Abstract
Ammonia synthesis is one of the most important processes operated by the chemical industry. Modern ammonia synthesis plants can produce up to 1800 tons of ammonia per day. Clearly, the design of the large reactors requires powerful and reliable calculation methods and the availability of a sound kinetic equation is an essential requirement. It is not only necessary for reactor design, but is also required to express catalyst performances generated from either laboratory or pilot plant experiments.
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References
C. Bokhoven, C. Van Heerden, R. Westrik, and P. Zwietering, in: Catalysis (P. H. Emmett, ed.), Vol. 3, p. 318, Reinhold, New York (1955).
M. Temkin and V. Pyzhev, Acta Physicochim. USSR 12, 327 (1940).
Ref. 1, p. 321.
M. Temkin, J. Phys. Chem. USSR 24, 1312 (1950).
A. Nielsen, J. Kjaer, and B. Hansen, J. Catal. 3, 68 (1964).
U. Guacci, F. Traina, G. Buzzi Ferraris, and R. Barisone, Ind. Eng. Chem., Prod. Des. Dev. 16, 166 (1977).
M. I. Temkin, N. M. Morozov, and E. N. Shapatina, Kinet. Catal. (Engl. Transi.) 4, 565 (1963).
G. W. Bridger and C. B. Snowdon, in: Catalyst Handbook, p. 141, Wolfe Scientific Books, London (1970).
I. A. Smirnof, N. M. Morozov, and M. I. Temkin, Dokl. Akad. Nauk SSSR 153, 386 (1963).
S. Brunauer, K. S. Love, and R. G. Keenan, J. Am. Chem. Soc. 64, 751 (1942).
A. Ozaki, H. S. Taylor, and M. Boudart, Proc. R. Soc. London, Scr. A 258, 47 (1960).
A. Nielsen, J. Kjaer, and B. Hansen, J. Catal. 3, 68 (1964).
R. Brill, J. Catal. 16, 16 (1970).
G. Buzzi Ferraris, G. Donati, F. Rejna, and S. Carrà, Chem. Eng. Sci. 29, 1621 (1974).
M. Bowker, I. B. Parker, and K. C. Waugh, Appl. Catal. 14, 101 (1985).
G. Ertl, in: Catalysis Science and Technology (J. R. Anderson and M. Boudart, eds.), Vol. 4, p. 273, Springer-Verlag, Berlin (1983).
P. Stoltze and J. K. Norskov, Phys. Rev. Lett. 55, 2502 (1985).
G. Ertl, Critical Reviews in Solid State and Materials Science, p. 349, CRC Press, Boca Raton (1982).
Nitrogen 31(9), 22 (1964).
U. Zardi, Ammonia Casale A.S., U.S. Patent No. 4,372,920 (1983).
G. Gramatica, Tecnimont S.p.A., U.S. Patent No. 4,205,044 (1980).
O. J. Quartulli and G. A. Wagner, Hydrocarbon Process. 12, 115 (1978).
S. Ergun, Chem. Eng. Prog. 48(2), 89 (1952).
C. E. Schwartz and J. M. Smith, Ind. Eng. Chem. 45(6), 1209 (1953).
O. Levenspiel and K. B. Bischoff, Advances in Chemical Engineering, Vol. 4, Academic Press, New York (1963).
P. N. Dwivedi and S. N. Upadhyay, Ind. Eng. Chem., Process Des. Dev. 16(2), 157 (1977).
D. C. Dyson and J. M. Simon, Ind. Eng. Chem., Fundam. 7(4), 605 (1968).
C. P. P. Singh and D. N. Saraf, Ind. Eng. Chem., Process Des. Dev. 18(3), 364 (1979).
A. Cappelli and A. Collina, Inst. Chem. Eng., Symp. Ser. 35(5), 10 (1972).
D. F. Fairbanks and C. R. Wilke, Ind. Eng. Chem. 42(3), 471 (1950).
A. Nielsen, An Investigation on Promoted Iron Catalysts for the Synthesis of Ammonia, 3rd ed., Jul. Gjellerups Forlag, Copenhagen (1968).
J. A. Beattie, Proc. Natl. Acad. Sci. U.S.A. 16, 14 (1930).
L. J. Gillespie and J. A. Beattie, Phys. Rev. 36, 743 (1930).
L. D. Gaines, Ind. Eng. Chem., Process Des. Dev. 16(3), 381 (1977).
B. Mansson and B. Andersen, Ind. Eng. Chem., Process Des. Dev. 25, 59 (1986).
H. W. Cooper, Hydr. Proc, Pet. Ref. 46(2), 159 (1967).
R. H. Newton, Ind. Eng. Chem. 27, 302 (1935).
Ya. S. Kazarnovskii, Zh. Fiz. Khim. 19, 392 (1945).
O. A. Hougen, K. M. Watson, and R. R. Ragatz, Chemical Process Principles, Part II, Wiley, New York (1947).
F. Horn, Z. Elektrochem. 65, 295 (1961).
S. Strelzoff, Technology and Manufacture of Ammonia, Wiley, New York (1981).
U. Zardi, Hydr. Proc. 8, 129 (1982).
Nitrogen 140(6), 30 (1982).
A. V. Slack and G. R. James, Ammonia, Vol. III, Marcel Dekker, New York (1977).
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Gramatica, G., Pernicone, N. (1991). Kinetics of Ammonia Synthesis and Influence on Converter Design. In: Jennings, J.R. (eds) Catalytic Ammonia Synthesis. Fundamental and Applied Catalysis. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9592-9_6
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DOI: https://doi.org/10.1007/978-1-4757-9592-9_6
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