Abstract
A 3D model for a section of cathode fuel cell comprised of a bipolar plate, a gas diffusion layer (GDL) and a catalyst layer was simulated. The diameter of the carbon fiber GDL is assumed to be the same; moreover, a new and simple method is introduced for the reconstruction of this layer numerically. This method gives the ability to model the heterogeneous and anisotropic structure of the GDL; furthermore, it allows easy implementation and provides realistic results with consideration of the lack of overlap between carbon fibers. The lattice Boltzmann method (LBM) was employed to simulate the flow and the electrochemical reaction. The impacts of changes in the activation potential and the GDL carbon fiber diameter on oxygen species and water vapor, as well as the electric current density distribution over the catalyst layer, were studied. The results showed that at higher values of the activation potential, the concentration of oxygen near the catalyst layer was lower. The current density over the catalyst layer also increased by increasing the activation potential; on the other hand, the mole fraction of water vapor in the cathode increased with the increase in the flow of gas products. Consequently, results indicated that the variation in the GDL carbon fiber diameter affects the distribution of reactants.
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References
F. Barbir, PEM fuel cells: Theory and practice, Academic press (2012).
D. Feroldi and M. Basualdo, Green Energy Technol., 87, 49 (2012).
H. Frey and W. Münch, BWK — Energie-Fachmagazin, 56, 58 (2004).
G. H. Song and H. Meng, Acta Mech. Sin. Xuebao, 29, 318 (2013).
H. A. Gasteiger and M. F. Mathias, Proc. 3rd Symp. Prot. Conduct. Membr. Fuel Cells, 1 (2002).
Y. Wang, K. S. Chen, J. Mishler, S. C. Cho and X. C. Adroher, Appl. Energy, 88, 981 (2011).
Spiegel, Colleen. PEM fuel cell modeling and simulation using MATLAB. Elsevier (2011).
S. Didari, T. A. L. Harris, W. Huang, S. M. Tessier and Y. Wang, ECS Trans., 41, 499 (2011).
J. Gostick, M. Ioannidis, M. Fowler and M. Pritzker, J. Power Sources, 173, 277 (2007).
N. Pourmahmoud, S. Rezazadeh, I. Mirzaee and V. Heidarpoor, J. Mech. Sci. Technol., 25, 2665 (2011).
Z. Shi and X. Wang, J. Fuel Cell Sci. Technol., 9, 021001 (2012).
R. Wu, X. Zhu, Q. Liao, R. Chen and G. M. Cui, Int. J. Hydrogen Energy, 38, 4067 (2013).
Y. Lee, J. Mech. Sci. Technol., 31, 1959 (2017).
M. Abdollahzadeh, J. C. Pascoa, A. A. Ranjbar and Q. Esmaili, Energy, 68, 478 (2014).
N. H. Maslan, M. M. Gau, M. S. Masdar, and M. I. Rosli, J. Eng. Sci. Technol., 11, 85 (2016).
M. Liang, Y. Liu, B. Xiao, S. Yang, Z. Wang and H. Han, Int. J. Hydrogen Energy, 43, 17880 (2018).
Y. Wang, C. Y. Wang and K. S. Chen, Electrochim. Acta, 52, 3965 (2007).
V. Radhakrishnan and P. Haridoss, Mater. Des., 32, 861 (2011).
K.-J. Lee, J. H. Nam and C.-J. Kim, Electrochim. Acta, 54, 1166 (2009).
H. Ostadi, P. Rama, Y. Liu, R. Chen, X. X. Zhang and K. Jiang, Chem. Eng. Sci., 65, 2213 (2010).
J. Becker, V. Schulz and A. Wiegmann, J. Fuel Cell Sci. Technol., 5, 021006 (2008).
L. Vázquez, A. H. Creus, P. Carro, P. Ocón, P. Herrasti, C. Palacio, J. M. Vara, R. C. Salvarezza and A. J. Arvia, J. Phys. Chem., 96, 10454 (1992).
M. Göbel, M. Godehardt and K. Schladitz, J. Power Sources, 355, 8 (2017).
J. Liao, G. Yang, S. Li, Q. Shen, Z. Jiang, H. Wang, L. Xu, M. Espi-noza-Andaluz and X. Pan, Energy Fuels, 35(3), 2654 (2021).
