Abstract
The solubility of ethylene in N-methyl-2-pyrrolidone (NMP) was evaluated at different temperatures, including 278.2, 298.2, and 328.2 K, and different pressures in an experimental pressure decaying setup. The kinetic and equilibrium results were obtained for pure gas absorption. Henry’s law constants were calculated at different temperatures. Eventually, thermodynamic modeling was done using Peng Robinson equation of state (PR-EOS) and UNIQUAC activity coefficient model. The binary interaction parameters, τ12, τ21, were adjusted and optimized. Regarding the values obtained for binary interaction parameters, it was concluded that this solution has non-ideal behavior. Indeed, because of its low prediction error (3–11%), it was concluded that the correlated thermodynamic model could accurately predict the experimental data.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
Abbreviations
- AAD:
-
absolute average deviation [dimensionless]
- E:
-
activity energy [kJ/mole]
- EOS:
-
equation of state
- G:
-
gibbs free energy [kJ/mole]
- H:
-
enthalpy [kJ/mole]
- KH :
-
Henry’s law constant [bar]
- M w :
-
molecular weight [g/mol]
- n:
-
moles (dimensionless)
- NMP:
-
N-methyl-2-pyrrolidone
- P:
-
pressure [bar]
- PR:
-
peng robinson
- q:
-
relative molecular area
- r:
-
relative molecular volume
- R:
-
gas constants [cm3·bar/mol·K]
- S:
-
entropy [kJ/mole·K]
- T:
-
temperature [K]
- UNIQUAC:
-
universal quasichemical
- V:
-
volume [ml]
- x:
-
solubility or mole fraction in liquid phase [dimensionless]
- y:
-
mole fraction in gas phase [dimensionless]
- Z:
-
compressibility factor [dimensionless]
- ω :
-
acentric factor [dimensionless]
- ρ :
-
density [g/cm3]
- Φ :
-
fugacity coefficient [dimensionless]
- γ :
-
activity coefficient [dimensionless]
- τ :
-
binary interaction parameters of UNIQUAC equation [dimensionless]
- 1:
-
initial
- c:
-
critical
- exp:
-
experimental
- eq:
-
equilibrium
- f:
-
final
- g:
-
gas
- i:
-
component i
- j:
-
component j
- mod:
-
model prediction
- r:
-
reduced
- s:
-
solvent
- sat:
-
saturation
- t:
-
total
References
Y. Pan, C. Jia, B. Liu, Z. Zhang, X. Tong, H. Li, Z. Li, R. Ssebadduka, C. Sun and L. Yang, Fluid Phase Equilib, 414, 14 (2016).
K.-S. Liao, S. Japip, J.-Y. Lai and T.-S. Chung, J. Membr. Sci., 534, 92 (2017).
M. Manteghian, S. M. M. Safavi and A. Mohammadi, Chem. Eng. J., 217, 379 (2013).
R. B. Eldridge, Ind. Eng. Chem. Res., 32, 2208 (1993).
Y. Wang, Z. Hu, Y. Cheng and D. Zhao, Ind. Eng. Chem. Res., 56, 4508 (2017).
S. Azizi, H. T. Dezfuli, A. Kargari and S. M. Peyghambarzadeh, Fluid Phase Equilib., 387, 190 (2015).
S. Wang, X. Li, H. Wu, Z. Tian, Q. Xin, G. He, D. Peng, S. Chen, Y. Yin and Z. Jiang, Energy Environ. Sci., 9, 1863 (2016).
T. A. Reine and R. B. Eldridge, Ind. Eng. Chem. Res., 44, 7505 (2005).
Z. Bao, G. Chang, H. Xing, R. Krishna, Q. Ren and B. Chen, Energy Environ. Sci., 9, 3612 (2016).
A. Malakhov, S. Bazhenov, V. Vasilevsky, I. Borisov, A. Ovcharova, A. Bildyukevich, V. Volkov, L. Giorno and A. Volkov, Sep. Purif. Technol., 219, 64 (2019).
J. Chmelař, K. Smolná, K. Haškovcová, M. Podivinská, J. Maršálek and J. Kosek, Polymer, 59, 270 (2015).
L. Moura, W. Darwich, C. C. Santini and M. F. C. Gomes, Chem. Eng. J., 280, 755 (2015).
H. Mortaheb, M. Mafi, B. Mokhtarani, A. Sharifi, M. Mirzaei, N. Khodapanah and F. Ghaemmaghami, Chem. Eng. J., 158, 384 (2010).
A. Shariati, L. J. Florusse and C. J. Peters, Fluid Phase Equilib., 387, 143 (2015).
Y. Sato, N. Hosaka, H. Inomata and K. Kanaka, Fluid Phase Equilib, 344, 112 (2013).
L.-s. Lee, H.-j. Ou and H.-l. Hsu, Fluid Phase Equilib., 231, 221 (2005).
