Skip to main content

New Aliphatic Polyester Layered-Silicate Nanocomposites

  • Conference paper
Biodegradable Polymers and Plastics

Abstract

Nowadays, the plastic industry occupies a predominant and growing place in our everyday life. However, many of the plastics only have application for a determined time. That is the reason why their after-use valorisation draws more and more attention from scientists and industrials. One solution to at least partially resolving the problem of plastics accumulation in the environment is to develop the sector of the biodegradable polymers. In this domain, aliphatic polyesters play a key-role1. These polymers exhibit many advantages in comparison to commodity plastics such as for instance polyolefins. In addition to their biodegradability, it is possible to modulate their lifetime by changing the nature of the ester repeating units or to enhance their thermo-mechanical properties by copolymerization, blending, and filling techniques.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. Vert, M., Schwarch, G., Coudane, J., 1995, Present and future of PLA polymers. JMS Pure Appl Chem. A32 (4): 787–796

    Google Scholar 

  2. Hyon, S.-H., Jamshidi, K., Ikada Y., 1999, Synthesis of polylactides with different molecular weights. Biomaterials 18: 1503–1508.

    Article  Google Scholar 

  3. Messersmith, P.B., Giannelis, E.P., 1993, Polymer-layered silicates nanocomposites: in situ intercalative polymerization of CL in layered silicates. Chem. Mater. 5: 1064–1066

    Article  CAS  Google Scholar 

  4. Alexandre, M., Dubois, Ph., 2000, Polymer-layered silicate nanocomposites: preparation, properties, and uses of new class of materials. Mater. Sci. Eng. R28(1-2): 1–65.

    CAS  Google Scholar 

  5. Messersmith, P.B., Giannelis, E.P., 1995, Synthesis and barrier properties of poly(ε-caprolactone)-layered silicate nanocoposites. J. Polym. Sci., Part A 33: 1047–1057.

    Article  CAS  Google Scholar 

  6. Giannelis, E.P., Krishnamoorti, R., Manias, E., 1999, Polymer-silicate nanocomposites: model systems for confined polymers brushes. Adv. Polym. Sci. 118: 108–147.

    Google Scholar 

  7. Lagaly, G., 1986, Interaction of alkylamines with different types of layered compounds. Solid State Ionics 22: 43–51.

    Article  CAS  Google Scholar 

  8. Vaia, R.A., Teukolsky, R.K., Giannelis, E.P., 1994, Interlayer structure and molecular environment of alkylammonium layered silicates. Chem. Mater. 6: 1017–1022.

    Article  CAS  Google Scholar 

  9. Pantoustier, N., Lepoittevin, B., Alexandre, M., Kubies, D., Calberg, C., Jérôme, R., Dubois, Ph., 2002, Biodegradable polyester layered silicate nanocomposites based on poly(ε-caprolactone). Polym. Eng. Sci. 42(9): 1928–1937.

    Article  CAS  Google Scholar 

  10. Pantoustier, N., Alexandre, M, Degée, Ph., Kubies, D., Calberg, C., Jérôme, R., Henrist, C., Rulmont, A., Dubois, Ph., 2001, Poly(ε-caprolactone) layered silicate nanocomposites: effect of clay surface modifiers on the melt intercalation process. e-Polymers 009: 1–9.

    Article  Google Scholar 

  11. Lepoittevin, B., Devalckenaere, M., Pantoustier, N., Alexandre, M., Kubies, D., Calberg, C., Jérôme, R., Henrist, C., Cloots, R., Rulmont, A., Dubois, Ph., 2002, Poly(ε-caprolactone)/clay nanocomposites prepared by melt intercalation: mechanical, thermal and rheological properties. Polymer 43: 4017–4023.

    Article  CAS  Google Scholar 

  12. Tortora, M., Gorrasi, G., Vittoria, V., Pollet, E., Lepoittevin, B., Pantoustier, N., Alexandre, M., Dubois, Ph., 2003, Vapor barrier properties of polycaprolactone montmorillonite nanocomposites: effect of clay dispersion. Polymer 44: 2271–2279.

    Article  Google Scholar 

  13. Kubies, D., Pantoustier, N., Dubois, Ph., Rulmont, A., Jérôme, R., 2002, Controlled Ring-Opening Polymerization of ε-caprolactone in the presence of layered silicates and formation of nanocomposites. Macromolecules 35: 3318–3320.

    Article  CAS  Google Scholar 

  14. Lepoittevin, B., Pantoustier, N., Devalckenaere, M., Alexandre, M., Calberg, C., Jérôme, R., Dubois, Ph., 2002, Poly(ε-caprolactone)/clay nanocomposites by in-situ intercalative polymerization catalyzed by dibutyltin dimethoxide. Macromolecules 35: 8385–8390.

    Article  CAS  Google Scholar 

  15. Mecerreyes, D., Jérôme, R., Dubois, Ph., 1999, Novel macromolecular architectures based on aliphatic polyesters: relevance of the coordination-insertion ring opening polymerization. Adv. Polym. Sci. 147: 1–59.

    Article  CAS  Google Scholar 

  16. Huong, X., Brittain, W.J., 2001, Synthesis and characterization of PMMA nanocomposites by suspension and emulsion polymerization. Macromolecules 34: 3255–3260.

    Article  Google Scholar 

  17. Lepoittevin, B., Pantoustier, N., Devalckenaere, M., Alexandre, M., Calberg, C., Jérôme, R., Henrist, C., Rulmont, A., Dubois, Ph., 2003, Polymer/layered silicate nanocomposites by combined intercalative polymerization and melt intercalation: a masterbatch process. Polymer 44: 2033–2040.

    Article  CAS  Google Scholar 

  18. Pluta, M., Galeski, A., Paul, M.-A., Alexandre, M., Dubois, Ph., 2002, Polylactide/montmorillonite nanocomposites and microcomposites prepared by melt blending: structure and some physical properties. J. Appl. Polym. Sci. 86: 1497–1506.

    Article  CAS  Google Scholar 

  19. Paul, M.-A., Alexandre, M., Degée, Ph., Henrist, C., Rulmont, A., Dubois, Ph., 2003, New nanocomposite materials based on plasticized poly(L-lactide) and organo-modified montmorillonites: thermal and morphological study. Polymer, 44: 443–450.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2003 Springer Science+Business Media New York

About this paper

Cite this paper

Pollet, E., Paul, MA., Dubois, P. (2003). New Aliphatic Polyester Layered-Silicate Nanocomposites. In: Chiellini, E., Solaro, R. (eds) Biodegradable Polymers and Plastics. Springer, Boston, MA. https://doi.org/10.1007/978-1-4419-9240-6_22

Download citation

  • DOI: https://doi.org/10.1007/978-1-4419-9240-6_22

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-4854-2

  • Online ISBN: 978-1-4419-9240-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics