Abstract
Oxidative dehydrogenation of propane to propene was investigated over Ba- promoted Ni0.9MoO4 catalysts (molar ratio of Ba/Mo: 1%, 3%, 6%, 9%, 12%, 15%). The selectivity for propene increases with the increasing number of basic sites on the catalyst, and molybdenum ions play an important role in propane activation. No significant deactivation of the 6% Ba- Ni0.9MoO4 and Ni0.9MoO4 at 773 K for 80 h and for 40 h, respectively, appeared, indicating that the 6% Ba- Ni0.9MoO4 has great advantage over the Ni0.9MoO4.
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Liu, Y., Wang, J., Zhou, G. et al. Oxidative Dehydrogenation of Propane to Propene over Barium Promoted Ni-Mo-O Catalyst. Reaction Kinetics and Catalysis Letters 73, 199–208 (2001). https://doi.org/10.1023/A:1014132332554
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DOI: https://doi.org/10.1023/A:1014132332554