Abstract
Used textiles, such as jeans wastes, exhibit a high potential for generating renewable and sustainable energy. However, limited research has been devoted toward investigating the kinetic and thermodynamic parameters of textile wastes during pyrolysis and applying these wastes as feedstock for fuels such as biogas. Therefore, this study investigated the kinetic and thermodynamic aspects of the thermal decomposition of jeans waste to evaluate its potential for sustainable energy production. Jeans waste was heat treated at 50–850 °C under different heating rates of 10–40 °C min−1. Active pyrolysis for the decomposition of jeans waste occurred at temperatures ranging from 250 to 550 °C. Specific Coats-Redfern-type reaction mechanisms were applied to determine the kinetic and thermodynamic variables in the active temperature zone. The thermodynamic parameters (ΔH and ΔG) and activation energies increased when the heating rate was increased from 10 to 30 °C min−1. When the heating rate was further increased to 40 °C min−1, ΔH, ΔG, and the activation energies decreased. For heating rates of 10, 20, 30, and 40 °C min−1, the pre-exponential factors varied in the ranges of 7.4×103 to 1.4×104, 1.8×104 to 5.1×1010, 2.8×104 to 5.3×1010, and 3.6×104 to 3.1×1010 min−1, respectively. In each reaction mechanism model, the entropy changed negatively for all the heating rates examined in this study. This work and its results could serve as a guide for implementing such pyrolysis processes for textile wastes at a practical scale for bioenergy applications.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
F. A. Brones, M. M. Carvalho and E. S. Zancul, J. Clean. Prod., 142, 8 (2017).
H. Rezk, A. M. Nassef, A. Inayat, E. T. Sayed, M. Shahbaz and A. G. Olabi, Sci. Total Environ., 658, 1150 (2019).
S. A. Sarkodie and V. Strezov, Sci. Total Environ., 639, 888 (2018).
M. Nazar, A. Yasar, S. A. Raza, A. Ahmad, R. Rasheed, M. Shahbaz and A. B. Tabinda, Biomass Convers. Biorefin., 11, 1 (2021).
J.-M. Ha, K.-R. Hwang, Y.-M. Kim, J. Jae, K. H. Kim, H. W. Lee, J.-Y. Kim and Y.-K. Park, Renew. Sust. Energ. Rev., 111, 422 (2019).
S. Oh, J. Lee, S. S. Lam, E. E. Kwon, J.-M. Ha, D. C. W. Tsang, Y. S. Ok, W-H. Chen and Y.-K. Park, Bioresour. Technol., 342, 126067 (2021).
M. Shahbaz, A. AlNouss, P. Parthasarathy, A. H. Abdelaal, H. Mackey, G. McKay and T. Al-Ansari, Biomass Convers. Biorefin., 12, 669 (2020).
S. Polat and P. Sayan, Energ. Source. Part A., 42, 1 (2020).
J.-Y. Kim, H. W. Lee, S. M. Lee, J. Jae and Y.-K. Park, Bioresour. Technol., 279, 373 (2019).
J. Lee, E. E. Kwon, S. S. Lam, W.-H. Chen, J. Rinklebe and Y.-K. Park, J. Clean. Prod., 321, 128989 (2021).
C. Park and J. Lee, Int. J. Energy Res., 45, 13088 (2021).
L. J. R. Nunes, R. Godina, J. C. O. Matias and J. P. S. Catalão, J. Clean. Prod., 171, 1353 (2018).
M. del Mar Barbero-Barrera, O. Pombo and M. de los Angeles Navacerrada, Compos. B. Eng., 94, 26 (2016).
R. Paul, Denim, Woodhead Publishing, United Kingdom (2015).
X. Meng, W. Fan, Y. Ma, T. Wei, H. Dou, X. Yang, H. Tian, Y. Yu, T. Zhang and L. Gao, Text. Res. J., 90, 695 (2020).
P. Peña-Pichardo, G. Martínez-Barrera, M. Martínez-López, F. Ureña-Núñez and J. M. L. dos Reis, Constr. Build. Mater., 177, 409 (2018).
H. Dahlbo, K. Aalto, H. Eskelinen and H. Salmenperä, Sustain. Prod. Consum., 9, 44 (2017).
C. Wen, Y. Wu, X. Chen, G. Jiang and D. Liu, J. Therm. Anal. Calorim., 128, 581 (2017).
A. Hanoğlu, A. Çay and J. Yanik, Energy J., 166, 664 (2019).
X. Chen, Y. Chen, H. Yang, W. Chen, X. Wang and H. Chen, Bioresour. Technol., 233, 15 (2017).
M. W. Seo, S. H. Lee, H. Nam, D. Lee, D. Tokmurzin, S. Wang and Y.-K. Park, Bioresour. Technol., 343, 126109 (2022).
S. Jung, N. P. Shetti, K. R. Reddy, M. N. Nadagouda, Y.-K. Park, T. M. Aminabhavi and E. E. Kwon, Energy Convers. Manag., 236, 114038 (2021).
Q. T. Trinh, A. Banerjee, K. B. Ansari, D. Q. Dao, A. Drif, N. T. Binh, D. T. Tung, P. M. Q. Binh, P. N. Amaniampong and P. T. Huyen, Biorefinery of alternative resources: Targeting green fuels and platform chemicals, Springer, Singapore (2020).
