Abstract
The kinetics of radical copolymerization of N-vinylsuccinimide with n-butyl methacrylate in pyridine was studied, and the previously unknown copolymerization constants of the monomers were determined. The calculations were performed using appropriate software and a new procedure for approximation of the experimental data, which allow determination of the kinetic parameters at high conversions with the minimum error. The copolymerization kinetics were compared for the reaction systems constituted by N-vinylsuccinimide and n-butyl methacrylate and by N-vinylsuccinimide and n-butyl acrylate.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
REFERENCES
Lavrov, N.A., Shal'nova, L.I., and Nikolaev, A.F., Zh. Prikl. Khim., 1997, vol. 70, no. 8, pp. 1356–1363.
Lavrov, N.A., Shal'nova, L.I., and Nikolaev, A.F., Plast. Massy, 2001, no. 10, pp. 5–9.
Shal'nova, L.I., Chudnova, V.M., and Trofimova, E.A., Plast. Massy, 1989, no. 11, pp. 29–34.
Lavrov, N.A., Zh. Prikl. Khim., 2003, vol. 76, no. 9, pp. 1409–1414.
Lavrov, N.A., Sivtsov, E.V., and Pisarev, A.G., Zh. Prikl. Khim., 2003, vol. 76, no. 7, pp. 1154–1159.
Lavrov, N.A., Sivtsov, E.V., and Nikolaev, A.F., Zh. Prikl. Khim., 1998, vol. 71, no. 12, pp. 2055–2056.
Lavrov, N.A., Pisarev, A.G., and Sivtsov, E.V., Obrabotka dannykh kinetiki radikal'noi (so)polimerizatsii komp'yuternymi metodami (Computer Processing of Data on Radical (Co)polymerization)), St. Petersburg: Sankt-Peterb. Gos. Tekhnol. Inst. (Tekh. Univ.), 2003.
Ezrielev, A.I., Brokhina, E.L., and Roskin, E.S., Vysokomol. Soedin., Ser. A, 1969, vol. 11, no. 8, pp. 1670–1680.
9. Kelen, T. and T-ud-os, F.,J. Macromol. Sci., Part A, 1975, vol. 9, no. 1, pp. 1–27.
Rao, S.P., Ponzatnam, S., Kapur, S.L., and Lyer, P.K., J. Polym. Sci., Polym. Lett. Ed., 1976, vol. 14, no. 9, pp. 513–516.
Gindin, L.M., Abkin, A.D., and Medvedev, S.S., Dokl. Akad. Nauk SSSR, 1947, vol. 56, no. 2, pp. 177–180.
Gindin, L.M., Abkin, A.D., and Medvedev, S.S., Zh. Fiz. Khim., 1947, vol. 21, no. 11, pp. 1269–1287.
Lavrov, N.A., Raschet cheredovaniya zven'ev v sopolimerakh(Calculation of Unit Alternation in Copolymers), Leningrad: Leningr. Tekhnol. Inst. im. Lensoveta, 1988.
Lavrov, N.A., Sivtsov, E.V., and Pisarev, A.G., Plast. Massy, 2001, no. 11, pp. 13–14.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lavrov, N.A., Pisarev, A.G. & Sivtsov, E.V. Copolymerization of N-Vinylsuccinimide with Butyl Methacrylate in Pyridine. Russian Journal of Applied Chemistry 77, 603–607 (2004). https://doi.org/10.1023/B:RJAC.0000038677.72892.50
Issue Date:
DOI: https://doi.org/10.1023/B:RJAC.0000038677.72892.50