Abstract
An “ink” solution based process, using spin-coating technique, followed by annealing in selenium environment with different temperature programs was utilized to prepare CIGSe thin films. Herein, the CuIn0.7Ga0.3Se2 nanocrystals were synthesized using ethanol — a “green” solvent. Three different solvents: 2-propanol, 2-methoxyethanol, and their 2: 1 mixture (v/v ratio), were investigated as a dispersion medium for the as-synthesized CIGSe nanocrystals to form a stable ink solution. The last one- a mixture of 2-propanol: 2-methoxyethanol=2: 1 (v/v), was found to be the most suitable. Furthermore, the influences of various annealing modes on the CIGSe grain size and density in the resulting film were also studied. The as-prepared CIGSe thin film was around 1 µm thick and possessed a tetragonal structure. A newly developed cheaper and “greener” non-vacuum process was applied successfully from the synthesis of nanocrystals to the formation of ink solution, and produced high quality thin films; this opens a new route to the cost-competitive commercialization of CIGSe thin film solar cells.
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This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20173010012980).
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Le, T.T.T., Le, N., Pallavolu, M.R. et al. Green and low-cost preparation of CIGSe thin film by a nanocrystals ink based spin-coating method. Korean J. Chem. Eng. 36, 2110–2117 (2019). https://doi.org/10.1007/s11814-019-0386-8
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DOI: https://doi.org/10.1007/s11814-019-0386-8