Abstract
This paper will focus on the heavy metals which occur in natural waters. They usually occur at the trace level; this situation holds even for the more elevated concentrations in polluted areas. Generally, the total heavy metal concentration is distributed between the dissolved state and the surface zones of suspended inorganic and organic matter. In this context, films of organic materials on the surface of inorganic particles will play a significant, although not exclusive, role in the binding of metals to suspended matter. In addition, metals will be taken up by aquatic organisms. Among them, the phytoplankton are of particular significance from the biomass aspect and the accumulation potential. In rather shallow waters, typically down to 100 m, the surface layers of sediments are also involved more or less significantly as depot sites in the dynamics of metal transfer and exchange between the components and various phases of a natural water system.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
Ahmed, R., Valenta, P., and Nürnberg, H.W., 1981, Voltammetric determination of mercury levels in tuna fish, Mikrochim. Acta (Wien), p. 171.
Baudo, R., in: this volume.
Bunt, J.S., 1975, Primary productivity in marine ecosystems, in: “Primary Productivity of the Biosphere”, H. Lieth and R.S. Whit¬taker, eds., Springer, Berlin.
Duinker, J.C., and Kramer, C.J.M., 1977, An experimental study on the speciation of dissolved zinc, cadmium, lead and copper in the River Rhine and North Sea water by differential pulse anodic stripping voltammetry, Mar. Chem., 5: 207.
Duursma, E.K., 1965, Biological and chemical aspects of dissolved or¬ganic matter in sea water, in: “Chemical Oceanography,Vol.l”,J.P. Riley and G. Skirrow, eds., Academic Press, London.
Dyrssen, D., and Wedborg, M., 1974, Equilibrium calculations of the speciation of elements in sea water, in: “The Sea, Volume 5”, E.D. Goldberg, ed., Wiley, New York.
Eigen, M., 1963, Ionen-and Ladungsübertragungsreaktionen in Lösung, Ber. Bunsenges. Phys. Chem., 67: 753.
Florence, T.M., and Batley, G.E., 1980, Chemical speciation in natural waters, CRC Crit. Rev. Anal. Chem., 9: 219.
Kuempel, J.R., and Schaap, W.B., 1968, Cyclic voltammetric study on the rate of ligand exchange between cadmium ion and Ca-EDTA, Inorg. Chem., 7: 2435.
Mantoura, R.F.C., Dickson, A., and Riley, J.P., 1978, The complexa¬tion of metals with humic materials in natural waters, Estuarine Coastal Mar. Sci., 6: 387.
Mart, L., 1979, Ermittlung und Vergleich des Pegels toxischer Spuren metalle in nordatlantischen und mediterranen Küstengewässern, Doctoral thesis, RWTH Aachen.
Mart, L., Nürnberg, H.W., and Dyrssen, P., 1982b, Low level deter¬mination of trace metals in Arctic sea water and snow by differ¬ential pulse anodic stripping voltammetry, in: “Trace Metals in Sea Water”, C.S. Wong, ed., Plenum Press, New York, in press.
Mart, L., Nürnberg, H.W., and Valenta, P., 1980a, Comparative base line studies on Pb-levels in European coastal waters, in: “Lead in the Environment”, M. Branica and Z. Konrad, eds., Pergamon Press, Oxford.
Mart, L., Nürnberg, H.W., and Valenta, P., 1980b, Voltammetric ultra trace analysis with a multicell system designed for clean bench working, Fresenius’ Z. Analyt. Chem., 300: 350.
Mart, L., Rützel, H., Klahre, P., Sipos, L., Platzek, U., Valenta, P., and Nürnberg, H.W., 1982a, Comparative studies on the distribu¬tion of trace metals in the oceans and coastal waters, in: “Trace Metals in Sea Water”, C.S. Wong, ed., Plenum Press, New York, in press.
Martincic, D., Stoeppler, M., Nürnberg, H.W., and Branica, M., 1982, Toxic metals levels in bivalves and their ambient water from the Lim Fjord, Thalassia Jugosl., in press.
Musani, Lj., Valenta, P., Nürnberg, H.W., Konrad, Z., and Branica, M.,1980, On the chelation of toxic trace metals by humic acid of marine origin, Estuarine Coastal Mar. Sci., 11: 639.
Nürnberg, H.W., 1979, Polarography and voltammetry in studies of toxic metals in man and his environment, Sci. Total Environm., 12: 35.
Nürnberg, H.W., 1981a, Voltammetric studies on toxic metal speciation in natural waters, Proc. Int. Conf. Heavy Metals in the Environ¬ment, Amsterdam, p. 635, CEP Consultants, Edinburgh.
Nürnberg, H.W., 1981b, Differentielle Pulspolarographie, Pulsvoltamme¬trie und Pulsinversvoltammetrie in:Analytiker-Taschenbuch,R. Bock, W. Fresenius, H. Günzler, W. Huber, G. Tölg, eds.,Springer,Bd. 2.
