Abstract
A novel electrochemical procedure was developed for the facile preparation of Gd-doped iron oxide nanoparticles (GdIO-NPs). A simple galvanostatic deposition (i=10 mA cm-2) was done in an additive-free aqueous solution containing FeCl2·4H2O, Fe(NO3)3·9H2O and GdCl3·6H2O. The XRD, FE-SEM, EDS and TEM characterizations showed that the product is composed of 15% GdIO-NPs with 10 nm in size. VSM analysis proved that the GdIO-NPs are superparamagnetic. The cyclic voltammetry and charge-discharge tests showed that the prepared GdIO-NPs are capable to deliver specific capacity as high as 190.1 F g-1 at 0.5A g-1 and capacity retention of 95.1% after 2000 cycling. Based on the results, it was concluded that the developed electrochemical strategy acts as an efficient procedure for the preparation of lanthanide doped MNPs with proper magnetic and supercapacitive characters.
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K. Ulbrich, K. Hola, V. Subr, A. Bakandritsos, J. Tucek and R. Zboril, Chem. Rev., 116, 5338 (2016).
M. Aghazadeh, R. Ahmadi, D. Gharailou, M. R. Ganjali and P. Norouzi, J. Mater. Sci.: Mater. Electron., 27, 8623 (2016).
M. Aghazadeh, J. Appl. Electrochem., 42, 89 (2012).
M. Aghazadeh, M. Hosseinifard, B. Sabour and S. Dalvand, Appl. Surf. Sci., 287, 187 (2013).
N. Venugopal, W. S. Kim and T. Yu, Korean J. Chem. Eng., 33, 1500 (2016).
M. G. Jeong, K. Zhuo, S. Cherevko and C. H. Chung, Korean J. Chem. Eng., 29, 1802 (2012).
M. Aghazadeh and M. R. Ganjali, Ceram. Int., 44, 520 (2018).
M. Aghazadeh, J. Mater. Sci.: Mater. Electron., 28, 3108 (2017).
A. Barani, M. Aghazadeh, M. R. Ganjali, B. Sabour, A. A. M. Barmi and S. Dalvand, Mater. Sci. Semiconduct. Process., 23, 85 (2014).
M. Aghazadeh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 28, 8144 (2017).
N. Madhukar Shinde, A. D. Jagadale, V. S. Kumbhar, T. R. Rana, J. H. Kim and C. D. Lokhande, Korean J. Chem. Eng., 32, 974 (2015).
R. Poonguzhali, N. Shanmugam, R. Gobi, A. Senthilkumar, G. Viruthagiri and N. Kannadasan, J. Power Sources., 293, 790 (2015).
M. Aghazadeh, A. Bahrami-Samani, D. Gharailou, M. Ghannadi Maragheh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 27, 11192 (2016).
M. Aghazadeh, M. R. Ganjali and P. Norouzi, J. Mater. Sci.: Mater. Electron., 27, 7707 (2016).
J. Tizfahm, M. Aghazadeh, M. G. Maragheh, M. R. Ganjali and P. Norouzi, Mater. Lett., 167, 153 (2016).
X. Huang, M. Kim, H. Suh and I. Kim, Korean J. Chem. Eng., 33, 2228 (2016).
M. Aghazadeh, M. Asadi, M. G. Maragheh, M. R. Ganjali and P. Norouzi, Appl. Surf. Sci., 364, 726 (2016).
M. Aghazadeh, M. G. Maragheh, M. R. Ganjali, P. Norouzi and F. Faridbod, Appl. Surf. Sci., 364, 141 (2016).
M. Aghazadeh, M. R. Ganjali and P. Noruzi, Thin Solid Films, 634, 24 (2017).
E. M. Jin, H. J. Lee, H. B. Jun and S. Mun Jeong, Korean J. Chem. Eng., 34, 891 (2017).
M. Aghazadeh, A. A. Malek Barmi, D. Gharailou, M. H. Peyrovi, B. Sabour and F. Najafi, Appl. Surf. Sci., 283, 871 (2013).
