Abstract
We studied the effect of bis[4,6-di-tert-butyl-N-(2,6-dimethylphenyl)-ortho-iminobenzosemi-quinono]cobalt(II) on the kinetics of the bulk polymerization of methyl methacrylate at 70°C and on the molecular-weight characteristics of the polymer synthesized. The effective chain transfer constant in the polymerization of methyl methacrylate in the presence of the complex in benzene at 70°C was determined by the Mayo method and by linearizing the macromolecule chain length distribution. The constants obtained were compared with the same parameters available from the literature for a number of known chain-transfer agents, viz., dodecyl mercaptan and cobalt porphyrin and oxime complexes.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
di Lena, F. and Matyjaszewski, K., Prog. Polym. Sci., 2010, vol. 35, no. 8, p. 959.
Grishin, D.F., Polym. Sci., Ser. C, 2011, vol. 53, p. 3.
Nicolas, J., Guillaneuf, Y., Lefay, C., Bertin, D., Gigmes, D., and Charleux, B., Prog. Polym. Sci., 2013, vol. 38, no. 1, p. 63.
Kolyakina, E.V. and Grishin, D.F., Russ. Chem. Rev., 2009, vol. 78, no. 6, p. 535.
Satoh, K., Kamigaito, M., and Sawamoto, M., Polym. Sci.: Compr. Ref., 2012, vol. 3, p. 429.
Debuigne, A., Poli, R., Jérômea, C., Jérômea, R., and Detrembleura, C., Prog. Polym. Sci., 2009, vol. 34, no. 3, p. 211
Poli, R., Polym. Sci.: Compr. Ref., 2012, vol. 3, p. 351.
Kolyakina, E.V. and Grishin, D.F., Russ. Chem. Rev., 2011, vol. 80, no. 7, p. 681.
Moad, G., Rizzardo, E., and Thang, S.H., Polymer, 2008, vol. 49, no. 5, p. 1079.
Smirnov, B.R., Morozova, I.S., Pushchaeva, L.M., Marchenko, A.P., and Enikolopyan, N.S., Dokl. Akad. Nauk SSSR, 1980, vol. 255, p. 603.
Enikolopyan, N.S., Smirnov, B.R., Ponomarev, G.V., and Belgovskii, I.M., J. Polym. Sci., Part A: Polym. Chem., 1981, vol. 19, p. 879.
Gridnev, A.A. and Ittel, S.D., Chem. Rev., 2001, vol. 101, no. 12, p. 3611.
Slavin, S., McEwan, K., and Haddleton, D.M., Polym. Sci.: Compr. Ref., 2012, vol. 3, p. 249.
Wayland, B.B., Poszmik, G., Mukerjee, S.L., and Fryd, M., J. Am. Chem. Soc., 1994, vol. 116, no. 17, p. 7943.
Wayland, B.B., Peng, C-H., Fu, X., Lu, Z., and Fryd, M., Macromolecules, 2006, vol. 39, no. 24, p. 8219.
Maria, S., Kaneyoshi, H., Matyjaszewski, K., and Poli, R., Chem. Eur. J., 2007, vol. 13, no. 9, p. 2480.
Li, Z.H., Zhang, Y.M., Xue, M.Z., Zhou, L., and Liu, Y.G., J. Polym. Sci., Part A: Polym. Chem., 2005, vol. 43, no. 21, p. 5207.
Huang, Z.-X., Zhang, Y.-M., Li, H., and Liu, Y.-G., Macromol. Chem. Phys., 2008, vol. 209, no. 8, p. 825.
Bao, F., Feng, L., Gao, J., Tan, Z., Xing, B., Ma, R., and Yan, C., PLoS ONE, 2010, vol. 5, no. 10, e13629. www.plosone.org
Kolyakina, E.V., Poddel’skii, A.I., and Grishin, D.F., Khim. Prom-st., 2013, vol. 90, no. 3, p. 107.
Kolyakina, E.V., Poddel’skii, A.I., and Grishin, D.F., Russ. Chem. Byull., 2014, vol. 63, p. 987.
