Abstract
The formation of methanol directly from methane and steam was observed over Cu ion-exchanged mordenite. Furthermore, the continuous production of methanol was achieved by co-feeding methane and steam over Cumordenite. The methanol production rate was comparable to that reported in the stepwise process in which activation, methane reaction, and extraction of methanol were carried out separately.
Article PDF
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
R. A. Kerr, Science, 328, 1624 (2010).
K. Aasberg-Petersen, I. Dybkjær, C.V. Ovesen, N.C. Schjødt, J. Sehested and S. G. Thomsen, J. Nat. Gas Sci. Eng., 3, 423 (2011).
C. Hammond, S. Conrad and I. Hermans, ChemSusChem, 5, 1668 (2012).
P. Schwach, X. Pan and X. Bao, Chem. Rev., 117(13), 8497 (2017).
P. Tian, Y. Wei, M. Ye and Z. Liu, ACS Catal., 5(3), 1922 (2015).
N. J. Gunsalus, A. Koppaka, S. H. Park, S. M. Bischof, B. G. Hashiguchi and R. A. Periana, Chem. Rev., 117 (13), 8521 (2017).
M. Ravi, M. Ranocchiari and J. A. van Bokhoven, Angew. Chemie - Int. Ed., 56, 16464 (2017).
V. L. Sushkevich, D. Palagin, M. Ranocchiari and J. A. van Bokhoven, Science, 356, 523 (2017).
V. L. Sushkevich, D. Palagin and J.A. van Bokhoven, Angew. Chem. Int. Ed., 57(29), 8906 (2018).
Y. Kim, T.Y. Kim, H. Lee and J. Yi, Chem. Commun., 53(29), 4116 (2017).
S.E. Bozbag, E.M. C. Alayon, J. Pechácek, M. Nachtegaal, M. Ranocchiari and J. A. van Bokhoven, Catal. Sci. Technol., 6(13), 5011 (2016).
M.B. Park, S. H. Ahn, A. Mansouri, M. Ranocchiari and J. A. van Bokhoven, ChemCatChem, 9(19), 3705 (2017).
K. Narsimhan, K. Iyoki, K. Dinh and Y. Román-Leshkov, ACS Cent. Sci., 2(6), 424 (2016).
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Rights and permissions
About this article
Cite this article
Lee, S.H., Kang, J.K. & Park, E.D. Continuous methanol synthesis directly from methane and steam over Cu(II)-exchanged mordenite. Korean J. Chem. Eng. 35, 2145–2149 (2018). https://doi.org/10.1007/s11814-018-0150-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-018-0150-5