Abstract
As N-isopropyl-2-propanamine+alkanol (C1-C3) systems are potential absorbents for CO2 capture, we measured density (ρ), viscosity (η) and the ultrasonic speed data (u) for N-isopropyl-2-propanamine (DIPA) with alkanol (C1-C3) at T=(298.15 and 308.15) K and 0.1 MPa. The experimental density (ρ), viscosity (η) and ultrasonic speed (u) data were used to derive excess molar volume (V Em ), apparent, partial, and excess partial molar volume, deviation in viscosity and deviation in ultrasonic speed, excess isentropic compressibility (\(\kappa _s^E\)). We predicted the V Em values using the Prigogine-Flory-Patterson theory (PFP) and by Nakata and Sakurai model. An Ab initio approach was proposed for the excess isentropic compressibility \((\kappa _s^E)\) and Δη data which not only reproduces the experimental data but also gives important parameters that describe the extent of depolymerization on mixing and strength of intermolecular interactions.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
N. Cahill, Significance, 15, 24 (2018).
H. Kwon, K. Tak, S. Maken, H. Kim, J. Park and I. Moon, Korean J. Chem. Eng., 34, 3048 (2017).
R. A. Kerr, Science, 312, 825 (2006).
F. Kong, G. Rim, M. G. Song, C. Rosu, P. Priyadarshini, R. P. Lively, M. J. Realff and C. W Jones, Korean J. Chem. Eng., 39(1), 1 (2022).
S. Chu, Science, 325, 1599 (2009).
M. Meinshausen, N. Meinshausen, W. Hare, S. C. Raper, K. Frieler, R. Knutti, D. J. Frame and M. R. Allen, Nature, 458, 1158 (2009).
H.-J. Song, S. Lee, S. Maken, S.-W. Ahn, J.-W. Park, B. Min and W. Koh, Energy Policy, 35, 5109 (2007).
H.-J. Song, S. Lee, S. Maken, J.-J. Park and J.-W Park, Fluid Phase Equilib, 246, 1 (2006).
S. Lee, J.-W Park, H.-J. Song, S. Maken and T. Filburn, Energy Policy, 36, 326 (2008).
A. Gaur, J.-W. Park, S. Maken, H.-J. Song and J.-J. Park, Fuel Process. Technol., 91, 635 (2010).
S. Lee, S.-I. Choi, S. Maken, H.-J. Song, H.-C. Shin, J.-W Park, K.-R. Jang and J.-H. Kim, J. Chem. Eng. Data, 50, 1773 (2005).
S. Lee, H.-J. Song, S. Maken, H.-C. Shin, H.-C. Song and J.-W Park, J. Chem. Eng. Data, 51, 504 (2006).
S. Lee, S. Maken, J.-W. Park, H.-J. Song, J. J. Park, J.-G. Shim, J.-H. Kim and H.-M. Eum, Fuel, 87, 1734 (2008).
H. Liu, X. Lu, L. Liu, J. Wang, P. Wang, P. Gao, T. Ren, G. Tian and D. Wang, Korean J. Chem. Eng., 39(9), 2513 (2022).
R. R. Wanderley, G. J. Ponce and H. K. Knuutila, Energy Fuels, 34, 8552 (2020).
Z. Xu, S. Wang, J. Liu and C. Chen, Energy Procedia, 23, 64 (2012).
Y Zhang, Z. Wang and S. Wang, J. Appl. Polym. Sci., 86, 2222 (2002).
C. Dell’Era, P. Uusi-Kyyny, E.-L. Rautama, M. Pakkanen and V. Alopaeus, Fluid Phase Equilib., 299, 51 (2010).
Z. Li, D. Zhao, Y. Zhuang, F. Yang, X. Liu and Y. Chen, J. Chem. Thermodyn., 133, 37 (2019).
J. A. Riddick, W. B. Bunger and T. K. Sakano, Organic Solvents. Physical Properties and Methods of Purification, Fourth Ed., Wiley New York (1986).
