Abstract
Synthetic hectorite clay minerals were hydrothermally crystallized with direct incorporation of a series of five water-soluble polyvinyl alcohols (PVA) of molecular weights from 9000-146,000. The molecular weight of PVA had little effect on the success of hydrothermal hectorite synthesis, d-spacing or the amount of polymer incorporated. The basal spacings range from 19.5 Å to 20.8 Å and the amount of polymer incorporated ranges from 20 wt.% to 23 wt.%. Incorporation of PVA within the clay inter-layers, along with Li(I) ions to compensate the lattice charge, is indicated. Thermal gravimetric analysis and small angle neutron scattering were used to further examine the polymer-clay systems. Small PVA-clay crystallites that are coated with excess PVA are indicated. Removal of the polymer does not alter the extended synthetic clay network, and the nitrogen BET surface area increases from <5 m2/g to >200 m2/g.
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The submitted manuscript has been authored by a contractor of the U.S. Government under contract No, W-31-109- ENG-38. Accordingly, the U.S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for U.S. Government purposes.
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Carrado, K.A., Thiyagarajan, P. & Elder, D.L. Polyvinyl Alcohol-Clay Complexes Formed by Direct Synthesis. Clays Clay Miner. 44, 506–514 (1996). https://doi.org/10.1346/CCMN.1996.0440409
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DOI: https://doi.org/10.1346/CCMN.1996.0440409