Abstract
The scaling relationships (Mark—Kuhn—Houwink—Sakurada type) are considered for the following hydrodynamic values: intrinsic viscosity, velocity sedimentation coefficient and translational diffusion coefficient and the concentration sedimentation coefficient (Gralen coefficient). By also taking into account the mass per unit length we can obtain “normalized scaling plots” which provide a convenient way of representing the rigidity of linear polymers.
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References
Tanford C (1961) Physical chemistry of macromolecules. Wiley, New York
Tsvetkov VN, Eskin VE, Frenkel SYa (1970) Structure of macromolecules in solution. Butterworths, London
Kirkwood J, Riseman J (1948) J Chem Phys 16:565
Svedberg T, Pedersen KO (1940) The ultracentrifuge. Oxford University Press, Oxford
Flory P (1953) Principles of polymer chemistry. Cornell University Press, Ithaca
Yamakawa H (1971) Modern theory of polymer solutions. Harper and Row, New York
Fujita H (1990) Polymer solutions. Elsevier, Amsterdam
Wales M, van Holde K (1954) J Polym Sci 14:81
Rowe A (1977) Biopolymers 16:2595
Pavlov G, Frenkel S (1995) Prog Colloid Polym Sci 99:101
Pavlov G (1997) Eur Biophys J 25:385
Gray H, Bloomfield V, Hearst J (1967) J Chem Phys 46:1493
Sharp P, Bloomfield V (1968) J Chem Phys 48:2149
Ptitsyn OB, Eizner Yu E (1959) Zh Tekh Fiz 29:1105
Pavlov G, Panarin E, Korneeva E, Kurochkin C, Baikov V, Ushakova V (1990) Makromol Chem 191:2889
Bushin SV, Astapenko EP (1986) Vysokomol Soedin 28:1499
Pavlov GM, Korneeva EV, Michailova NA, Ivanova NP, Panarin EF (1993) Vysokomol Soedin 35:1647
de Gennes P (1979) Scaling concepts in polymer physics. Cornell University Press, Ithaca
Mandelbrot B (1982) The fractal geometry of nature. Freeman, San Fransisco
Pietronero L, Tosatti E (eds) (1986) Fractal in physics. Elsevier, Amsterdam
Grosberg A, Khochlov A (1989) Physics in the world of polymers. Nauka, Moscow
Pavlov G, Rowe A, Harding S (1997) Trends Anal Chem 16:401
Pavlov G, Korneeva E, Harding S, Jumel K, Meijer E, Nepogodiev S, Peerling H, Stoddart J (1999) Carbohydr Polym 38:195
Pavlov G, Korneeva E, Roy R, Michailova N, Cejas Ortega P, Alamino Perez M (1999) Progr Colloid Polym Sci PCPS 109
Tsvetkov VN (1989) Rigid-chain polymers. Consultants Bureau, New York
Yanaki T, Norisuye T, Fujita H (1980) Macromolecules 13:345
Geiduschek EP, Holtzer A (1958) Adv Biol Med Phys 6:431
Crothers DM, Zimm BH (1965) J Mol Biol 12:525
Aten JBT, Cohen JA (1965) J Mol Biol 12:537
Eigner J, Doty P (1965) J Mol Biol 12:549
Creeth J, Knight C (1965) Biochim Biophys Acta 102:549
Sato T, Norisuye T, Fujita H (1984) Macromolecules 17:2696
Pavlov GM, Kozlov AN, Martchenko GN, Tsvetkov VN (1982) Vysokomol Soedin 24B:284
Kawahara K, Ohta K, Miyamoto H, Nakamura S (1984) Carbohydr Polym 4:335
Kato T, Katsuki T, Takahashi A (1984) Macromolecules 17:1726
Buliga GS, Brant DA (1987) Int J Biol Macromol 9:71
Nishinari K, Kohyama K, Williams PA, Phillips GO, Burchard W, Ogino K (1991) Macromolecules 24:5590
Pavlov GM, Korneeva EV, Yevlampieva NP (1994) Int J Biol Macromol 16:318
Pavlov GM, Michailova NA, Tarabukina EB, Korneeva EV (1995) Prog Colloid Polym Sci 99:109
Noda J, Saito S, Fujimoto T, Nagasawa M (1967) J Phys Chem 71:4048
Abe M, Sakato K, Kageyama T, Fukatsu M, Kurata M (1968) Bull Chem Soc Jpn 41:2330
Kotera A, Saito T, Hamada T (1972) Polym J 3:421
Noda J, Mizutani K, Kato T (1977) Macromolecules 10:618
Peeters FAH, Smits HJE (1981) Bull Soc Chim Belg 90:111
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Pavlov, G.M., Harding, S.E., Rowe, A.J. (1999). Normalized scaling relations as a natural classification of linear macromolecules according to size. In: Cölfen, H. (eds) Analytical Ultracentrifugation V. Progress in Colloid and Polymer Science, vol 113. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-48703-4_12
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DOI: https://doi.org/10.1007/3-540-48703-4_12
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