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Modern Solvent Systems in Industrial Homogeneous Catalysis

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Modern Solvents in Organic Synthesis

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 206))

Abstract

Water can be used very advantageously as the solvent in homogeneous catalytic reactions and thus gives rise to a specific class of aqueous biphasic reactions among two-phase reactions. This new use of water has two very positive consequences: an advantageous effect on the selectivity of the homogeneous catalytic reactions and the opportunity, for the first time, to “immobilize” the homogeneous catalyst by means of the “liquid support” water, then to separate it simply and immediately from the reaction products after its task is complete and thus to return it to the catalysis cycle. Apart from the industrial use of hydroformylation (oxo process), fine chemicals are also being increasingly prepared by the aqueous, homogeneously catalyzed biphasic technique.

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  1. Hoechst AG, D-65926, Frankfurt/M, Germany

    Boy Cornils

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  1. Institut für Organische Chemie, Ludwig Maximilians-Universität München, Butenanderstr. 5 - 13, D-81377, München, Germany

    Paul Knochel

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Cornils, B. (1999). Modern Solvent Systems in Industrial Homogeneous Catalysis. In: Knochel, P. (eds) Modern Solvents in Organic Synthesis. Topics in Current Chemistry, vol 206. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-48664-X_6

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  • DOI: https://doi.org/10.1007/3-540-48664-X_6

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