Abstract
It was found that, in diacetylene oligomers constisred of monomer units with an non-conjugated system of π-electrons, the efficiency of fluorescence quenching depends on the chain length within the range from 2 to 40 repeating units. This effect is consistent with the model of propagation of delocalized excitons in a noncovalent aggregate of several oligomer chains. The result obtained in the study confirms the assumption that a collective effect due to excitons can exist in a supramolecular aggregate of non-conjugated molecules.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Nielsen, C.B. and McCulloch, I., Progr. Polym. Sci.; 2013, http://dx.doi.org/10.1016/j.progpolymsci. 2013.05.003.
Chen, J.-T. and Hsu, C.-S., Polymer 2013; http://dx.doi.org/10.1016/j.polymer.2013.04.037.
Andrew, T.L. and Swager, T.M., J. Polym. Sci. B: Polym. Phys., 2011, vol. 49, pp. 476–498.
Grancini, G., Maiuri, M., Fazzi, D., et al., Nature Mater., 2013, vol. 12, pp. 29–33.
Kose, M.E., Graf, P., Kopidakis, N., et al., ChemPhysChem., 2009, vol. 10, pp. 3285–3294.
Clavaguera, S., Dautel, O.J., Hairault, L., et al., J. Polym. Sci.: A: Polym. Chem., 2009, vol. 47, pp. 4141–4149.
Chasteena, S.V., Carter, S.A., and Rumbles, G., J. Chem. Phys., 2006, vol. 124, pp. 214704-1–214704-6.
Xie, D., Parthasarathy, A., and Schanze, K.S., Langmuir, 2011, vol. 27, pp. 11732–11736.
Prokhorov, V.V., Pozin, S.I., Lypenko, D.A., et al., Chem. Phys. Lett., 2012, vol. 535, pp. 94–99.
Lim, J.M., Kim, P., Yoon, M.-C., et al., Chem. Sci., 2013, vol. 4, pp. 388–397.
Siemsen, P., Livingston, R.C., and Diederich, F., Angewandte Chem., Int. Ed., 2000, vol. 39, pp. 2632–2657.
Balaraman, K. and Kesavan, V., Synthesis, 2010, vol. 20, pp. 3461–3466.
Vlasov, Yu.G., Levichev, S.S., and Kruchinin, A.A., Russ. J. Appl. Chem., 2012, vol. 85, no. 6, pp. 940–944.
Potapov, A.S., Khlebnikov, A.I., and Vasilevskii, S.F., Russ. J. Org. Chem., 2006, vol. 42, no. 9, pp. 1368–1373.
Lakowicz, J.R., Principles of Fluorescence Spectroscopy, New York, 1999, p. 239.
Banjoko, V., Xu, Y., Mintz, E., and Pang, Y., Polymer, 2009, vol. 50, pp. 2001–2009.
Pilzak, G.S., Baggerman, J., van Lagen, B., et al., Chem. Eur. J., 2009, vol. 15, pp. 2296–2304.
Yao, H., Domoto, K., Isohashi, T., and Kimura, K., Langmuir, 2005, vol. 21, pp. 1067–1073.
Kirkus, M., Wang, L., Mothy, S., et al., J. Phys. Chem. A, 2012, vol. 116, pp. 7927–7936.
Wanichacheva, N., Prapawattanapol, N., Lee, V.S., et al., J. Luminescence, 2013, vol. 134, pp. 686–690.
Spano, F.C., Accounts Chem. Research, 2010, vol. 43, pp. 429–439.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original English Text © Yu.G. Vlasov, A.A. Kruchinin, D.S. Ryabukhin, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 11, pp. 1711–1717.
Rights and permissions
About this article
Cite this article
Vlasov, Y.G., Kruchinin, A.A. & Ryabukhin, D.S. Fluorescence quenching features in non-conjugated diacetylene oligomers. Russ J Appl Chem 86, 1663–1669 (2013). https://doi.org/10.1134/S1070427213110062
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427213110062