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Fluorine

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Multinuclear NMR

Abstract

Because of the high inherent NMR sensitivity of 19F nuclei, even the novice will have no difficulty observing 19F NMR spectra. The liquid reference which has evolved as a standard is CFCI3. This reference suffers from the same problems as most external reference liquids in that it has a sizable temperature dependence.(1) Use of CFCI3 or C6F6 as an internal reference is not recommended; both have fairly sizable solvent shifts.(2,3) In general, 19F solvent effects are greater than those of 1H, so that a report of chemical shifts ideally should include the conditions under which the sample is observed, e.g., neat liquid, 298 K.

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References

  1. Jameson, C. J.; Jameson, A. K.; Burrell, P. M. J. Chem. Phys. 1980, 73, 6013–6020; Jameson, C.J.; Jameson, A. K.; Oppusunggu, D. J. Chem. Phys. 1984, 81, 85–90.

    Article  CAS  Google Scholar 

  2. Dungan, C. H.; Van Wazer, J. R. Compilation of Reported 19F NMR Chemical Shifts; Wiley: New York, 1970.

    Google Scholar 

  3. Cyr, N.; Raza, M. A.; Reeves, L. W. Mol. Phys. 1972, 24, 459–460.

    Article  CAS  Google Scholar 

  4. Rummens, F. H. A. NMR Basic Princ. Prog. 1975, 10, 1–118.

    Google Scholar 

  5. Tong, J. P. K.; Langford, C. H.; Stengle, T. R. Can. J. Chem. 1974, 52, 1721–1731.

    Article  CAS  Google Scholar 

  6. Emsley, J. W.; Phillips, L.; Wray, V. Prog. NMR Spectrosc. 1975, 10, 83–756.

    Article  Google Scholar 

  7. Jameson, A. K.; Moyer, J.; Jameson, C. J. J. Chem. Phys. 1978, 68, 2873–2877.

    Article  CAS  Google Scholar 

  8. Bacon, J.; Gillespie, R. J.; Hartman, J. S.; Rao, U. R. K. Mol. Phys. 1970, 18, 561–570.

    Article  CAS  Google Scholar 

  9. Emsley, J. W.; Phillips, L. Prog. NMR Spectrosc. 1971, 7, 1–526.

    Article  Google Scholar 

  10. Wray, V. Annu. Rep. NMR Spectrosc. 1980, 10B, 1–507.

    Article  Google Scholar 

  11. Jones, K.; Mooney, E. F. Annu. Rep. NMR Spectrosc. 1971, 4, 391–495.

    Article  CAS  Google Scholar 

  12. Fields, R. Annu. Rep. NMR Spectrosc. 1972, 5A, 99–304.

    Article  Google Scholar 

  13. Cavalli, L. Annu. Rep. NMR Spectrosc. 1976, 6B, 43–222.

    Article  Google Scholar 

  14. Fields, R. Annu. Rep. NMR Spectrosc. 1977, 7, 1–117.

    Article  CAS  Google Scholar 

  15. Holloway, J. H.; Schrobilgen, G. J. Inorg. Chem. 1981, 20, 3363–3368.

    Article  CAS  Google Scholar 

  16. Holloway, J. H.; Schrobilgen, G. J. Inorg. Chem. 1980, 19, 2632–2640.

    Article  CAS  Google Scholar 

  17. Mason, J. J. Chem. Soc., Dalton Trans. 1975, 1426–1431.

    Google Scholar 

  18. Hindermann, D. K.; Cornwell, C. D. J. Chem. Phys. 1968, 48, 2017–2024.

    Article  CAS  Google Scholar 

  19. Weiss, R. Phys. Rev. 1963, 131, 659–665.

    Article  CAS  Google Scholar 

