Abstract
Platinum(IV) was extracted from chloride solution using kerosene solution of trioctyl ammonium chloride, methyltrioctylammonium chloride, and tetraoctyl ammonium chloride ionic liquids as solvents in high yields. To increase the Pt(IV) recovery and heterogenize the process for easy handling at industrial scale, these three ionic liquids were directly impregnated on some solid carriers, such as silica gel-60, silica gel-100, Amberlite XAD-7 ion-exchange resin, and Amberlite XAD-7 ion-exchange resin to form sorbents in nature of supported ionic liquid phase. The influence of some factors, such as ionic liquid and solid carrier structure, IL/Pt molar ratio, and ionic liquid loading as well as sorption isotherms, was investigated. The stripping and desorption of Pt(IV) using different eluents and reusability of ionic liquids and supported ionic liquid phases were also evaluated.
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Abbreviations
- [N0888]Cl:
-
trioctyl ammonium chloride
- [N1888]Cl:
-
methyltrioctylammonium chloride
- [N8888]Cl:
-
tetraoctyl ammonium chloride
- FT-IR:
-
fourier transform infrared spectroscopy
- IL:
-
ionic liquid
- NMR:
-
nuclear magnetic resonance spectroscopy
- SILP:
-
supported ionic liquid phase
- XAD-4:
-
amberlite XAD-4 exchange resins
- XAD-7:
-
amberlite XAD-7 exchange resins
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Acknowledgements
This work was supported by the National Foundation for Science and Technology Development, Ministry of Science and Technology, Vietnam (grant number 104.01-2016.57, 2017).
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Bui, T.T.L., Uong, H.T.N., Nguyen, D.K. et al. Using solid carriers impregnated with ammonium ionic liquids for platinum(IV) recovery from chloride solutions. Korean J. Chem. Eng. 37, 2262–2272 (2020). https://doi.org/10.1007/s11814-020-0659-2
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DOI: https://doi.org/10.1007/s11814-020-0659-2