Abstract
N/S dual-doped carbon materials were synthesized from coffee waste and cysteine for use as porous carbon electrode materials for electric double layer capacitors. The capacitance of the carbon materials was calculated from the experimental results of cyclic voltammetry and galvanostatic charge-discharge tests. The N/S-doped carbon materials obtained from heat-treatment with cysteine exhibited a higher discharge capacitance, 71.3 F/g, than that of the carbon without the cysteine treatment, 43.8 F/g, at 1 A/g. This is because the N/S dual-doped carbons possess a higher wettability than that of the other carbon material, even though the N/S doping with cysteine destroys the porous carbon structure, which reduces the BET surface area of the carbon samples. Elemental analysis was performed to determine the portions of nitrogen and sulfur elements doped into the carbon. From the XPS results, various states of nitrogen and sulfur elements were identified, and SEM/TEM images were obtained to observe their morphologies and porous structures.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
A. G. Pandolfo and A. F. Hollenkamp, J. Power Sources, 157, 11 (2006).
M. D. Stoller and R. S. Ruoff, J. Energy Environ. Sci., 3, 1294 (2010).
L. Hao, X. Li and L. Zhi, Adv. Mater., 25, 3899 (2013).
B. E. Conway, Electrochemical supercapacitors: Scientific fundamentals and technological applications, Plenum Press, New York (1999).
P. Simon and Y. Gogotsi, Nat. Mater., 7, 845 (2008).
Y.-J. Kim, B.-J. Lee, H. Suezaki, T. Chino, Y. Abe, T. Yanagiura, K. C. Park and M. Endo, Carbon, 44, 1592 (2006).
W. Lee, M. Kwon, S. Park, D. Lim, J.-H. Cha and H. Lee, Chem.- Asian J., 8, 1569 (2013).
K. S. Lee, M. Park, S. Choi and J.-D. Kim, Colloids Surf. A: Physicochem. Eng. Aspects, 529, 107 (2017).
S. H. Kwon, E. Lee, B.-S. Kim, S.-G. Kim, B.-J. Lee, M.-S. Kim and J. C. Jung, Korean J. Chem. Eng., 32, 248 (2015).
I. Yang, D. Kwon, M.-S. Kim and J. C. Jung, Carbon, 132, 503 (2018).
N. M. Shinde, A. D. Jagadale, V. S. Kumbhar, T. R. Rana, J. Kim and C. D. Lokhande, Korean J. Chem. Eng., 32, 974 (2015).
N. Venugopal and W.-S. Kim, Korean J. Chem. Eng., 32, 1918 (2015).
W.-J. Lee, S. Jeong, H. Lee, B.-J. Kim, K.-H. An, Y.-K. Park and S.-C. Jung, Korean J. Chem. Eng., 34, 2993 (2017).
J. Banerjee, K. Dutta, M. A. Kader and S. K. Nayak, Polym. Adv. Technol., 30, 1902 (2019).
Y. Tian, C. Yang, X. Song, J. Liu, L. Zhao, P. Zhang and L. Gao, Chem. Eng. J., 374, 59 (2019).
J. P. Paraknowitsch and A. Thomas, J. Energy Environ. Sci., 6, 2839 (2013).
Y. Kim, W. Lee, G. M. Kim and J. W. Lee, RSC Adv., 6, 54889 (2016).
W. Lee, G. M. Kim, S. Baik and J. W. Lee, Electrochim. Acta, 210, 743 (2016).
A. Byeon, W. Lee, G. M. Kim and J. W. Lee, J. CO2Util., 16, 420 (2016).
Z. Yang, L. Xie, Y. Chen, T. Xue, B. Ma, K. Zhang, J. Zhao and J. Wei, Appl. Surf. Sci., 493, 1205 (2019).
Y. S. Yun, M. H. Park, S. J. Hong, M. E. Lee, Y. W. Park and H.-J. Jin, ACS Appl. Mater. Interfaces, 7, 3684 (2015).
S. M. Unni, L. George, S. N. Bhange, R. N. Devi and S. Kurungot, RSC Adv., 6, 82103 (2016).
D. Y. Chung, Y. J. Son, J. M. Yoo, J. S. Kang, C.-Y. Ahn, S. Park, Y.-E. Sung, ACS Appl. Mater. Interfaces, 9, 41303 (2017).
L. Jiang, L. Sheng and Z. Fan, Sci. China Mater., 61, 133 (2018).
A. Srinu, S. G. Peera, V. Parthiban, B. Bhuvaneshwari and A. K. Sahu, Chem Select, 3, 690 (2018).
I. I. Misnon, N. K. M. Zain and R. Jose, Waste Biomass Valoriz., 10, 1731 (2019).
R. Campos-Vega, G. Loarca-Piña, H.A. Vergara-Castañeda, B. D. Oomah, Trends Food Sci. Technol., 45, 24 (2015).
J. Zhang, Z. Xia and L. Dai, Sci. Adv., 1, e1500564 (2015).
S. Niu, W. Lv, G. Zhou, Y. He, B. Li, Q.-H. Yang and F. Kang, Chem. Commun., 51, 17720 (2015).
H. Zhang, Y. Niu and W. Hu, J. Colloid Interface Sci., 505, 32 (2017).
Z.-S. Wu, W. Ren, L. Xu, F. Li and H.-M. Cheng, ACS Nano, 5, 5463 (2011).
J. Liu, C. K. Poh, D. Zhan, L. Lai, S. H. Lim, L. Wang, X. Liu, N. G. Sahoo, C. Li, Z. Shen and J. Lin, Nano Energy, 2, 377 (2013).
J. Wu, Z. Pan, Y. Zhang, B. Wang and H. Peng, J. Mater. Chem. A, 6, 12932 (2018).
W. Kiciński, M. Szala and M. Bystrzejewski, Carbon, 68, 1 (2014).
J. Yan, Q. Wang, T. Wei and Z. Fan, Adv. Energy Mater., 4, 1300816 (2014).
T. Wang, P. Zhang, Y. Sun, B. Liu, Y. Liu, Z.-A. Qiao, Q. Huo and S. Dai, Chem. Mater., 29, 4044 (2017).
T. Wang, Y. Sun, L. Zhang, K. Li, Y. Yi, S. Song, M. Li, Z.-A. Qiao and S. Dai, Adv. Mater., 31, 1807876 (2019).
B. Quan, S.-H. Yu, D. Y. Chung, A. Jin, J. H. Park, Y.-E. Sung and Y. Piao, Sci. Rep., 4, 5639 (2014).
C. Kim, J.-W. Lee, J.-H. Kim and K.-S. Yang, Korean J. Chem. Eng., 23, 592 (2006).
D. Yuan, J. Chen, J. Zeng and S. Tan, Electrochem. Commun., 10, 1067 (2008).
Acknowledgement
This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20182010202100).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Hong, J., Kim, H., Lee, J.E. et al. Nitrogen and sulfur dual-doped porous carbon derived from coffee waste and cysteine for electrochemical energy storage. Korean J. Chem. Eng. 37, 1218–1225 (2020). https://doi.org/10.1007/s11814-020-0544-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-020-0544-z