Abstract
The most general and simple theory intended to fit liquid and solid solutions is the regular solution theory developed by vanLaar and Lorenz (1925), Heitler (1926), and Hildebrand (1928). The term regular solution was proposed by Hildebrand (1929) for solutions described by random and yet nonideal behavior. This proposed behavior was properly called the zeroth approximation to the regular solutions by Guggenheim,1 as distinct from the first approximation, to be discussed later in this chapter. Early developments in this field are presented in a number of publications.1–3
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References
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© 1986 Plenum Press, New York
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Gokcen, N.A. (1986). Theories of Solutions. In: Statistical Thermodynamics of Alloys. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-5053-8_4
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DOI: https://doi.org/10.1007/978-1-4684-5053-8_4
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