Poddel’sky, A.L., Cherkasov, V.K., Fukin, G.K., Bubnov, M.P., Abakumova, L.G., and Abakumov, G.A., Inorg. Chim. Acta, 2004, vol. 357, no. 12, p. 3632.
Organic Syntheses, New York: Wiley, 1946–1952, vols. 26–32.
Weissberger, A., Proskauer, E.S., Riddick, J.A., and Toops, E.E., Technics of Organic Chemistry, vol. 7: Organic Solvents: Physical Properties and Methods of Purification, New York: Wiley, 1955.
Arulin, V.I. and Efimov, L.I., in Tr. Khim. Khim. Tekhnol. Gor’kov. Gos. Univ., 1970, no. 2, p. 74.
Belen’kii, B.G. and Vilenchik, L.Z., Khromatografiya polimerov (Chromatography of Polymers), Moscow: Khimiya, 1978.
US Patent 2006036049 A1, 2006.
WO Patent 2004007509, 2004.
Brasse, M., Cámpora, J., Davies, M., Teuma, E., Palma, P., álvarez, E., Sanz, E., and Reyes, M.L., Adv. Synth. Catal., 2007, vol. 349, no. 13, p. 2111.
Shamenkova, O.A., Kopylova, N.A., Semchikov, Yu.D., Kurskii, Yu.A., Cherkasov, V.K., and Abakumov, G.A., Polym. Sci., B, 2005, vol. 47, no. 11, p. 314.
Kolyakina, E.V., Vaganova, L.B., Lado, A.V., Piskunov, A.V., Cherkasov, V.K., and Grishin, D.F., Russ. Chem. Byull., 2007, vol. 56, p. 1363.
Vaganova, L.B., Kolyakina, E.V., Lado, A.V., Piskunov, A.V., and Grishin, D.F., Polym. Sci., B, 2009, vol. 51, nos. 3–4, p. 96.
Handbook of Radical Polymerization, Matyjaszewski, K. and Davis, T.P., Eds., Hoboken, N.J.: Wiley-Interscience, 2002.
Mayo, F.R., J. Am. Chem. Soc., 1943, vol. 65, no. 12, p. 2324.
Clay, P.A. and Gilbert, R.G., Macromolecules, 1995, vol. 28, no. 2, p. 552.
Heuts, J.P.A., Kukulj, D., Forster, D.J., and Davis, T.P., Macromolecules, 1998, vol. 31, p. 2894.
Kapfenstein, H.M. and Davis, T.P., Macromol. Chem. Phys., 1998, vol. 199, p. 2403.
Moad, G. and Moad, C.L., Macromolecules, 1996, vol. 29, p. 7727.
Heuts, J.P., Forster, D.J., Davis, T.P., Yamada, B., Yamazoe, H., and Azukizawa, M., Macromolecules, 1999, vol. 32, no. 8, p. 2511.
Polymer Handbook, Brandrup, J., Immergut, E.H., and Grulke, E.A., Eds., New York: Wiley, 1999.
Vollmerhaus, R., Pierik, S., and Herk, A., Macromol. Symp., 2001, vol. 165, no. 1, p. 123.
De la Fuente, J.L. and Madruga, E.L., J. Polym. Sci., Part A: Polym. Chem., 2000, vol. 38, no. 1, p. 170.
Madruga, E.L., Roman, J.S., and Benedi P., J. Appl. Polym. Sci., 1990, vol. 41, nos. 5–6, p. 1133.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.V. Kolyakina, Yu.E. Ovchinnikova, I.D. Grishin, A.I. Poddel’skii, D.F. Grishin, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 3, pp. 268–276.
Rights and permissions
About this article
Cite this article
Kolyakina, E.V., Ovchinnikova, Y.E., Grishin, I.D. et al. Methyl methacrylate polymerization involving a cobalt ortho-iminobenzosemiquinone complex: Determination of the chain transfer constant. Kinet Catal 56, 267–275 (2015). https://doi.org/10.1134/S0023158415030118
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0023158415030118