Abstract
The recovery of iron phosphate involves the addition of oxidizer to oxidize Fe2+ in the spent LiFePO4 (LFP) material to Fe3+ and the agent commonly used is hydrogen peroxide (H2O2). Nevertheless, H2O2 has disadvantages of high price, easy decomposition and low utilization efficiency. In this manuscript, a facile method is proposed for efficient synergistic oxidation of Fe2+ in spent LFP leachate with a mixture of oxygen and ozone. Specifically, we found by thermodynamic computations that the dominant oxidation groups of ozone during oxidation varied with acidity. The oxidation would produce a large number of iron-phosphate complex groups (Fe3H6(PO4) 3+4 , FeH8(PO4) −4 and Fe2HPO 4+4 ) in the phosphorus-sulfur mixed acid system, leading to a paradoxical pH drop. The optimized conditions for H2O2 oxidation were explored. It was determined experimentally that oxidation by gas mixture and O2 belonged to the firstorder and second-order reactions with activation energies of 28.68 kJ/mol and 34.61 kJ/mol, respectively, which were both controlled by a mixture of chemical reaction and diffusion. The optimized oxidation method was finally determined by evaluating the cost and oxidation rate of the oxidizers. The results in this study offer a promising method for new low-cost and efficient Fe2+ oxidation for industrial production.
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Acknowledgements
We gratefully acknowledge support from the Inter-university Cooperation Project of General Undergraduate Colleges and Universities in Liaoning Province (China), the Key Deployment Projects of Chinese Academy of Sciences (No. ZDRW_CN_2020-1), and the Innovation Academy for Green Manufacture, Chinese Academy of Sciences (IAGM-2019-A15).
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A facile method for efficient synergistic oxidation of Fe2+ in phosphorus-sulfur mixed acid system with a mixture of oxygen and ozone
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Liu, Dy., Lou, Wb., Sun, Sn. et al. A facile method for efficient synergistic oxidation of Fe2+ in phosphorus-sulfur mixed acid system with a mixture of oxygen and ozone. Korean J. Chem. Eng. 39, 3323–3333 (2022). https://doi.org/10.1007/s11814-022-1206-0
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DOI: https://doi.org/10.1007/s11814-022-1206-0