M. Rani and S. Maken, Korean J. Chem. Eng., 30(8), 1636 (2013).
M. Rani, S. Maken and S. J. Park, Korean J. Chem. Eng., 36, 1401 (2019).
S. Gahlyan, M. Rani, I. Lee, I. Moon and S. K. Maken, Korean J. Chem. Eng., 32(1), 168 (2015).
S. Gahlyan, R. Devi, S. Verma, M. Rani, S. J. Park and S. Maken, Korean J. Chem. Eng., 37, 1181 (2020).
S. Oswal, P. Oswal, R. Gardas, S. G. Patel and R. G. Shinde, Fluid Phase Equilib., 216, 33 (2004).
P. Tyagi, K. Kumar, M. Rani and V. Bhankar, J. Chem. Eng. Data, 64, 3213 (2019).
G. P. Dubey and K. Kumar, J. Chem. Eng. Data, 61, 1967 (2016).
M. I. Aralaguppi, C. V. Jadar and T. M. Aminabhavi, J. Chem. Eng. i>Data, 44, 216 (1999).
E. Vercher, A. V Orchillés, P. J. Miguel and A. Martínez-Andreu, J Chem. Eng. Data, 52, 1468 (2007).
P. S. Nikam, M. C. Jadhav and M. Hasan, J. Chem. Eng. Data, 40, 931 (1995).
P. K. Pandey, V. K. Pandey, A. Awasthi, A. K. Nain and A. Awasthi, Thermochim. Acta, 586, 58 (2014).
R. Sadeghi and S. Azizpour, J. Chem. Eng. Data, 56, 240 (2011).
P. S. Nikam, L. N. Shirsat and M. Hasan, J. Chem. Eng. Data, 43, 732 (1998).
A. Estrada-Baltazar, G. A. Iglesias-Silva and C. Caballero-Cerón, J. Chem. Eng. Data, 58, 3351 (2013).
M. I. Aralaguppi, C. V. Jadar and T. M. Aminabhavi, J. Chem. Eng. Data, 44, 435 (1999).
S. Gahlyan, S. Verma, M. Rani and S. Maken, Korean Chem. Eng. Res., 55, 520 (2017).
C. A. Cerdeiriña, C. A. Tovar, J. Troncoso, E. Carballo and L. Romaní, Fluid Phase Equilib., 157, 93 (1999).
M. Rani, S. Gahlyan, A. Gaur and S. Maken, Chinese J. Chem. Eng., 23, 689 (2015).
S. Gahlyan, S. Verma, M. Rani and S. Maken, Korean J. Chem. Eng., 35, 1167 (2018).
S. L. Oswal and H. S. Desai, Fluid Phase Equilib, 149, 359 (1998).
N. Riesco, S. Villa, J. A. González, I. García de la Fuente and J. C. Cobos, Fluid Phase Equilib., 202, 345 (2002).
S. Gahlyan, N. Verma, S. Verma, M. Rani, S. J. Park and S. Maken, J. Mol. Liq., 298, 111946 (2020).
S. Gahlyan, S. Verma, M. Rani and S. Maken, J. Mol. Liq., 244, 233 (2017).
Y Maham, T. T. Teng, L. G. Hepler and A. E. Mather, J. Sol. Chem., 23, 195 (1994).
I. Prigogine, N. Trappeniers and V. Mathot, Discuss. Faraday Soc., 15, 93 (1953).
I. Prigogine, N. Trappeniers and V. Mathot, J. Chem. Phys., 21, 559 (1953).
I. Prigogine and V. Mathot, J. Chem. Phys., 20, 49 (1952).
I. Prigogine, A. Bellemans and V Mathot, The molecular theory of solutions north-holland publishing company, Amsterdam (1957).
M. Nakata and M. Sakurai, J. Chem. Soc. Faraday Trans. 1: Phys. Chem. Condens. Phases, 83, 2449 (1987).
P. Bhagat and S. Maken, Asian J. Chem., 32, 2443 (2020).
M. L. Huggins, J. Phys. Chem., 74, 371 (1970).
M. L. Huggins, Polymer, 12, 389 (1971).
P. Bhagat and S. Maken, J. Mol. Liq., 323(1), 114640 (2020).
Acknowledgement
This work was supported by Netaji Subhas University of Technology, New Delhi and Inha University Research Grant.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Supporting Information
Additional information as noted in the text. This information is available via the Internet at http://www.springer.com/chemistry/ journal/11814.
Supporting Information
11814_2023_1422_MOESM1_ESM.pdf
Thermophysical properties of N-isopropyl-2-propanamine+alkanol (C1-C3) mixtures as absorbents for carbon dioxide capture
Rights and permissions
About this article
Cite this article
Verma, S., Bhagat, P., Gahlyan, S. et al. Thermophysical properties of N-isopropyl-2-propanamine+alkanol (C1-C3) mixtures as absorbents for carbon dioxide capture. Korean J. Chem. Eng. 40, 2293–2302 (2023). https://doi.org/10.1007/s11814-023-1422-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-023-1422-2