Abstract
Emulsifier-free emulsion copolymerization of acrolein with styrene and methyl methacrylate in the presence of potassium persulfate was developed to prepare microspheres with surface aldehyde groups. The kinetics of monomer copolymerization was studied and the conditions for preparing monodisperse microspheres 370-1000 nm in diameter were determined.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
REFERENCES
Prokopov, N.I., Gritskova, I.A., Cherkasova, V.R., and Chalykh, A.E., Usp. Khim., 1996, vol. 65, no. 2, pp. 178-192.
Margel, S. and Wiesel, E., J. Polym. Sci., Polym. Chem. Ed., 1984, vol. 22, no. 1, pp. 145-151.
Rembaum, A., Chang, M., and Richards, G., J. Polym. Sci., Polym. Chem. Ed., 1984, vol. 22, no. 3, pp. 609-621.
Pavlova, I.S., Lukin, Yu.V., Kovalenko, V.A., et al., Bioorg. Khim., 1994, vol. 20, no. 7, pp. 731-739.
Zhorov, O.V., Preigerzon, V.A., Lukin, Yu.V., et al., Bioorg. Khim., 1995, vol. 21, no. 4, pp. 261-263.
LeDissez, C., Wong, P.C., Mitchell, A.R., and Brooks, D.E., Macromolecules, 1996, vol. 29, no. 3, pp. 953-959.
Kowalczuk, D., Marsault, J.-P., and Slomkowski, S., Colloid Polym. Sci., 1996, vol. 274, no. 6, pp. 513-519.
Yan, C., Zanhg, X., and Sun, Z., J. Appl. Polym. Sci., 1990, vol. 40, no. 1, pp. 89-98.
Lishanskii, I.S., Men'shikova, A.Yu., Evseeva, T.G., et al., Vysokomol. Soedin., 1991, vol. 33, no. 6, pp. 413-416.
Men'shikova, A.Yu., Dmitrieva, I.B., Kuchuk, V.I., et al., Kolloidn. Zh., 1999, vol. 61, no. 6, pp. 799-808.
Tennikova, T.B. and Freitag, R., J. High Resol. Chromatogr., 2000, vol. 23, no. 1, pp. 27-38.
Eliseeva, V.I., Polimernye dispersii (Polymer Dispersions), Moscow: Khimiya, 1980.
Copolymerization, Ham, G.E., Ed., New York: Interscience, 1964.
Eliseeva, V.I. and Aslamazova, T.R., Usp. Khim., 1991, vol. 60, no. 2, pp. 398-429.
Suzawa, T. and Shirahama, H., Adv. Colloid Interface Sci., 1991, vol. 35, pp. 139-172.
Men'shikova, A.Yu., Skurkis, Yu.O., Kuchuk, V.I., et al., Kolloidn. Zh., 2001, vol. 63, no. 5, pp. 678-686.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Men'shikova, A.Y., Evseeva, T.G., Chekina, N.A. et al. Monodisperse Microspheres Based on Acrolein Copolymers. Russian Journal of Applied Chemistry 74, 1728–1734 (2001). https://doi.org/10.1023/A:1014825823341
Issue Date:
DOI: https://doi.org/10.1023/A:1014825823341