Abstract
Interaction of ethyl cyanoacetate with hydrogen selenide afforded new reagent for obtaining selenium-containing heterocycles such as ethyl 3-amino-3-selenoxopropanoate. Starting from the latter substituted selenazoles and ethyl 3-selenoxo-2,3,5,6,7,8-hexahydroisiquinoline-4-carboxylates were synthesized. The structure of the obtained compounds was confirmed by IR, NMR spectroscopy and gas chromatography-mass spectrometry.
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Mlochowski, J., Kloc, K., Lisiak, R., Potaszek, P., and Wojtowicz, H., Arkivoc, 2007, p. 14.
EP Patent 1541145, 2003.
US Patent US 6620804, 2003.
US Patent 7087639, 2006.
Litvinov, V.P. and Dyachenko, V.D., Russ. Chem. Rev., 1997, vol. 66, no. 11, p. 923.
Murai, T., Top. Curr. Chem., 2005, vol. 251, p. 247. DOI: 10.1007/b101011.
Ninomiya, M., Garud, D.R., and Koketsu, M., Coord. Chem. Rev., 2011, vol. 255, nos. 23–24, p. 2968. DOI: 10.1016/j.ccr.2011.07.009.
Litvinov, V.P. and Dyachenko, V.D., Doklady Akad. Nauk, 1997, vol. 352, no. 5, p. 636.
Dyachenko, I.V., Ramazanova, E.Yu., and Dyachenko, V.D., Russ. J. Org. Chem., 2007, vol. 50, no. 12, p. 1821. DOI: 10.1134/S1070428014120185.
Litvinov, V.P., Sharanin, Yu.A., Shestopalov, A.M., and Dyachenko, V.D., Synlett, 1992, no. 1, p. 87. DOI: 10.1055/s-1992-21277.
Dyachenko, V.D. and Litvinov, V.P., Doklady Akad. Nauk, 1997, vol. 355, no. 1, p. 62.
Geisler, K., Jacobs, A., Kunzler, A., Mathes, M., Girrleit, I., Zimmermann, B., Bulka, E., Pfeiffer, W.-D., and Langer, P., Synlett, 2002, no. 12, p. 1983. DOI: 10.1055/s-2002-35604.
Rappoport, Z., Acc. Chem. Res., 1992, vol. 25, no. 10, p. 474. DOI: 10.1021/ar00022a007.
Litvinov, V.P., Yakunin, Ya.Yu., and Dyachenko, V.D., Chem. Heterocycl. Compd., 2001, vol. 37, no. 1, p. 37. DOI: 10.1023/A:1017536700235.
Dyachenko, I.V. and Vovk, M.V., Russ. J. Org. Chem., 2013, vol. 49, no. 5, p. 771. DOI: 10.1134/S107042801305028X.
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Original Russian Text © I.V. Dyachenko, V.D. Dyachenko, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 7, pp. 1152–1155.
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Dyachenko, I.V., Dyachenko, V.D. Ethyl 3-amino-3-selenoxopropanoate as a new reagent for the synthesis of selenium-containing heterocycles. Russ J Gen Chem 85, 1673–1676 (2015). https://doi.org/10.1134/S1070363215070178
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DOI: https://doi.org/10.1134/S1070363215070178