Abstract
To try to summarize the status of the experimental situation in binary mixtures close to their dissolution point is a rather difficult task. A large number of experiments has been performed in the field since more than one century, and especially in the last 15 years. It has therefore been necessary to omit a number of interesting experiments. The justification of our choice has been chiefly the quality of the experimentation, and the consistency of the results in different laboratories. Ten binary mixtures have been selected, which allowed critical exponents, amplitudes and non-analytical corrections to be determined. We have contributed to the experimental study of 6 of them in our laboratory.
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References
D. Beysens, J. Chem. Phys. 71, 2557 (1979).
D. Beysens, R. Tufeu and Y. Garrabos, J. de Phys. Lett. 40, L-623, (1979).
J. K. Bhattacharjee and R.A. Ferrell, preprint.
H. C. Burstyn, R.F. Chang and J.V. Sengers, Phys. Rev. Lett. 44, 410 (1980).
K. Kawasaki, Ann. Phys. (N.Y) 61, 1 (1970).
E. D. Siggia, B.I. Halperin and P.C. Hohenberg, Phys. Rev. B13, 2110 (1976).
P. Bergé, P. Calmettes, C. Laj, M. Tournarie, and B. Volochine, Phys. Rev. Lett. 24, 1223 (1970).
See for instance G. Parette and R. Kahn, J. Physique 32, Colloque C1, 523 (1971).
See for instance G.W. Brady, D. Mc Intyre, M.E. Myers, and A.M. Wims, J. Chem. Phys. 44, 2197 (1966).
See for instance B.J. Berne and P. Pecora, Dynamic Light Scattering, (Wiley, New-York, 1976).
A.J. Bray, Phys. Rev. B14, 1248 (1976). Numerical values in
R.F. Chang, H. Burstyn, J.V. Sengers and A.J, Bray, Phys. Rev. A19, 866 (1979).
D. Beysens, A. Bourgou and P. Calmettes, to be published.
See for instance D. Beysens, J. Chem. Phys. 64, 2579 (1976).
See for instance D. Beysens, A. Bourgou and H. Charlin, Phys. Lett. A53, 236 (1975); L.A. Reith and H.L. Swinney, Phys. Rev. A12, 1094 (1975); A.J. Bray and R.F. Chang, Phys. Rev. A12, 2594 (1975); for practical evaluations, D. Beysens and G. Zalczer, Opt. Comm. 26, 172 (1978).
Y. Garrabos, G. Zalczer and D. Beysens, to be published.
D. Beysens, A. Bourgou and G. Zalczer, J. de Physique, Colloque, 37, C-1, 225 (1976).
P. Berge and M. Dubois, Phys. Rev. Lett. 27, 1125 (1971).
P. Calmettes, I. Lagües, and C. Laj, Phys. Rev. Lett. 28, 478 (1972).
P. Calmettes, thesis (Paris VI, 1978) (unpublished).
See, for instance, W.I. Goldburg and J.S. Huang, in “Fluctuations, Instabilities and Phase Transitions”, ed. by T. Riste, NATO Advanced Study Institute Series (Plenum, N.Y, 1975) and ref. therein.
See, for instance, Yu P. Blagoï, V.I. Sokhan and L.A. Pavlichenko, J.E.T.P. Lett. 11, 190 (1970); P.C. Hohenberg and M. Bormatz, Phys. Rev. A6, 289 (1972); M. Giglio and A. Vendramini, Phys. Rev. Lett. 35 168 (1975); J.C. Greer, T.E. Block, and C.M. Knobler, Phys. Rev. Lett. 34, 250 (1975).
S. C. Greer, Phys. Rev. A14, 1770 (1976).
D. T. Jacobs, D.J. Anthony, R.C. Mockler and W.J. O’Sullivan, Chem. Phys. 20, 219 (1977).
D. A. Balzarini, Can. J. Phys. 52, 499 (1974).
B. A. Scheibner, C.M. Sorensen, D.T. Jacobs, R.C. Mockler and W.J. O’Sullivan, Chem. Phys. 31, 209 (1978).
D. Beysens and A. Bourgou, Phys. Rev. A19, 2407 (1979).
D. Beysens and J. Wesfreid, J. Chem. Phys. 71, 119 (1979).
D. Beysens and P. Calmettes, J. Chem, Phys. 66, 766 (1977).
See for instance J. Thoen, E. Bloemen, and W. Van Daël, J. Chem. Phys. 68, 735 (1978) and ref. therein.
P. Calmettes and C. Laj, Phys. Rev. Lett. 36, 1372 (1976).
J. C. Le Guillou and J. Zinn-Justin, Phys. Rev. B21, 3976 (1980) and ref. therein.
C. Bervillier, Phys. Rev. B14, 4964 (1976).
C. Bervillier, and C. Godreche, Phys. Rev. B21, 5427 (1980).
D. Stauffer, M. Ferer and M. Wortis, Phys. Rev. Lett. 29, 345 (1972).
A. Aharony and P.C. Hohenberg, Phys. Rev. B13, 3081 (1976).
N.B. Rozhdestvenskaya and E.N. Gorbachova, Opt. Comm. 30, 383 (1979).