A. H. Kakaee, G. R. Molaeimanesh and M. H. Elyasi Garmaroudi, Int. J. Hydrogen Energy, 43, 15481 (2018).
Y. T. Mu, L. Chen, Y. L. He and W. Q. Tao, Build. Environ., 92, 236 (2015).
R. Bahoosh, M. Jafari and S. S. Bahrainian, J. Heat Mass Transf. Res., 6, 105 (2019).
L. Chapelle, M. Lévesque, P. Brøndsted, M. R. Foldschack and Y. Kusano, in ICCM Int. Conf. Compos. Mater. (2015).
K. Schladitz, S. Peters, D. Reinel-Bitzer, A. Wiegmann and J. Ohser, Comput. Mater. Sci., 38, 56 (2006).
C. Peyrega, D. Jeulin, C. Delisée and J. Malvestio, Image Anal. Stereol., 28, 129 (2009).
L. Chen, H.-B. Luan, Y.-L. He and W.-Q. Tao, Int. J. Therm. Sci., 51, 132 (2012).
V. P. Schulz, J. Becker, A. Wiegmann, P. P. Mukherjee and C.-Y. Wang, J. Electrochem. Soc., 154, B419 (2007).
L. Hao and P. Cheng, J. Power Sources, 186, 104 (2009).
Y. Wang, S. Cho, R. Thiedmann, V. Schmidt, W. Lehnert and X. Feng, Int. J. Heat Mass Transf., 53, 1128 (2010).
J. Feder, J. Theor. Biol., 87, 237 (1980).
F. Naddeo, N. Cappetti and A. Naddeo, Comput. Mater. Sci., 81, 239 (2014).
H. Moussaddy, Doctoral dissertation, Montral University (2013).
N. Provatas, M. Haataja, J. Asikainen, S. Majaniemi, M. Alava and T. Ala-Nissila, Colloids Surfaces A Physicochem. Eng. Asp., 165, 209 (2000).
G. Falcucci, S. Ubertini, E. Galloni and E. Jannelli, in EFC 2009 — Piero Lunghi Conf. Proc. 3rd Eur. Fuel Cell Technol. Appl. Conf. (2009).
B. Han, J. Yu and H. Meng, J. Power Sources, 202, 175 (2012).
L. Xiao, M. Luo, H. Zhang, R. Zeis and P.-C. Sui, J. Electrochem. Soc., 166, F377 (2019).
G. R. Molaeimanesh, M. H. Shojaeefard and M. R. Moqaddari, Korean J. Chem. Eng., 36, 136 (2019).
P. L. Bhatnagar, E.P. Gross and M. Krook, Phys. Rev., 94, 511 (1954).
G.R. Molaeimanesh and M.H. Akbari, Korean J. Chem. Eng., 32, 397 (2015).
X. Shan and H. Chen, Phys. Rev. E, 47, 1815 (1993).
A. A. Mohamad, Lattice boltzmann method, 2nd Ed., Springer-Verlag, London (2011).
S. Succi, Oxford Univ. Press, Oxford (2001).
H. R. Ashorynejad, K. Javaherdeh and H. E. A. Van den Akker, Int. J. Hydrogen Energy, 41, 14239 (2016).
M. R. Kamali, S. Sundaresan, H. E. A. Van den Akker and J. J. J. Gillissen, Chem. Eng. J., 207-208, 587 (2012).
L. Vinet and A. Zhedanov, Arch. Ophthalmol., 122, 552 (2010).
H. Anton, Methods Enzymol., 461, 397 (2009).
G. R. Molaeimanesh and M. H. Akbari, J. Power Sources, 258, 89 (2014).
Q. Zou and X. He, Phys. Fluids, 9, 1591 (1997).
D. A. Nield and A. Bejan, Convection in porous media, Springer, New York (2013).
M. Kaviany, Mech. Eng. Ser., 53, 726 (1995).
A. Koponen, D. Kandhai, E. Hellén, M. Alava, A. Hoekstra, M. Kataja, K. Niskanen, P. Sloot and J. Timonen, Phys. Rev. Lett., 80, 716 (1998).
C. N. Davies, Proc. Inst. Mech. Eng., 167, 185 (1952).
O. Filippova and D. Hänel, J. Comput. Phys., 147, 219 (1998).
A. Koponen, M. Kataja and J. Timonen, Phys. Rev. E — Stat. Physics, Plasmas, Fluids, Relat. Interdiscip. Top., 56, 3319 (1997).
Acknowledgements
The authors thank the reviewers and editor for the constructive comments. The authors would like to thank the Vice-chancellor for research, Shahid Chamran University of Ahvaz (Grant number: 94/3/02/315790).
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Bahoosh, R., Jafari, M. & Bahrainian, S.S. 3-D modeling of proton exchange fuel cell cathode with a novel random generation of gas diffusion porous layer. Korean J. Chem. Eng. 38, 1703–1714 (2021). https://doi.org/10.1007/s11814-019-0462-0
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DOI: https://doi.org/10.1007/s11814-019-0462-0