Abstract
New regulators of radical polymerization of methyl methacrylate based on N-(aryl)-o-iminoquinones of various structures are proposed. It is shown that samples of polymethylmethacrylate with the participation of N-(aryl)-o-iminobenzoquinones could be used as macroinitiators of polymerization. Optimal conditions to synthesize polymers in the presence of o-iminobenzoquinones are determined, which make it possible to obtain polymethylmethacrylate with a polydispersity coefficient of no more than 1.5 on deep conversions during bulk polymerization.
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References
E. V. Kolyakina and D. F. Grishin, Russ. Chem. Rev. 80 (7), 683 (2011).
F. R. Mayo and R. A. Gregg, J. Am. Chem. Soc. 70 (3), 1284 (1948).
I. M. Kolthoff and F. A. Bovey, Chem. Rev. 42, 491 (1948).
D. F. Grishin, A. A. Shchepalov, and V. K. Cherkasov, J. Polym. Sci., Part A: Polym. Chem. 47 (9), 928 (2005).
J. R. Caille, A. Debuigne, and R. Jérôme, J. Polym. Sci., Part A: Polym. Chem. 43 (13), 2723 (2005).
A. Debuigne, J. R. Caille, and R. Jérôme, Macromolecules 38 (15), 6310 (2005).
T. Fukuda and A. Goto, Polym. Sci., Compr. Ref. 3, 119 (2012).
The Chemistry of Quinoid Compounds, Ed. by S. Patai and Z. Rappoport (Wiley, New York, 1988).
L. B. Vaganova, O. S. Lizyakina, M. G. Chegerev, A. V. Piskunov, and D. F. Grishin, RF Patent No. 2604538 (2016).
L. B. Vaganova, A. N. Kaprinina, I. N. Meshcheryakova, M. G. Chegerev, A. V. Piskunov, and D. F. Grishin, Russ. Chem. Bull., Int. Ed. 63 (3), 744 (2014).
L. B. Vaganova, A. A. Shchepalov, I. N. Meshcheryakova, M. G. Chegerev, A. V. Piskunov, and D. F. Grishin, Dokl. Chem. 447 (2), 286 (2012).
Encyclopedia of Polymers (Sovetskaya Entsiklopedia, Moscow, 1972), Vol. 1 [in Russian].
Synthesis of Organic Drugs, Ed. by B. A. Kazanskii (Izd. Inostr. Lit., Moscow, 1953) [in Russian].
A. J. Gordon and R. A. Ford, The Chemists Companion (Wiley, New York, 1972).
G. A. Abakumov, N. O. Druzhkov, Yu. A. Kurskii, and A. S. Shavyrin, Russ. Chem. Bull., Int. Ed. 52 (3), 712 (2003).
A. I. Poddel’sky, Y. A. Kuskii, A. V. Piskunov, N. V. Somov, V. K. Cherkasov, and G. A. Abakumov, Appl. Organomet. Chem. 25 (3), 180 (2011).
G. A. Abakumov, V. K. Cherkasov, N. O. Druzhkov, Y. A. Kuskii, G. K. Fukin, L. G. Abakumova, and T. N. Kocherova, Synth. Commun. 36 (21), 3241 (2006).
B. G. Belen’kii and L. Z. Vilenchik, Chromatography of Polymers (Khimiya, Moscow, 1978) [in Russian].
A. Carrington and A. D. McLachlan, Introduction to Magnetic Resonance with Applications to Chemistry and Chemical Physics (Harper&Row, New York, 1967).
A. V. Piskunov, I. N. Meshcheryakova, E. V. Baranov, G. K. Fukin, V. K. Cherkasov, and G. A. Abakumov, Russ. Chem. Bull., Int. Ed. 59, 361 (2010).
O. G. Mishchenko, I. V. Spirina, S. V. Maslennikov, A. V. Piskunov, I. N. Meshcheryakova, S. V. Panteleev, and R. V. Kroik, Russ. J. Gen. Chem. 84 (4), 642 (2014).
G. A. Abakumov, N. O. Druzhkov, Yu. A. Kurskii, L. G. Abakumova, A. S. Shavyrin, G. K. Fukin, A. I. Poddel’skii, V. K. Cherkasov, and L. S. Okhlopkova, Russ. Chem. Bull., Int. Ed. 47 (11), 2571 (2005).
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Original Russian Text © L.B. Vaganova, O.S. Lizyakina, M.G. Chegerev, A.V. Piskunov, D.F. Grishin, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2017, Vol. 59, No. 5, pp. 326–336.
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Vaganova, L.B., Lizyakina, O.S., Chegerev, M.G. et al. Polymerization of methyl methacrylate in the presence of o-iminoquinones: Reversible and irreversible inhibition. Polym. Sci. Ser. B 59, 506–515 (2017). https://doi.org/10.1134/S1560090417050165
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DOI: https://doi.org/10.1134/S1560090417050165