  20. Baker, M. R.; Anderson, C. H.; Ramsey, N. F. Phys. Rev. A 1964, 133, 1533–1536.

    Article  CAS  Google Scholar 

  21. Stevens, R. M.; Lipscomb, W. N. J. Chem. Phys. 1964, 41, 184–194.

    Article  CAS  Google Scholar 

  22. Gierke, T. D.; Flygare, W. H. J. Am. Chem. Soc. 1972, 94, 7277–7283.

    Article  CAS  Google Scholar 

  23. Casleton, K. H.; Gierke, T. D.; Wang, J. H. S.; Kukolich, S. G. J. Chem. Phys. 1976, 64, 471–476.

    Article  CAS  Google Scholar 

  24. Muenter, J. S.; Klemperer, W. J. Chem. Phys. 1970, 52, 6033–6037.

    Article  Google Scholar 

  25. Davis, R. E.; Muenter, J. S. J. Chem. Phys. 1967, 57, 2836–2838.

    Article  Google Scholar 

  26. Fabricant, B.; Muenter, J. S. J. Chem. Phys. 1977, 66, 5274–5277.

    Article  CAS  Google Scholar 

  27. Wang, J. H. S.; Kukolich, S. G. J. Am. Chem. Soc. 1973, 95, 4138–4141.

    Article  CAS  Google Scholar 

  28. Weiss, V. M.; Todd, H. D.; Lo, M. K.; Gutowsky, H. S.; Flygare, W. H. Chem. Phys. 1967, 47, 4021–4029.

    CAS  Google Scholar 

  29. Flygare, W. H. Chem. Rev. 1974, 653–687.

    Google Scholar 

  30. Ozier, I.; Lee, S. S.; Ramsey, N. F. J. Chem. Phys. 1976, 65, 3985–3993.

    Article  CAS  Google Scholar 

  31. Ozier, I.; Yi, P. N.; Ramsey, N. F. J. Chem. Phys. 1977, 66, 143–146.

    Article  CAS  Google Scholar 

  32. Wofsy, S. C.; Muenter, J. S.; Klemperer, W. J. Chem. Phys. 1971, 55, 2014–2019.

    Article  CAS  Google Scholar 

  33. White, R. L. Rev. Mod. Phys. 1955, 27, 276–288.

    Article  CAS  Google Scholar 

  34. Jameson, C. J.; Jameson, A. K.; Honarbakhsh, J. J. Chem. Phys. 1984, 81, 5266–5267.

    Article  CAS  Google Scholar 

  35. Ozier, I.; Crapo, L. M.; Lee, S. S. Phys. Rev. A 1968, 172, 63–82.

    Article  CAS  Google Scholar 

  36. Landolt-Börnstein Zahlenwerte und Funktionen aus Naturwissenschaften und Technik, Neue Serie, Group II; Springer-Verlag: Berlin, 1974; Vol. 6, pp. 2–383 to 2–434.

    Google Scholar 

  37. Tigelaar, H. L.; Flygare, W. H. Chem. Phys. Lett. 1970, 7, 254–256.

    Article  CAS  Google Scholar 

  38. Holmes, J. R.; Stewart, B. B.; MacKenzie, J. S. J. Chem. Phys. 1962, 37, 2728–2729.

    Article  CAS  Google Scholar 

  39. Lawrence, N. J.; Ogden, J. S.; Turner, J. J. J. Chem. Soc., Chem. Commun. 1966, 102–103.

    Google Scholar 

  40. Nebgen, J. W.; Metz, F. I.; Rose, W. B. J. Am. Chem. Soc. 1967, 89, 3118–3121.

    Article  CAS  Google Scholar 

  41. Gutowsky, H. S.; Hoffman, C. J. J. Chem. Phys. 1951, 19, 1259–1267.

    Article  CAS  Google Scholar 

  42. Buckingham, A. D.; Stephens, P. J. J. Chem. Soc. A 1964, 2747–2759, 4583–4587.

    Google Scholar 

  43. Andrew, E. R. Philos. Trans. R. Soc. London Ser. A 1981, 299, 505–520.

    Article  CAS  Google Scholar 

  44. Garg, S. K.; Ripmeester, J. A.; Davidson, D. W. J. Magn. Reson. 1980, 39, 317–323; J. Chem. Phys. 1982, 77, 2847–2851.

