia Mudstone Group (Cropwell Bishop Formation) at Bantycock mine (Worley and Reeves 2007). Both of sites feature thick gypsum rock layer, similar to those beneath the Mosul Dam.
NX cylinder samples (54 mm diameter and L/D = 2.5) were prepared following common practice (ASTM 2010; Bieniawski et al. 1978; Dreybrodt et al. 2002). A suitable loading rate of 0.025 MPa/s was determined following ASTM and ISRM standards (ASTM 2010; Bieniawski et al. 1978). A circumferential extensometer was used in the mid height of cylinders to calculate the radial strain (Fig. 139.2c). Ultrasonic observations were recorded for each sample in air dry state and after each of the immersion periods.
Unloaded gypsum samples were slowly saturated by vacuum, then soaked at atmospheric pressure at 5, 10, 15, 30 and 50 weeks. Three samples were used at each time interval for short-term loading tests. Continuous loading (2,688 kPa) using a modified oedometer was also applied to samples for 50 weeks. During soaking, the water was changed every 7 days and conductivity measurements taken. A full account of the methodology can be found in Salih (2013).
4 Discussion
It is clear that saturation weakens gypsum rock, and this weakness progressively develops over time where there is a flow of water. This is relevant to the context of dams, and other large structures, where groundwater flow is enhanced, and where fresh water is constantly being introduced to the gypsum.
All the samples showed signs of dissolution, manifested as a change in shape over time. This change in shape does not, however, explain all the weakening that took place. There must also be a contribution from changes taking place within the samples.
Several characteristics of the gypsum influence the rate of dissolution weakening. Iraqi samples dissolved at a faster rate that the UK samples. This appears to be due to the size of the gypsum crystals, which were larger in the samples from Bantycock mine.
The larger dissolution values of Iraqi samples under atmospheric pressure than white/Bantycock samples in short-term datasets (Fig. 139.1) were correlated with the effects of gypsum crystal size and shape in characterizing the dissolution process i.e. larger crystals dissolve less quickly than smaller crystals. Slight differences in impurities within the gypsum, as reflected by the different colours of gypsum from Bantycock (white and pink) may also contribute to differences in response e.g. Fig. 139.1a where the strength of the pink gypsum declines much more quickly than the white gypsum. The shape of internal structures, determined by cracks and fissures, may also be a factor as these allow fresh water to penetrate the gypsum. In addition, many of the cracks contain impurities that have different mechanical and chemical properties to the gypsum. Samples that were soaked without loading showed more evidence of weakening through crack-enhanced dissolution than samples under constant load for 50 weeks. This may be because the high load caused the cracks to close through simple translational movement and through small amounts of creep. It should be noted that the water was under atmospheric pressure during these tests. Under pressure conditions similar to those found beneath large dams such as at Mosul, water may well be able to penetrate thin cracks.
The research has a number of implications for large structures than both load the ground and modify groundwater flow, such as large dams:
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The role of percolating fresh water in enhancing dissolution is confirmed. The significant head difference induced by a dam can be expected to increase the potential for groundwater flow and increase the likelihood of cavity formation. Similar effects could be induced by localized dewatering, or by wetter conditions caused by climate change.
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Importantly, the dissolution does not just generate macro-cavities. There is also alteration of apparently intact gypsum which increases its potential for failure.
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Sometimes subtle differences in gypsum, such as impurities and crack frequency can have a significant impact on the timing of failure.
5 Conclusion
The research has shown that the evolving behavior of weak soluble rocks such as gypsum can be investigated in the laboratory over extended periods. It highlights that the hazard presented by such rocks is not just simply one of dissolution induced cavities. It is also a progressive weakening of the rock mass itself.
Clearly, the findings suggest that the risk of failure in large dams is a result of a more complex set of processes than may have been expected. This has implications for mitigation solutions. If the problem is perceived as just being caused by cavity formation, then a solution might be to simply fill the cavities with grout on an ad hoc basis. This ignores the weakening of the ‘solid’ gypsum—and may make the problem worse. Localized injections of grout are likely to deflect and focus groundwater flow on the intact gypsum. This creates a risk of enhanced generation of new cavities, and of forcing more water into the gypsum and so reducing its overall strength.
Other than removing dams such as that at Mosul and elsewhere—an unattractive option given the need for water and power—the only solution is a systematic approach to creating a deep impermeable barrier that will significantly slow, or even stop, the movement of fresh water through the gypsum rock. Such a solution will inevitably be expensive, and challenging to achieve, but the cost must be weighed up against the risk of losing an essential piece of infrastructure.
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Salih, N.B., Collins, P.E.F., Kershaw, S. (2015). Dissolution Influences on Gypsum Rock Under Short and Long-term Loading: Implications for Dams. In: Lollino, G., et al. Engineering Geology for Society and Territory - Volume 6. Springer, Cham. https://doi.org/10.1007/978-3-319-09060-3_139
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