Abstract
A modified group-contribution PC-SAFT EoS combined with the Free-volume theory (FVT), recently proposed (DOI:https://doi.org/10.1016/j.fluid.2019.112280) to simultaneously model the fluid phase equilibria and viscosity of fluids, is extended in this work to estimate the viscosity of 1-alkenes. Generalized correlation coefficients are proposed for the FVT triplet parameter set, which makes it possible to extrapolate the viscosity prediction of similar compounds that are not included in the fitting pool. The model is validated using a large experimental data of 1-alkenes over wide range of temperature and pressure (up to 2,500 bars). For 1-pentene to 1-triacontene, the overall average absolute deviation of the experimental liquid and vapor viscosity from those calculated by the model is of 5.37% and 1.41%, respectively, which are appropriate for most industrial applications.
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Abbreviations
- AAD:
-
average absolute deviation
- CP-PC-SAFT:
-
critical point-based modified PC-SAFT
- DIPPR:
-
design institute for physical property data
- EoS:
-
equation of state
- mg-SAFT:
-
modified group-contribution PC-SAFT
- FVT:
-
free-volume theory
- FT:
-
friction theory
- EFT-YS:
-
expanded fluid theory-Yarranton and Satyro
- Npt:
-
number of data points
- P:
-
pressure [bar]
- PC-SAFT:
-
perturbed-chain statistical associating fluid theory
- PR:
-
peng-robinson
- SAFT:
-
statistical associating fluid theory
- SRK:
-
Soave-Redlich-Kwong
- T:
-
temperature [K]
- exp:
-
experimental
- calc:
-
calculated
References
E. Hendriks, G. M. Kontogeorgis, R. Dohrn, J.-C. de Hemptinne, I. G. Economou, L. F. Zilnik and V. Vesovic, Ind. Eng. Chem. Res., 49, 11131 (2010).
C. Nieto-Draghi, G. Fayet, B. Creton, X. Rozanska, P. Rotureau, J.-C. de Hemptinne, P. Ungerer, B. Rousseau and C. Adamo, Chem. Rev., 115, 13093 (2015).
A. K. Mehrotra, W. D. Monnery and W. Y. Svrcek, Fluid Phase Equilib., 117, 344 (1996).
H. O. Baled, I. K. Gamwo, R. M. Enick and M. A. McHugh, Fuel, 218, 89 (2018).
I. Polishuk, Ind. Eng. Chem. Res., 54, 6999 (2015).
R. J. Martins, M. J. E. d. M. Cardoso and O. E. Barcia, Ind. Eng. Chem. Res., 42, 3824 (2003).
A. Allal, C. Boned and A. Baylaucq, Phys. Rev. E, 64, 011203 (2001).
S. E. Quiñones-Cisneros, C. K. Zéberg-Mikkelsen, J. Fernández and J. García, AIChE J., 52, 1600 (2006).
M. A. Satyro and H. W. Yarranton, Fluid Phase Equilib., 298, 1 (2010).
I. Polishuk and A. Yitzhak, Ind. Eng. Chem. Res., 53, 959 (2014).
M. He, X. Qi, X. Liu, C. Su and N. Lv, Int. J. Refrigeration, 54, 55 (2015).
S. P. Tan, H. Adidharma, B. F. Towler and M. Radosz, Ind. Eng. Chem. Res., 44, 8409 (2005).
F. Llovell, R. Marcos and L. Vega, J. Phys. Chem. B, 117, 8159 (2013).
J. Gross and G. Sadowski, Ind. Eng. Chem. Res., 40, 1244 (2001).
D. NguyenHuynh, Fluid Phase Equilib., 430, 33 (2016).
D. NguyenHuynh, T. Q. C. Mai and T. K. S. Tran, Fluid Phase Equilib., 501, 112280 (2019).
D. NguyenHuynh, M. T. Luu, X. T. T. Nguyen, C. T. Q. Mai and S. T. K. Tran, Fluid Phase Equilib., 502, 112298 (2019).
T. T. X. Nguyen and D. NguyenHuynh, Fluid Phase Equilib., 472, 128 (2018).
P. D. Neufeld, A. Janzen and R. Aziz, J. Chem. Phys., 57, 1100 (1972).
D. NguyenHuynh and D. NguyenHuynh, Fluid Phase Equilib., 434, 176 (2017).
D. Nguyenhuynh, Modélisation thermodynamique de mélanges symétriques et asymétriques de composés polaires oxygénés et/ou aromatiques par gc-saft, phd thesis, Institut Galileé, Universite Paris Nord, Villetaneuse, France (2008, pp. 59–105).
D. NguyenHuynh, Fluid Phase Equilib., 473, 201 (2018).
R. Rowley, Dippr data compilation of pure chemical properties, Design Institute for Physical Properties, Ref Type: Electronic Citation (2010).
D. I. Sagdeev, M. G. Fomina, G. K. Mukhamedzyanov and I. M. Abdulagatov, J. Mol. Liq., 197, 160 (2014).
D. I. Sagdeev, M. G. Fomina, G. K. Mukhamedzyanov and I. M. Abdulagatov, Thermochim. Acta, 592, 73 (2014).
D. I. Sagdeev, M. G. Fomina and I. M. Abdulagatov, J. Solution Chem., 46, 966 (2017).
H. Lubarsky, I. Polishuk and D. NguyenHuynh, J. Supercrit. Fluids, 110, 11 (2016).
H. Lubarsky, I. Polishuk and D. NguyenHuynh, J. Supercrit. Fluids, 115, 65 (2016).
D. NguyenHuynh, S. T. K. Tran and C. Mai, Ind. Eng. Chem. Res., 58(36), 16963 (2019).
D. NguyenHuynh and C. T. Q. Mai, Ind. Eng. Chem. Res., 58, 8923 (2019).
E. T. Hashim, L. Ghalib and H. Adell, Pet. Sci. Technol., 30, 2341 (2012).
H. Gürbüz Yücel and S. Özdo an, Can. J. Chem. Eng., 76, 148 (1998).
D. I. Sagdeev, M. G. Fomina, G. K. Mukhamedzyanov and I. M. Abdulagatov, J. Chem. Eng. Data, 59, 1105 (2014).
D. I. Sagdeev, M. G. Fomina, G. K. Mukhamedzyanov and I. M. Abdulagatov, High Temp.-High Pressures, 42, 509 (2013).
K. Lucas and K. Stephan, Viscosity of dense fluids, Plenum Press: New York (1979).
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NguyenHuynh, D., Luu, M.T., Mai, C.T.Q. et al. Free-volume theory coupled with modified group-contribution PC-SAFT for predicting viscosities of 1-alkenes. Korean J. Chem. Eng. 37, 402–410 (2020). https://doi.org/10.1007/s11814-019-0473-x
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DOI: https://doi.org/10.1007/s11814-019-0473-x