Abstract
High-resolution 19F and 13C NMR spectra of difluoro(fluorosulfonyl)- and difluoro(fluorosulfonyloxy) acetyl fluorides were studied, and specific features of complex spin-spin coupling of fluorine and carbon nuclei were characterized. The mechanisms of 19F and 13C coupling were interpreted.
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Harris, R.K. and Woodman, C.M., J. Mol. Spectrosc., 1968, vol. 26, pp. 432–433.
Rae, D., Weigold, J.A., Contreras, R.H., and Biekofsky, R.R., Magn. Reson. Chem., 1993, vol. 31, pp. 836–840.
Mallory, C.W. and Baker, M.B., J. Am. Chem. Soc., 1990, vol. 112, pp. 2577–2581.
Brey, W.S., J. Fluorine Chem., 2005, vol. 126, pp. 389–399.
Adcock, W., Matthews, D.G., and Risvi, S.Q.A., Aust. J. Chem., 1971, vol. 24, pp. 1829–1838.
Adcock. W. and Risvi, S.Q.A., Aust. J. Chem., 1973, vol. 26, pp. 2659–2663.
Adcock, W., Bullpitt, M., and Kitching, W., J. Org. Chem., 1977, vol. 42, pp. 2411–2418.
Contreras, R.H., Rae, I.D., Staffa, A., et al., Aust. J. Chem., 1987, vol. 40, pp. 1923–1940.
Contreras, R.H., Keavy, D.J., Olson, E.R., et al., Magn. Res. Chem., 1991, vol. 29, pp. 422–432.
Kimber, B.J., Feeney, J., Roberts, G.C.K., et al., Nature, 1978, vol. 271, pp. 184–185.
Ng, S. and Sederholm, C.H., J. Chem. Phys., 1964, vol. 40, no. 8, pp. 2090–2094.
Brey, W.S., J. Fluorine Chem., 2005, vol. 126, pp. 389–399.
Kvíčala, J., Hrabal, R., Czernek, J., et al., J. Fluorine Chem., 2002, vol. 113, pp. 211–218.
Jaime-Figueroa, S., Kurz, L.J., Liu, Y., and Cruz, R., Spectrochim. Acta, Part A, 2000, vol. 56, pp. 1167–1178.
Zhang, C.-P., Wang, Z.-L., Chen, Q.-Y., et al., J. Fluorine Chem., 2010, vol. 131, no. 3, pp. 433–438.
US Patent 4466881.
Petrakis, L. and Sederholm, C.H., J. Chem. Phys., 1961, vol. 35, pp. 1243–1248.
Lindon, J.C., Tranter, G.E., and Holmes, J.L., Encyclopedia of Spectroscopy and Spectrometry, Elsevier, 2000.
Liu, P., Goddard, J.D., Arsenault, G., et al., Chemosphere, 2007, vol. 69, no. 8, pp. 1213–1220.
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Original Russian Text © G.A. Emel’yanov, V.I. Polyanskii, D.M. Kostycheva, L.V. Osetrova, V.M. Rodin, E.E. Shchadilova, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 3, pp. 445–450.
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Emel’yanov, G.A., Polyanskii, V.I., Kostycheva, D.M. et al. An experimental study of 19F-19F and 13C-19F spin-spin coupling in molecules of difluoro(fluorosulfonyl)- and difluoro(fluorosulfonyloxy)acetyl fluorides. Russ J Appl Chem 84, 437–442 (2011). https://doi.org/10.1134/S1070427211030189
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DOI: https://doi.org/10.1134/S1070427211030189