Abstract
Covalent organic frameworks(COFs) are emerging photocatalysts for hydrogen evolution in water splitting in recent years. They offer a pre-designable platform to design tailor-made structures and chemically adjustable functionality in terms of photocatalysis. In this review, we summarize the recent striking progress of COF-based photocatalysts in design and synthesis. Firstly, different approaches to functionalizing building blocks, diversifying linkages, extending π-conjugation and establishing D-A conjugation are illustrated for enhancing photocatalytic activity. Next, post-modification of backbones and pores is detailed for emphasizing the synergistic catalytic uniqueness of COFs. Besides, the strategy of preparing COF-related composites with various semiconductors is outlined for optimizing the electronic properties. Finally, we conclude with the current challenges and promising opportunities for the exploration of new COF-based photocatalysts.
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This work was supported by the National Natural Science Foundation of China(No. 51973039).
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Liu, S., Guo, J. Two-dimensional Covalent Organic Frameworks: Intrinsic Synergy Promoting Photocatalytic Hydrogen Evolution. Chem. Res. Chin. Univ. 38, 373–381 (2022). https://doi.org/10.1007/s40242-022-2007-z
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DOI: https://doi.org/10.1007/s40242-022-2007-z