    CAS  Google Scholar 

  45. Mehring, M. NMR Basic Princ. Progr. 1976, 11, 1–243.

    Google Scholar 

  46. Appleman, B. R.; Dailey, B. P. Adv. Magn. Reson. 1974, 7, 231–320.

    CAS  Google Scholar 

  47. Haeberlen, U. Adv. Magn. Reson. 1976, Suppl. 1, 1–186.

    Google Scholar 

  48. Lindman, B.; Forsen, S. NMR Basic Princ. Prog. 1976, 12, 1–365.

    Google Scholar 

  49. Shustorovich, E.; Dobosh, P. A. J. Magn. Reson. 1980, 39, 79–99.

    CAS  Google Scholar 

  50. Shustorovich, E.; Dobosh, P. A. J. Magn. Reson. 1980, 39, 101–117.

    CAS  Google Scholar 

  51. Ewing, D. F. NMR Spec. Per. Rep. R.S.C. 1983, 12, 68–95.

    CAS  Google Scholar 

  52. Ewing, D. F. NMR Spec. Per. Rep. R.S.C. 1982, 11, 71–105.

    CAS  Google Scholar 

  53. Ewing, D. F. NMR Spec. Per. Rep. R.S.C. 1981, 10, 74–111.

    CAS  Google Scholar 

  54. Ewing, D. F. NMR Spec. Per. Rep. R.S.C. 1980, 9, 68–100.

    CAS  Google Scholar 

  55. Gillespie, R. J.; Netzer, A.; Schrobilgen, G. J. Inorg. Chem. 1974, 13, 1455–1459.

    Article  CAS  Google Scholar 

  56. Mitchell, P. J.; Phillips, L.; Roberts, S. J.; Wray, V. Org. Magn. Reson. 1974, 6, 126–127.

    Article  CAS  Google Scholar 

  57. Witanowski, M.; Stefaniak, L.; Webb, G. A. Annu. Rep. NMR Spectrosc. 1981, IIB, 1–502.

    Google Scholar 

  58. Martin, G. J.; Martin, M. L.; Gouesnard, J. P. NMR Basic Princ. Prog. 1981, 18, 1–382.

    Google Scholar 

  59. Courtney, J. A.; Armstrong, R. L. Can. J. Phys. 1972, 50, 1252–1261.

    Article  CAS  Google Scholar 

  60. Finney, R. J.; Wolfe, M.; Jonas, J. J. Chem. Phys. 1977, 67, 4004–4011.

    Article  CAS  Google Scholar 

  61. Courtney, J. A.; Armstrong, R. L. J. Chem. Phys. 1970, 52, 2158–2159.

    Article  CAS  Google Scholar 

  62. Dybowski, C. R.; Chien, M.; Wade, C. G. J. Chem. Phys. 1972, 56, 4229–4231.

    Article  CAS  Google Scholar 

  63. Armstrong, R. L.; Courtney, J. A. Can. J. Phys. 1972, 50, 1262–1272.

    Article  CAS  Google Scholar 

  64. Gillen, K. T.; Douglass, D. C.; Griffiths, J. E. J. Chem. Phys. 1978, 69, 461–467.

    Article  CAS  Google Scholar 

  65. Hinshaw, W. S.; Hubbard, P. S. J. Chem. Phys. 1971, 54, 428–431.

    Article  CAS  Google Scholar 

  66. Maryott, A. A.; Farrar, T. C.; Malmberg, M. S. J. Chem. Phys. 1971, 54, 64–71.

    Article  CAS  Google Scholar 

  67. Rugheimer, J. H.; Hubbard, P. S. J. Chem. Phys. 1963, 39, 552–569.

    Article  CAS  Google Scholar 

  68. Gillen, K. T.; Douglass, D. C.; Malmberg, M. S.; Maryott, A. A. J. Chem. Phys. 1972, 57, 5170–5179.

    Article  CAS  Google Scholar 

  69. DeZwaan, J.; Finney, R. J.; Jonas, J. J. Chem. Phys. 60, 3223–3230.

    Google Scholar 

  70. Bull, T. E. J. Chem. Phys. 1975, 62, 222–226.

    Article  CAS  Google Scholar 

  71. Morgan, K.; Sayer, B. G.; Schrobilgen, G. J. J. Magn. Reson. 1983, 52, 139–142.

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Illinois, Chicago, Illinois, 60680, USA

    Cynthia J. Jameson

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  1. Cynthia J. Jameson
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  1. The Open University, Milton Keynes, Buckinghamshire, England

    Joan Mason

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© 1987 Plenum Press, New York

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Jameson, C.J. (1987). Fluorine. In: Mason, J. (eds) Multinuclear NMR. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1783-8_16

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  • DOI: https://doi.org/10.1007/978-1-4613-1783-8_16

  • Publisher Name: Springer, Boston, MA

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