S. R. Naqvi, R. Tariq, Z. Hameed, I. Ali, S. A. Taqvi, M. Naqvi, M. B. K. Niazi, T. Noor and W. Farooq, Fuel, 233, 529 (2018).
S. Yousef, M. Tatariants, M. Tichonovas, Z. Sarwar, I. Jonuškienė and L. Kliucininkas, Resour. Conserv. Recycl., 145, 359 (2019).
J. Lee, E. E. Kwon and Y.-K. Park, Catal. Today, 355, 263 (2020).
Y.-M. Kim, J. Jae, B.-S. Kim, Y. Hong, S.-C. Jung and Y.-K. Park, Energy Convers. Manag., 149, 966 (2017).
S. Valizadeh, S. S. Lam, C. H. Ko, S. H. Lee, A. Farooq, Y. J. Yu, J.-K. Jeon, S.-C. Jung, G. H. Rhee and Y.-K. Park, Bioresour. Technol., 320, 124313 (2021).
S. Valizadeh, S.-H. Jang, G. Hoon Rhee, J. Lee, P. Loke Show, M. Ali Khan, B.-H. Jeon, K.-Y. Andrew Lin, C. Hyun Ko, W.-H. Chen and Y.-K. Park, Chem. Eng. J., 433, 133793 (2022).
D. Zeng, S. Wang, J. Peng, Y. Gui, H. Liu, F. Yang and M. Li, ChemistrySelect, 4, 7649 (2019).
S. Yousef, J. Eimontas, N. Striūgas, M. Tatariants, M. A. Abdelnaby, S. Tuckute and L. Kliucininkas, Energy Convers. Manag., 196, 688 (2019).
S. R. Naqvi, R. Tariq, Z. Hameed, I. Ali, M. Naqvi, W.-H. Chen, S. Ceylan, H. Rashid, J. Ahmad and S. A. Taqvi, Renew. Energy, 131, 854 (2019).
G. Mishra, J. Kumar and T. Bhaskar, Bioresour. Technol., 182, 282 (2015).
S. R. Naqvi, Z. Hameed, R. Tariq, S. A. Taqvi, I. Ali, M. B. K. Niazi, T. Noor, A. Hussain, N. Iqbal and M. Shahbaz, J. Waste Manag., 85, 131 (2019).
K. A. Motghare, A. P. Rathod, K. L. Wasewar and N. K. Labhsetwar, J. Waste Manag., 47, 40 (2016).
D. Yoon, K. Y. Chung, W. Chang, S. M. Kim, M. J. Lee, Z. Lee and J. Kim, Chem. Mater., 27, 266 (2015).
T. Szabó, O. Berkesi, P. Forgó, K. Josepovits, Y. Sanakis, D. Petridis and I. Dékány, Chem. Mater., 18, 2740 (2006).
A. Islam, Y. Molla, T. K. Dey, M. Jamal, R. Rathanasamy and M. Uddin, J. Polym. Res., 28, 1 (2021).
D. Zhao, K. Chen, F. Yang, G. Feng, Y. Sun and Y. Dai, Cellulose, 20, 3205 (2013).
S. Yousef, M. Tatariants, M. Tichonovas, L. Kliucininkas, S.-I. Lukošiūtė and L. Yan, J. Clean. Prod., 254, 120078 (2020).
Z. Akyürek, Sustainability, 11, 2280 (2019).
A. Skreiberg, Ø. Skreiberg, J. Sandquist and L. Sørum, Fuel, 90, 2182 (2011).
X. Yang, Y. Zhao, R. Li, Y. Wu and M. Yang, Thermochim. Acta, 665, 20 (2018).
W.-H. Chen, C. F. Eng., Y.-Y. Lin and Q.-V. Bach, Energy Convers. Manag., 221, 113165 (2020).
A. Zaker, Z. Chen, M. Zaheer-Uddin and J. Guo, J. Environ. Chem. Eng., 9, 104554 (2021).
G. Xia, W. Han, Z. Xu, J. Zhang, F. Kong, J. Zhang, X. Zhang and F. Jia, J. Environ. Chem. Eng., 9, 106182 (2021).
V. Balasundram, N. Ibrahim, R. M. Kasmani, M. K. A. Hamid, R. Isha, H. Hasbullah and R. R. Ali, J. Clean. Prod., 167, 218 (2017).
X. Yuan, T. He, H. Cao and Q. Yuan, Renew. Energy, 107, 489 (2017).
S. C. Turmanova, S. D. Genieva, A. S. Dimitrova and L. T. Vlaev, Express Polym. Lett., 2, 133 (2008).
A. C. M. Loy, D. K. W. Gan, S. Yusup, B. L. F. Chin, M. K. Lam, M. Shahbaz, P. Unrean, M. N. Acda and E. Rianawati, Bioresour. Technol., 261, 213 (2018).
Acknowledgements
The authors would like to thank the University of the Punjab, Lahore, Pakistan, and Hamad bin Khalifa University, Qatar, for financial and technical assistance for this study. Additional support from the Korea Institute of Energy Technology Evaluation and Planning (KETEP) granted financial resource from the Ministry of Trade, Industry & Energy (MOTIE), Republic of Korea (No. 2021010000001B) was also appreciated.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Tariq, R., Inayat, A., Shahbaz, M. et al. Kinetic and thermodynamic evaluation of pyrolysis of jeans waste via coats-redfern method. Korean J. Chem. Eng. 40, 155–161 (2023). https://doi.org/10.1007/s11814-022-1248-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-022-1248-3