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Linear Correlations of Substituent Effects in 1H, 19F, and 13C Nuclear Magnetic Resonance Spectroscopy

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Advances in Linear Free Energy Relationships

Abstract

Nuclear magnetic resonance (nmr), from its inception, has provided useful and sometimes unique information about molecules. Nuclear shielding and spin-spin coupling data could lead to a complete understanding of the electronic environment of magnetic nuclei. This potential, however, has been only partly realised, primarily because theoretical interpretations of magnetic phenomena have not yet been as successful as empirical ones in providing information about the nature of electronic environments in and the transmission of electronic effects through a molecule.

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Authors and Affiliations

  1. University of Georgia, Athens, Georgia, 30601, USA

    M. Thomas Tribble

  2. Louisiana State University, Baton Rouge, Louisiana, 70803, USA

    James G. Traynham

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  1. M. Thomas Tribble
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  1. Department of Chemistry, The University, Hull, HU6 7RX, England

    N. B. Chapman  & J. Shorter  & 

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Tribble, M.T., Traynham, J.G. (1972). Linear Correlations of Substituent Effects in 1H, 19F, and 13C Nuclear Magnetic Resonance Spectroscopy. In: Chapman, N.B., Shorter, J. (eds) Advances in Linear Free Energy Relationships. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8660-9_4

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