Abstract
Photooxidation reactions belong to the most important processes operating in the atmospheric aging of polydienes. Photooxidative degradation and/or crosslinking of polydienes is generally considered to proceed by reactions of free polymer alkyl-, alkylperoxy-, alkyloxy- and other free-radicals formed by photolysis or photoexcitation of internal (e.g., chromophoric groups such as carbonyl groups) and/or external impurities (e.g., traces of catalysts, initiators and other additives.1–4
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References
J. F. Rabek in: “Comprehensive Chemical Kinetics,” Vol. 14, C. H. Bamford and C. F. Tipper, Eds., Elsevier, Amsterdam, 1975, p. 425.
B. Rånby and J. F. Rabek, Photodegradation, Photoox idation and Photostabilization of Polymers, Wiley, London, 1975.
B. Rånby and J. F. Rabek in; “Long Term Properties of Polymers and Polymeric Materials,” B. Rånby and J. F. Rabek, Eds., Appl. Polymer Sumposia, No. 35, 1980, p. 243.
J. F. McKellar and N. S. Allen, Photochemistry of Manmade Polymers, Applied Science Publ., London, 1979.
J. F. Rabek and B. Rånby, Photochem. Photobiol.,28, 557 (1978).
J. F. Rabek and B. Rånby, Photochem. Photobiol.,30, 133 (1979).
J. F. Rabek and B. Rånby, Rev. Roum. Chim.,25, 1045 (1980).
J. F. Rabek and B. Rånby, J. Appl. Polym. Sci.,23, 339 (1979).
J. F. Rabek, J. Lucki and B. Rånby, Europ. Polym. J.,15, 1089 (1979).
J. F. Rabek and D. Lala,J. Polym. Sci.,B18, 427 (1980).
D. Lala,J. F. Rabek and B. Rånby, Europ. Polym. J.,16, 735 (1980).
D. Lala and J. F. Rabek, Europ. Polym. J.,177 (1981).
D. Lala and J. F. Rabek, Polym. Degrad. Stabil.,3, 383 (1980/ 1981).
J. F. Rabek, B. Rånby, J. Arct and Z. Golubski, Europ. Polym. J.,18, 87 (1982).
M. A. Golub, R. V. Gemmer and M. I. Rosenberger, Adv. Chem. Ser.,169, 11 (1977).
M. A. Golub, M. I. Rosenberger and R. V. Gemmer, Rubb. Chem. Technol.,50, 704 (1977).
M. A. Golub, NASA Technical Memorandum No. 78604, June, 1979.
H. C. Ng and J. E. Guillet, Macromolecules,11, 929 (1978).
H. C. Ng and J. E. Guillet, Photochem. Photobiol.,24, 571 (1978).
S. E. Morsi, A. B. Zaki, S. H. Etaiw, W. M. Khalifa and M. AlSayed-Salem, Polymer,22, 942 (1981).
A. Heller, Mol. Photochem.,1, 257 (1969).
S. Califano, Vibrational States, Wiley, N.Y., 1976.
H. Ratajczak and W. J. Orville-Thomas, Molecular Interactions, Wiley, N.Y., 1980.
B. R. Henry and M. Kasha, Ann. Rev. Phys. Chem.,19, 161 (1968).
M. Bixon and J. Jortner, J. Chem. Phys.,48, 715 (1968).
D. P. Chock, J. Jortner and S. A. Rice, J. Chem. Phys.,49, 610 (1968).
W. Siebrand and D. F. Williams, J. Chem. Phys.,49, 1860 (1968).
S. Patai, The Chemistry of the Carbonyl Group, Wiley, N.Y., 1966.
B. Rånby and J. F. Rabek, ESR Spectroscopy in Polymer Research, Springer Verlag, Berlin, 1977.
T. J. Henman, Dev. Polym. Stabil.,1, 39 (1979).
J. Pospišil, Dev. Polym. Stabil.,1, 1 (1979).
J. Pospišil, Adv. Polym. Sci.,36, 70 (1980).
J. C. Westfahl, C. J. Carman and R. W. Layer, Rubb. Chem. Technol.,45, 402 (1972).
J. R. Shelton, Rubber Chem. Technol.,49, 359 (1972).
E. R. Altwicker, Chem. Rev.,67, 475 (1967).
L. R. Makoney, Angew. Chem., 81, 555 (1969).
A. L. Buchachenko, Stable Radicals, Consultant Bureau, N.Y., 1965.
L. Taymir and J. Pospišil, Angew. Makromol. Chem.,39, 189 (1974).
M. J. Thomas and C. F. Foote, Photochem. Photobiol.,27, 683 (1978).
C. S. Foote, M. Thomas and T. Y. Ching, J. Photochem.,5, 172 (1976).
B. Stevens, S. R. Perez and R. D. Small, Photochem. Photobiol.,19, 315 (1974).
N. S. Allen, Polym. Photochem.,1, 243 (1981).
G. Balint, A. Rockebauer, T. Kelen, F. Tüdos and L. Jokay, Polym. Photochem.,1, 139 (1981).
P. N. Son, Polym. Degrad. Stab.,2, 295 (1980).
N. S. Allen, Polym. Degrad. Stabil.,2, 179 (1980).
N. S. Allen and J. F. McKellar, Brit. Polym. J.,9, 302 (1977).
N. S. Allen, Polym. Degrad. Stabil.,2, 129 (1980).
D. J. Carlsson, D. W. Grattan and D. M. Wiles, Polym. Degrad. Stabil.,1, 69 (1979).
N. S. Allen, Polym. Degrad. Stabil.,3, 73 (1980).
D. K. C. Hodgeman, J. Polym. Sci.,18, 533 (1980).
G. Balint, T. Kelen, F. Tüdos and A. Rehak, Polym. Bull.,1, 647 (1979).
V. B. Ivanov, V. Y. Shlapintokh, V. Y. Kvostach, 0. M. Shapiro and E. G. Rozantsev, J. Photochem.,4, 313 (1975).
D. Belluš, A. Lind and J. E. Watt, J. Chem. Soc. Chem. Comm.,1972, 1190.
Y. Lion, M. Delmelle and A. Van de Vorst, Nature,263, 442 (1976).
J. Moan and E. Wold, Nature,279, 450 (1979).
Y. Lion, E. Gandin and A. Van de Vorst, Photochem. Photobiol.,31, 305 (1980).
J. F. Rabek, B. Rånby and J. Arct, Polymer Degradation and Stability, (1982).
Y. Y. Yang, J. Lucki, J. F. Rabek and B. Rånby, Polymer Photochemistry, (1982).
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© 1984 Plenum Press, New York
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Rabek, J.F. (1984). Recent Developments in Photodegradation and Photostabilization of Polydienes. In: Kresta, J.E. (eds) Polymer Additives. Polymer Science and Technology, vol 26. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2797-4_1
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DOI: https://doi.org/10.1007/978-1-4613-2797-4_1
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