Abstract
The rheological behaviour of dissolved polymers is very complex. Both experiment and theory in this field have undergone rapid development in recent years. Therefore, we describe the possibilities of predicting the viscoelastic properties as well as the shear stability using the entanglement and reptation concepts and exemplifying mainly with narrow distributed polystyrene samples. The viscoelastic properties are discussed in relation to molar mass, concentration, solvent quality, chemical structure and shear rate. The structure-property relationships derived here permit the prediction of both the zero-shear viscosity, η0, as well as the shear rate dependent viscosity η(\( \dot \gamma \)). These relationships can be extended to non-Newtonian fluids. For solutions of coiled polymers in a thermodynamically good solvent, five distinct states of solution are formed: ideally dilute solution, semi-dilute particle solution, semi-dilute network solution, concentrated particle solution and concentrated network solution. For non-homogeneous, semi-dilute (moderately concentrated) solutions the slope in the linear region of the flow curve [η=f(\( \dot \gamma \))] must be standardised against the overlap parameter c· [η ]. Furthermore, it is possible to predict the onset of shear degradation of polymeric liquids subjected to a laminar velocity field on the basis of molecular modeling. Also described is the phenomenon that the elastic nature (first normal stress difference) may overwhelm the viscous nature (shear stress) at relatively low shear rates. This high elasticity can cause deviation from laminar flow conditions and the onset conditions can be detected by plotting Sr=f(τ12).
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References
Cheftel JC, Cuq JL, Lorient D ( 1992) Lebensmittel-Proteine. Behr’s, Hamburg, p 88
Harris P ( 1990) Food gels. Elsevier Applied Science, New York, p 208
Walter RH (1998) Polysaccharide association structures in food. Marcel Dekker, New York, p 289
Lapasin R, Pricl S (1995) Rheology of industrial polysaccharides. Theory and applications. Padstow, Cornell, p 135
Laba D (1993) Rheological properties of cosmetics and toiletries. Marcel Dekker, New York, p 55
Casale A, Porter RSA (1978) Polymer stress reactions, vol 1. Academic Press, New York, p 70
Koedritz LF, Harvey AH, Honarpour M (1989) Introduction to petroleum reservoir analysis. Gulf, Houston
Gampert B (1985) The influence of polymer additives on velocity and temperature fields. Springer, Berlin Heidelberg New York, p 371
Kulicke W-M, Gräger H, Kötter M (1989) Adv Polym Sci 89:1
Glass JE. (1986) Water-soluble polymers. Beauty with performance. American Chemical Society, Washington, DC, p 183
Hebeish A, El-Zairy MR, El-Rafie MH, Higazy A, El-Sisy F (1991) Starch 43:98
Woffindin C, Hoenich NA (1992) JNS Nephrol Dialysis Transplant 7:340
Beretka J (1992) J Chem Technol BioTechnol 55:269
Schulz DN, Glass JE (1991) Polymers as rheology modifiers. American Chemical Society, Washington, DC, p 322
Carr ME (1992) Starch 44:219
Paine AJ (1990) J Colloid Interface Sci 138:157
Cohen E (1993) Arch Insect Biochem Physiol 22:245
Glass JE, Swift G ( 1990) Agricultural and synthetic polymers. American Chemical Society, Washington, DC, p 33
Kniewske R, Kulicke W-M (1983) Makromol Chem 184:2173
Kulicke W-M, Kniewske R (1984) Rheol Acta 23:75
Kulicke W-M, Griebel Th, Bouldin M (1991) Polymer News 16:39
Bouldin M, Kulicke W-M, Kehler H (1988) Colloid Polym Sci 266:793
Kulicke W-M (1986) Fließverhalten von Stoffen und Stoffengemischen. Hüthig & Wepf, Basel, p 218
Kulicke W-M, Klein J, Kniewske R (1982) Progress Polym Sci 8:373
Kulicke W-M, Haas R (1984) Ind Eng Chem Fundam 23:308
Haas R, Kulicke W-M (1984) Ind Eng Chem Fundam 23:316
Schramm G (1994) A practical approach to rheology and rheometry. Haake, Karlsruhe, p 146
Carreau PJ, De Kee DCR, Chhabra RP (1997) Rheology of polymeric systems. Principles and applications. Hanser, Munich, p 35
Macosko CW (1994) Rheology. Principles, measurements and applications. VCH, New York, p 86
Bird RB, Armstrong RC, Hassager O (1977) Dynamics of polymeric liquids. Wiley, New York
Mark JE, Eisenberg A, Graessley WW, Mandelkern L, Koenig JL (1984) Physical properties of polymers. American Chemical Society, Washington, DC
Barnes HA, Hutton JF, Walters K (1989) An introduction to rheology. Elsevier, Amsterdam
Rouse PE (1953) J Chem Phys 21:1272
Zimm BH (1956) J Chem Phys 24:269
Bueche F (1952) J Chem Phys 20:1959
Debye P, Bueche F (1948) J Chem Phys 16:573
Bueche F (1956) J Chem Phys 25:599
Berry GC, Fox TG (1968) Adv Polym Sci 5:261
Ferry JD, Landel RF, Williams ML (1955) J Appl Phys 26:359
