Abstract
Three new compounds, namely, [Zn(mtpo)2(H2O)4](1), [Cd(mtpo)2·CH3CH2OH] n (2) and [Mn(mtpo)2·CH3CH2OH] n (3)(Hmtpo=4,7-dihydro-5-methyl-7-oxo-[1,2,4]triazolo[1,5-a]pyrimidine), have been synthesized via hydrothermal or solvothermal methods and characterized by means of elemental analyses, Fourier transform infrared(FTIR) spectroscopy, powder X-ray diffraction(PXRD), thermogravimetric analysis(TGA) and single-crystal X-ray diffraction. The results obtained from the single-crystal X-ray diffraction indicate that compound 1 has a mononuclear structure, and crystallizes in a monoclinic crystal system with P21/c space group, which exhibits a 2D supramolecular network constructed by hydrogen bonds and π-π interactions. Compounds 2 and 3 are isomorphous and crystallize in a tetragonal system with space group of I41/a. The M2+(M=Cd, Mn) ions in compounds 2 and 3 have the octahedral coordination geometry. Hmtpo acts as a bridging ligand linking the metal ions to form an infinite 3D framework with 4-connected {42·84} topology. There are hydrogen bonds between the guest ethanol molecules and the mtpo− ligands, which make the ethanol molecules exist in a 3D framework. In addition, luminescent properties of compounds 1 and 2 as well as magnetic property of compound 3 were investigated and water vapor adsorption and nitrogen sorption for compounds 2 and 3 were researched at 298 and 77 K, respectively.
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Supported by the National Natural Science Foundation of China(Nos.21271024, 20971014) and the Natural Science Foundation of Beijing City, China(No.2112037).
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Lü, L., Mu, B., Li, N. et al. Synthesis, structures and properties of three new compounds based on multidentate ligand containing triazole and pyrimidine. Chem. Res. Chin. Univ. 31, 712–718 (2015). https://doi.org/10.1007/s40242-015-5051-0
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DOI: https://doi.org/10.1007/s40242-015-5051-0