Abstract
Acetoxylation of octa-1,3-dienylbenzene in glacial acetic acid in the presence of catalysts with intermetallic phases based on Pd and Rh and Group IIIA-VIA elements was studied. The relationship between the total selectivity of the reaction with respect to diacetoxy derivatives and the Aller-Rochow electronegativity of second modifying elements was examined. The most efficient catalytic systems were determined.
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de Vekki, A.V., Okislitel’noe atsetoksilirovanie nenasyshchennykh uglevo dorodov v prisutstvii metallokompleksnykh i intermetallicheskikh katalizatorov (Oxidative Acetoxylation of Unsaturated Hydrocarbons in the Presence of Metal-Complex and Intermetallic Catalysts), Moscow: TsNIITEneftekhim., Ser. Neftekhim., 1996, issues 1–2.
Grisha, A.S. and de Vekki, A.V., Abstracts of Papers, XIV Mezh dunarodnaya Chugaevskaya konferentsiya po koordinatsionnoi khimii, 06–11 iyunya 2011 g. (XIV Int. Chugaev Conf. on Coordination Chemistry, June 06–11, 2011), Suzdal’, 2011.
de Vekki, A.V. and Yakushkin, M.I., Kinet. Kataliz, 1987, vol. 28, no. 5, pp. 1099–1104.
de Vekki, A.V., Zh. Prikl. Khim., 1996, vol. 69, no. 10, pp. 1691–1696.
de Vekki, A.V., Catalytic Oxidative Acetoxylation of Unsaturated Hydrocarbons, Doctoral Dissertation, St. Petersburg, 1994.
de Vekki, A.V., Yakushkin, M.I., and Kul’chitskaya, T.Yu., Kinet. Kataliz, 1988, vol. 29, no. 6, pp. 1355–1361.
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Original Russian Text © A.S. Grisha, A.V. de Vekki, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 7, pp. 1129–1134.
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Grisha, A.S., de Vekki, A.V. Catalytic oxidative acetoxylation of octa-1,3-dienylbenzene. Russ J Appl Chem 84, 1201–1206 (2011). https://doi.org/10.1134/S1070427211070135
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DOI: https://doi.org/10.1134/S1070427211070135