Nürnberg, H.W., 1982a, Voltammetric trace analysis in ecological chemistry of toxic metals, Pure Appl. Chem., in press.
Nürnberg, H.W., 1982b, Features of voltammetric investigations on trace metal speciation in sea water and inland waters, Thalassia Jugosl., in press.
Nürnberg, H.W., and Raspor, B., 1981, Applications of voltammetry in studies of the speciation of heavy metals by organic chelators in sea water, Environ. Technol. Lett., 2: 457.
Nürnberg, H.W., and Valenta, P., 1982, Potentialities and applications of voltammetry in chemical speciation of trace metals in the sea, in: “Trace Metals in Sea Water”, C.S. Wong, ed., Plenum Press, New York, in press.
Ogura, N., 1972, Rate and extent of decomposition of dissolved organic matter in surface sea water, Mar. Biol., 13: 89.
Pytkowicz, R.M., and Hawley, J.E., 1974, Bicarbonate and carbonate ion-pairs and a model of sea water at 25°C, Limnol. Oceanogr., 19: 223.
Raspor, B., Nürnberg, H.W., Valenta, P., and Branica, M., 1980a, The chelation of Pb by organic ligands in sea water, in: “Lead in the Environment”, M. Branica and Z. Konrad, eds., Pergamon Press, Oxford.
Raspor, B., Nürnberg, H.W., Valenta, P., and Branica, M., 1980b, Kinetics and mechanism of trace metal chelation in sea water, J. Electroanal. Chem., 115: 293.
Raspor, B., Nürnberg, H.W., Valenta, P., and Branica,M., 1981, Voltam¬metric studies on the stability of the Zn(II)-chelates with NTA and EDTA and the kinetics of their formation in Lake Ontario water, Limnol. Oceanogr., 26: 54
Raspor, B., Nürnberg, H.W., Valenta, P., and Branica, M., unpublished work.
Raspor, B., Valenta, P., Nürnberg, H.W., and Branica, M., 1977, Pol-arographic studies on the kinetics and mechanism of Cd(II)-che¬late formation with EDTA in sea water, Thalassia Jugosl., 13: 79.
Raspor, B., Valenta, P., Nürnberg, H.W., and Branica, M., 1979, Volt¬ammetric studies on the potentialities of Cd(II)-chelate forma¬tion in sea water, Rapp. Comm. Int. Mer Médit., 25 /26: 31.
Sillên, G., and Martell, A.E., 1971, “Stability Constants of Metal Ion Complexes, Second Edition”, Chem. Soc. Spec. Publ., No. 17.
Simoes Goncalves, M.L.S., and Valenta, P., 1982, Voltammetric and potentiometric investigations on the complexation of Zn(II) by glycine in sea water, J. Electroanal. Chem., in press.
Simoes Goncalves, M.L.S., Valenta, P., and Nürnberg, H.W., 1982, Voltammetric and potentiometric investigations on the complexa tion of Cd(II) by glycine in sea water, J. Electroanal. Chem., in press.
Sipos, L., Raspor, B., Nürnberg, H.W., and Pytkowicz, R.M., 1980,. Interaction of metal complexes with coulombic ion-pairs in aqueous media of high salinity, Mar. Chem., 9: 37.
Stoeppler, M., and Brandt, K., 1979, Trace metals in krill, krill products and fish from the Antarctic Scotia Sea, Z. Lebensm.Unters. Forsch., 169: 95.
Stoeppler, M., and Nürnberg, H.W., 1979, Typical levels and accumula¬tion of toxic trace metals in muscle tissue and organs of marine organisms from different European seas, Ecotoxicol. Environ. Safety, 3: 335.
Sugawara, M., and Valenta, P., 1982, Voltammetric studies on the speciation of trace metals by amino acids in sea water, Rapp. Comm. Int. Mer Médit., in press.
Valenta, P., in: this volume.
Whitfield, M., and Turner, D.R., 1980, Theoretical studies of the chemical speciation of lead in sea water, in: “Lead in the Marine Environment”, M. Branica and Z. Konrad, eds., Pergamon Press, Oxford.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 Plenum Press, New York
About this chapter
Cite this chapter
Nürnberg, H.W. (1983). Voltammetric Studies on Trace Metal Speciation in Natural Waters Part II: Application and Conclusions for Chemical Oceanography and Chemical Limnology. In: Leppard, G.G. (eds) Trace Element Speciation in Surface Waters and Its Ecological Implications. NATO Conference Series, vol 6. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8234-8_13
Download citation
DOI: https://doi.org/10.1007/978-1-4684-8234-8_13
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-8236-2
Online ISBN: 978-1-4684-8234-8
eBook Packages: Springer Book Archive