Abstract
Ni/SBA-15 catalyst was prepared by homogeneous precipitation method (Ni-HP) and used for dry reforming of methane (DRM). The related characterization results indicated that the Ni particles were highly dispersed with a size range of 2-5 nm. Compared with Ni/SBA-15 catalyst prepared by impregnation (Ni-IM), the reduction temperature of Ni-HP obtained from H2-TPR was greatly improved, suggesting the stronger metal-support interaction. After reacting at 700 °C for 100 h, the CH4 conversion of DRM over Ni-HP catalyst slightly decreased from 74.5% to 73.8%. While, for the Ni-IM catalyst, the CH4 conversion dropped from 61.7% to 37.3%. Furthermore, the average particle size of Ni-HP was 3.7 nm and 4.7 nm before and after the long-time stability test, respectively, ascribed to the good anti-sintering property. Although a certain amount of coke was produced, mainly with disorder filamentous carbon of base-growth, the Ni/SBA-15 prepared by homogeneous precipitation exhibited excellent catalytic activity and stability.
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Zhang, Q., Wang, J., Ning, P. et al. Dry reforming of methane over Ni/SBA-15 catalysts prepared by homogeneous precipitation method. Korean J. Chem. Eng. 34, 2823–2831 (2017). https://doi.org/10.1007/s11814-017-0182-2
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DOI: https://doi.org/10.1007/s11814-017-0182-2