I. H. Cho, H. K. Yasuda and T. R. Marrero, J. Chem. Eng. Data, 40, 107 (1995).
J. Dojcansky, S. Bafroncova and J. Surovy, Chem. Pap., 55, 71 (2001).
K. Nagahama, I. Suzuki and M. Hirata, J. Chem. Eng. Japan, 4, 1 (1971).
A. J. Cancelas, M. A. Plata, M. A. Bashir, M. Bartke, V. Monteil and T. F. McKenna, Macromol. Chem. Phys., 219, 1700565 (2018).
S. Kumar and M. K. Mondal, Korean J. Chem. Eng., 35, 1335 (2018).
A. Dashti, F. Zargari, H.R. Harami, A. H. Mohammadi and Z. Nikfarjam, Korean J. Chem. Eng., 36, 1637 (2019).
A. Kitagishi, S. Takizawa, Y. Sato and H. Inomata, Fluid Phase Equilib., 492, 110 (2019).
Y. Mi, C. Yao, S. Zhao and G. Chen, Chem. Eng. Process.-Process Intensification, 137, 137 (2019).
J. M. Smith, H. C. Van Ness and M. M. Abbott, Introduction to chemical engineering thermodynamics, 7th Ed., Mc-Graw-Hill, Boston (2005).
E. W. Washburn, Chemistry and technology, Knovel, New York (2003).
M. Bohloul, M. A. Sadeghabadi, S. M. Peyghambarzadeh and M. Dehghani, Fluid Phase Equilib., 447, 132 (2017).
M. Bohloul, A. Vatani and S. M. Peyghambarzadeh, Fluid Phase Equilib., 365, 106 (2014).
S. Azizi, S. M. Peyghambarzadeh, M. Saremi and H. Tahmasebi, Heat Mass Transfer., 50, 1699 (2014).
H. Roeentan, S. Azizi, G. Bakeri and S. M. Peyghambarzadeh, Chem. Eng. Res. Design, 117, 240 (2017).
J.-N. Jaubert and F. Mutelet, Fluid Phase Equilib., 224, 285 (2004).
S. Oba, S. Suzuki, H. Tanaka, K. Nagahama and M. Hirata, J. Jpn. Pet. Inst., 28, 202 (1985).
I. Polishuk, J. Wisniak and H. Segura, Chem. Eng. Sci., 55, 5705 (2000).
G. Wibawa, M. F. Nafi, A. Permatasari and A. Mustain, Modern Appl. Sci., 9, 177 (2015).
S.-E. K. Fateen, M. M. Khalil and A. O. Elnabawy, J. Adv. Res., 4, 137 (2013).
X. Pu, L. Wu and Y. Liu, Int. J. Chem. Eng. Appl., 8, 92 (2017).
J. M. Prausnitz, R. N. Lichtenthaler and E. G. Azevedo, Molecular thermodynamics of fluid phase equilibria, Pearson Education, London (1999).
S. Brelvi, Ind. Eng. Chem. Process Design Dev., 21, 367 (1982).
A. Farajnezhad, O. A. Afshar, M. A. Khansary, S. Shirazian and M. Ghadiri, Fluid Phase Equilib., 417, 181 (2016).
B. E. Poling, J. M. Prausnitz and J. P. O’connell, The properties of gases and liquids, Mcgraw-Hill, New York (2001).
S. Skjold-Jorgensen, B. Kolbe, J. Gmehling and P. Rasmussen, Ind. Eng. Chem. Process Design Dev., 18, 714 (1979).
H. Svensson, C. Hulteberg and H. T. Karlsson, Int. J. Greenhouse Gas Control, 17, 89 (2013).
Z. Wu, S. Zeck and H. Knapp, Berichte der Bunsengesellschaft für Physikalische Chemie, 89, 1009 (1985).
E. R. Shenderei and F. P. Ivanovskii, Khim Prom, 10, 91 (1963).
H. Renon, J. Y. Lenoir and P. Renault, J. Chem. Eng. Data, 16, 340 (1971).
S. Shakhova, Y. P. Zubchenko and L. Kaplan, Khim Prom, 49, 108 (1973).
E. R. Shenderei and F. P. Ivanovskii, Gazov. Prom, 7, 11 (1962).
Acknowledgement
This paper was prepared from a Ph.D. thesis conducted in the Department of Chemical Engineering, Mahshahr branch, Islamic Azad University, Mahshahr, Iran.
Author information
Authors and Affiliations
Corresponding author
Additional information
Supporting Information
Additional information as noted in the text. This information is available via the Internet at http://www.springer.com/chemistry/journal/11814.
Electronic supplementary material
11814_2020_671_MOESM1_ESM.pdf
Solubility of ethylene in N-methyl-2-pyrrolidone: Experimental study and estimation of UNIQUAC activity model parameters
Rights and permissions
About this article
Cite this article
Yousefi, M., Azizi, S., Peyghambarzadeh, S.M. et al. Solubility of ethylene in N-methyl-2-pyrrolidone: Experimental study and estimation of UNIQUAC activity model parameters. Korean J. Chem. Eng. 38, 852–861 (2021). https://doi.org/10.1007/s11814-020-0671-6
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-020-0671-6