Graessley W, Hazelton R, Lindeman R (1967) Trans Soc Rheol 11:267
Graessley W (1967) J Chem Phys 47:1942
Graessley W (1965) J Chem Phys 43:2696
De Gennes PG (1971) J Chem Phys 55:572
De Gennes PG (1979) Scaling concepts in polymer physics. Cornell University Press, Ithaca, New York
Leger L, De Gennes PG (1982) Annu Rev Phys Chem 33:49
Doi M (1983) J Polym Sci Polym Phys Ed 21:667
Doi M, Edwards SF (1986) The theory of polymer dynamics. Oxford University Press, 234
Doi M, Edwards SF (1978) J Chem Soc Farad Trans 74:1802
Han CD, Jhon MS (1986) J Appl Polym Sci 32:3809
Han CD (1976) Rheology in polymer processing. Academic Press, London, p 61
Forsman WC (1989) Polymers in solution. Theoretical considerations and newer methods of characterization. Plenum Press, New York, p 145
Lodge AS (1964) Elastic liquids. Academic Press, New York
Simha R, Zakin L (1962) J Coll Sci 17:270
De Gennes PG (1976) Macromolecules 9:587
Klein J (1978) Macromolecules 11:852
Fujita H (1990) Polymer solutions. Elsevier, Amsterdam, p 182
Graessley WW (1974) Adv Polym Sci 16:49
Baumgärtel M, Willenbacher N (1996) Rheol Acta 35:168
Masuda T, Kitagawa K, Onogi S (1970) Polymer J (Japan) 1:418
Kulicke W-M, Klare J (1980) Angew Makromol Chem 84:67
Casale A, Moroni A, Civardi E (1976) Angew Makromol Chem 53:1
Casale A, Porter RS, Johnson JF (1971) J Macromol Sci-Rvs Macromol Chem C5:387
Huggins ML (1942) J Am Chem Soc 64:2716
Daoud M, Cotton JP, Farnoux B, Jannink G, Sarma G, Benoit H, Dupressix R, Picot C, De Gennes PG (1975) Macromolecules 6:804
Zakin JL, Wu R, Luh H, Mayhan KG (1976) J Polym Sci Polym Phys Ed 14:299
Schurz J (1975) Rheol Acta 14:293
Onogi S, Kobayashi TKojima Y, Taniguchi Y (1963) J Appl Polym Sci 7:847
Griebel TH, Kulicke W-M, Kniewske R (1992) Mehl und Brot 5:154
Arendt O, Kulicke W-M (1998) Angew Makromol Chem 259:61
Böhm N., Kulicke W-M (1999) Carbohydr Res 293
Robinson G, Ross-Murphy SB, Morris ER (1982) Carbohydr Res 107:17
Abdel-Alim AH, Balke ST, Hamielec AE (1973) J Appl Polym Sci 17:1431
Attane P, LeRoy P, Picard JM, Turrel GJ (1981) Non-Newtonian Fluid Mech 9:13
Ferry JD (1978) Pure Appl Chem 50:299
Ferry JD (1980) Viscoelastic properties of polymers, 3rd edn. Wiley, New York, p 38
Stratton RA (1966) J Colloid Interface Sci 22:517
Wissbrunn KF, Metzner AB, Rangel-Nafaille C (1984) Macromolecules 17:1187
Kehler H, Kulicke W-M (1986) Chem Eng Technol 10:802
Elias HG (1996) Polymere von Monomeren und Makromolekülen zu Werkstoffen eine Einführung. Hüthig & Wepf, Heidelberg, p 273
Vinogradov GV, Malkin AV (1980) Rheology of polymers. Springer, Berlin Heidelberg New York, p 128
Williams MC (1967) AIChE J 13:534
Cross MM (1969) J Appl Polym Sci 13:765
Kulicke W-M, Porter RS (1981) J Polym Sci Ed 19:1173
Middleman S (1977) Fundamentals of polymer processing. McGraw-Hill, New York, chap 15
Kulicke W-M, Kiss G, Porter RS (1977) Rheol Acta 16:568
Petersen JF, Rautenbach R, Schümmer P (1975) Rheol Acta 14:968
Jackson R, Kaye A (1966) Br J Appl Phys 17:1355
Kulicke W-M, Porter RS (1979) J Appl Polym Sci 23:953
Kulicke W-M, Jeberien HE, Kiss G, Porter RS (1979) Rheol Acta 18:711
Pearsom JRA (1976) J Fluid Mech 4:163
Walters K (1975) Rheometry. Wiley, New York, p 65
King MJ, Waters ND (1970) Rheol Acta 9:164
Fewell ME, Hellums JD (1974) AlChE Winter Conf Washington, DC, Dec 1–5
Turian RM (1972) Ind Eng Chem Fundam 11:361
Gleisle W (1976) Rheol Acta 15:305
Giesekus H (1965) Rheol Acta 4:85
Lodge AS (1964) Elastic liquids. Academic Press, New York
Lodge AS (1974) Body tensor fields in continuum mechanics. Academic Press, New York
Adams N, Lodge AS (1964) Phil Trans R Soc London A256:149
Southern JH, Paul DR (1974) Polym Eng Sci 14:560
Kulicke W-M, Böse N (1982) Polym Bull 7:205
Kulicke W-M, Hörl H-H (1983) Angew Makromol Chem 116:149
Oertel R, Kulicke W-M (1991) Rheol Acta 30:140
Kulicke W-M, Reinhardt U (1993) Polym Mat Sci Eng 69:491
Reinhardt UT, Eidam D, Kulicke W-M (1994) J Getreide, Mehl und Brot 4:56
Kulicke W-M, Duhm L, Schuch A (1994) Chem-Ing-Technik 12:1643
Kulicke W-M, Kull AH, Kull W, Thielking H, Engelhardt J, Pannek J-B (1996) Polymers 13:2723
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Dedicated to the late Professor Roger S. Porter, University of Massachusetts, USA
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Grigorescu, G., Kulicke, WM. (2000). Prediction of Viscoelastic Properties and Shear Stability of Polymers in Solution. In: Viscoelasticity, Atomistic Models, Statistical Chemistry. Advances in Polymer Science, vol 152. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-46778-5_1
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DOI: https://doi.org/10.1007/3-540-46778-5_1
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