Y. Garrabos, R. Tufeu and B. Le Neindre, J. Chem. Phys. 68, 495 (1978).
H. C. Burstyn, J.V. Sengers and P. Esfandiari, Phys. Rev. A22, 282 (1980).
P.C. Hohenberg, private communication.
E. D. Siggia, B.I. Halperin and P.C. Hohenberg, Phys. Rev. B13, 2110 (1976).
B. Volochine, thesis (Paris, 1973, unpublished).
I.M. Arefev, I.L. Fabelinskii, M.A. Anisimov, Yu. F. Kiyachenko, and V.P. Voronov, Opt. Commun. 9, 69 (1973).
D. Thiel, B. Chu. A. Stein and G. Allen, J. Chem. Phys. 62, 3689 (1975).
C. C. Lai and S.H. Chen, Phys. Lett. 41A, 259 (1972).
E. Gülari, A.F. Collings, R.L. Schmidt and C.J. Pings, J. Chem. Phys. 56, 6169 (1972).
J. Timmermans, “The Physico-Chemical constant of binary systems in concentrated solutions”, Vol. 1, Interscience, Pub. Inc. N.Y (1959) and ref. therein.
B. Chu., F.J. Schoenes and W.P. Kao, J. of Am. Chem. Soc. 90, 3042 (1968).
E. Gülari, A.F. Collings, R.L. Schmidt and C.J. Pings, J. Chem. Phys. 56, 6169 (1972).
D. Atack and O.K. Rice, Disc. Trans. Farad. Soc. 23, 2428 (1953), reanalyzed by Wims and al, ref.[50].
A. Wims, D. Mc Intyre and F. Hynne, J. Chem. Phys. 50, 616 (1969).
F. Kohler and O.K. Rice, J. Chem. Phys. 26, 1614 (1957).
See Ref.[59], part I.
E.S.R. Gopal, R. Ramachandra, P. Chandrasekhar, K. Govindarajun, and S.V. Subramanyam, Phys. Rev. Lett. 32, 284 (1974), reanalyzed in ref.[22].
J. Reeder, T.H. Block, and C.M. Knobler, J. Chem. Therm. 8, 133 (1976).
R.J.L. Andon and J.D. Cox, J. Chem. Soc. 4601 (1952).
G. Morrisson and C.M. Knobler, J. Chem. Phys. 65, 5507 (1976).
H. Klein and D. Woermann, Ber. Bunsenges. Phys. Chem. 79, 1180 (1975).
S. C. Greer and R. Hocken, J. Chem. Phys. 63, 5067 (1975).
M. Pelger, H. Klein and D. Woermann, J. Chem. Phys. 67, 5362 (1977).
M. A. Anisimov, A.V. Voronel and T.M. Ovodova, J.E.T.P. Lett. 34, 583 (1972).
H. Klein and D. Woermann, J. Chem. Phys. 62, 2913 (1974).
H. Klein and D. Woermann, J. Chem. Phys. 65, 2913 (1976).
C. M. Sorensen, R.C. Mockler and W.J. O’Sullivan, Phys. Rev. Lett. 40, 777 (1978).
S. H. Chen, C.C. Lai, and J. Rouch, J. Chem. Phys. 68, 1994 (1978) and ref. therein.
D. Woermann and W. Sarholz, Ber. Bunsenges. Physik. Chem. 69, 319 (1965).
G. Zalczer, Private communication. Fit of the data from ref.[67] with ν = 0.630 imposed, giving ξo/R = 3.06 − 3.10 Å.
B. Chu, S.P. Lee and W. Tscharnuter, Phys. Rev. A7, 353 (1973).
V. K. Semenchenko, E.L. Zorina, Dokl. Akad. Neuk. SSSR 73 331 (1950), and 84, 1191 (1952), and E.F. Zhuralev, Zh. Obshch. Khim. 31, 363 (1961).
D. Beysens, S.H. Chen, J.P. Chabrat, L. Letamendia, J. Rouch and C. Vaucamps, J. de Physique Lett. 38, L-203 (1977).
G. Arcovito, C. Falori, M. Roberti and L. Mistura, Phys. Rev. Lett. 22, 1040 (1969).
C.M. Sorensen, R.C. Mockler and W.J. O’Sullivan, Phys. Rev. A16, 365 (1977).
B. Chu, D. Thiel, W. Tscharnüter and D. Fenby, J. de Phys. C1, 33, C-111 (1972).
R. Tsaï and D. Mc Intyre, J. Chem. Phys. 60, 937 (1974).
J. C. Allegra, A. Stein, and G.F. Allen, J. Chem. Phys. 55, 1716 (1971).
D. R. Thomson and O.K. Rice, J. Am. Chem. Soc. 86 3547 (1964) reanalyzed in Ref.[76].
P. Heller, Rep. Prog. Phys. 30, 731 (1967).
A. Bourgou and D. Beysens, to be published.
E. Gürmen, M. Chandrasekhar, P.E. Chumbley, H.D. Bale, D.A. Dolejsi, J.S. Lin and P.W. Schmidt, Phys. Rev. A22, 170 (1980).
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Beysens, D. (1982). Status of the Experimental Situation in Critical Binary Fluids. In: Lévy, M., Le Guillou, JC., Zinn-Justin, J. (eds) Phase Transitions Cargèse 1980. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3347-0_2
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