G. H. Jeong, H. M. Lee, H. Lee, C. K. Kim, Y. Piao, J. H. Lee, J. H. Kim and S. W. Kim, RSC Adv., 4, 51619 (2014).
M. Aghazadeh and S. Dalvand, J. Electrochem. Soc., 161, D18 (2014).
M. Aghazadeh, S. Dalvand and M. Hosseinifard, Ceram. Int., 40, 3485 (2014).
M. Aghazadeh, H. Mohammad Shiri and A. A. Malek Barmi, Appl. Surf. Sci., 273, 237 (2013).
M. Aghazadeh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 28, 11406 (2017).
J. Talat Mehrabad, M. Aghazadeh, M. Ghannadi Maragheh and M. R. Ganjali, Mater. Lett., 184, 223 (2016).
M. Aghazadeh, A. Rashidi and M. R. Ganjali, Electronic. Mater. Lett., 14, 37 (2018).
J. Gou, S. Xie, Y. Liu and C. Liu, Electrochim. Acta, 210, 915 (2016).
J. Tizfahm, B. Safibonab, M. Aghazadeh, A. Majdabadi, B. Sabour and S. Dalvand, Colloids Surf. A, 443, 544 (2014).
M. Aghazadeh, M. Ghaemi, A. N. Golikand and A. Ahmadi, Mater. Lett., 65, 2545 (2011).
M. Aghazadeh, M. Ghaemi, B. Sabour and S. Dalvand, J. Solid State Electrochem., 18, 1569 (2014).
M. Aghazadeh, B. Sabour, M. R. Ganjali and S. Dalvand, Appl. Surf. Sci., 313, 581 (2014).
A. A. Yadav, J. Mater. Sci.: Mater. Electron., 27, 12876 (2016).
M. Aghazadeh, I. Karimzadeh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 28, 18121 (2017).
M. Zhang, J. Sha, X. Miao, E. Liu, C. Shi, J. Li, C. He, Q. Li and N. Zhao, J. Alloys Compd., 696, 956 (2017).
E. Mitchell, R. K. Gupt, K. Mensah-Darkw, D. Kumar, K. Ramasamy, B. K. Gupta and P. Kahol, New J. Chem., 38, 4344 (2014).
V. D. Nithya and N. Sabari Arul, J. Power Source, 327, 297 (2016).
L. Wang, H. Ji, S. Wang, L. Kong, X. Jiang and G. Yang, Nanoscale, 5, 3793 (2013).
M. Aghazadeh, I. Karimzadeh and M. R. Ganjali, Mater. Lett., 209, 450 (2017).
V. D. Nithya and N. Sabari Arul, J. Mater. Chem. A., 4, 10767 (2016).
Z. Zhou, W. Xie, S. Li, X. Jiang, D. He, S. Peng and F. Ma, J. Solid State Electrochem., 19, 1211 (2015).
Y. Yang, J. Li, D. Chen and J. Zhao, ACS Appl. Mater. Interfaces, 8, 26730 (2016).
S. Chen, R. Zhou, Y. Chen, Y. Fu, P. Li, Y. Song and L. Wang, J. Nanopart. Res., 19, 127 (2017).
Y. Z. Wu, M. Chen, X. H. Yan, J. Ren, Y. Dai, J. J. Wang, J. M. Pan, Y. P. Wang and X. N. Cheng, Mater. Lett., 198, 114 (2017).
H. Fan, R. Niu, J. Duan, W. Liu and W. Shen, ACS Appl. Mater. Interfaces, 8, 19475 (2016).
X. Yang, J. Kan, F. Zhang, M. Zhu and Z. Li, J. Inorg. Org. Polym. Mater., 27, 542 (2017).
X. Tang, R. Jia, T. Zhai and H. Xia, ACS Appl. Mater. Interfaces, 7, 27518 (2015).
T. Xia, X. Xu, J. Wang, C. Xu, F. Meng, Z. Shi, J. Lian and J. M. Bassat, Electrochim. Acta, 160, 114 (2015).
W. M. Zhang, X. L. Wu, J. S. Hu, Y. G. Guo and L. J. Wan, Adv. Funct. Mater., 18, 3941 (2008).
C. R. De Silva, S. Smith, I. Shim, J. Pyun, T. Gutu, J. Jiao and Z. Zheng, J. Am. Chem. Soc., 131, 6336 (2009).
J. C. Park, S. Yeo, M. Kim, G. T. Lee and J. H. Seo, Mater. Lett., 181, 272 (2016).
H. Zhang, V. Malik, S. Mallapragada and M. Akinc, J. Magn. Magn. Mater., 423, 386 (2017).
F. J. Douglas, D. A. MacLaren, N. Maclean, I. Andreu, F. J. Kettles and F. Tuna, RSC Adv., 6, 74500 (2016).
I. Karimzadeh, M. Aghazadeh, M. R. Ganjali, P. Norouzi, T. Doroudi and P. H. Kolivand, Mater. Lett., 189, 290 (2017).
I. Karimzadeh, M. Aghazadeh, M. R. Ganjali, P. Norouzi, S. Shirvani-Arani, T. Doroudi, P. H. Kolivand, S. A. Marashi and D. Gharailoud, Mater. Lett., 179, 5 (2016).
M. Aghazadeh and M. R. Ganjali, J. Mater. Sci.: Mater. Electron., 29, 4981 (2018).
I. Karimzadeh, M. Aghazadeh, M. R. Ganjali and T. Dourudi, Curr. Nanosci., 13, 167 (2017).
I. Karimzadeh, H. Rezagholipour Dizaji and M. Aghazadeh, Mater. Res. Express, 3, 095022 (2016).
M. Aghazadeh and M. R. Ganjali, J. Mater. Sci., 53, 295 (2018).
Z. Bakhtiary, A. A. Saei, M. J. Hajipour, M. Raoufi, O. Vermesh and M. Mahmoudi, Nanomed., 12, 287 (2016).
K. Ulbrich, K. Hola, V. Subr, A. Bakandritsos, J. Tucek and R. Zboril, Chem. Rev., 116, 5338 (2016).
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Aghazadeh, M., Karimzadeh, I., Maragheh, M.G. et al. Gd3+ doped Fe3O4 nanoparticles with proper magnetic and supercapacitive characteristics: A novel synthesis platform and characterization. Korean J. Chem. Eng. 35, 1341–1347 (2018). https://doi.org/10.1007/s11814-018-0027-7
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DOI: https://doi.org/10.1007/s11814-018-0027-7